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Production and Characterization of Green Biosorbent Based on Modified Corn Cob Decorated Magnetite Nanoparticles

DOI: 10.4236/msce.2023.112001, PP. 1-12

Keywords: Green Biosorbent, Corn Cob, Magnetite Nanoparticles, Surface Chemistry, NaOH Activation

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Abstract:

In most developing countries, particularly in the countries of sub-Saharan Africa, corn cobs are considered as waste polluting the environment during the harvest period of this cereal. In order to valorize this agricultural waste, high-performance, inexpensive and low-energy consumption magnetic bioadsorbents were prepared from corn cobs. The chemically activated raw corn cob was magnetized by coating the surface with magnetite nanoparticles. The prepared biosorbents were characterized by FT-IR, XRD, FE-SEM associated with EDX, HR-TEM, TG analysis, BET surface area analysis and XPS. The maximum specific surface area of 35.22 m2/g was reached. An attempt to use of these magnetic biosorbents for the removal of heavy metal like Cr(VI) from aqueous solution was envisaged.

References

[1]  Crini, G., Lichtfouse, E., Wilson, L. and Morin-Crini, N. (2019) Conventional and non-Conventional Adsorbents for Wastewater Treatment. Environmental Chemistry Letters, 17, 195-213.
https://doi.org/10.1007/s10311-018-0786-8
[2]  Gupta, V.K., Carrott, P.J.M., Ribeiro, M.M.L. and Suhas, C. (2009) Low-Cost Adsorbents: Growing Approach to Wastewater Treatment—A Review. Critical Review in Environmental Science and Technology, 39, 783-842.
https://doi.org/10.1080/10643380801977610
[3]  Tang, S., Chen, Y., Xie, R., Jiang, W. and Jiang, Y. (2016) Preparation of Activated Carbon from Corn Cob and Its Adsorption Behavior on Cr(VI) Removal. Water Science & Technology, 73, 2654-2661.
https://doi.org/10.2166/wst.2016.120
[4]  Kaźmierczak, J., Nowicki, P. and Pietrzak, R. (2013) Sorption Properties of Activated Carbons Obtained from Corn Cobs by Chemical and Physical Activation. Adsorption, 19, 273-281.
https://doi.org/10.1007/s10450-012-9450-y
[5]  Song, M., Jin, B., Xiao, R., Yang, L., Wu, Y., Zhong, Z. and Huang, Y. (2013) The Comparison of Two Activation Techniques to Prepare Activated Carbon from Corn Cob. Biomass and Bioenergy, 48, 250-256.
https://doi.org/10.1016/j.biombioe.2012.11.007
[6]  El-Sayed, G.O., Yehia, M.M. and Asaad, A.A. (2014) Assessment of Activated Carbon Prepared from Corncob by Chemical Activation with Phosphoric Acid. Water Resources and Industry, 7-8, 66-75.
https://doi.org/10.1016/j.wri.2014.10.001
[7]  Jain, A., Jayaraman, S., Balasubramanian, R. and Srinivasan, M.P. (2014) Hydrothermal Pre-Treatment for Mesoporous Carbon Synthesis: Enhancement of Chemical Activation. Journal of Materials Chemistry A, 2, 520-528.
https://doi.org/10.1039/C3TA12648J
[8]  Liu, Z. and Zhang, F.-S. (2011) Removal of Copper(II) and Phenol from Aqueous Solution Using Porous Carbons Derived from Hydrothermal Chars. Desalination, 267, 101-106.
https://doi.org/10.1016/j.desal.2010.09.013
[9]  Jiang, W., Zhang, L., Guo, X., Yang, M., Lu, Y. and Wang, Y. (2019) Adsorption of Cationic Dye from Water Using an Iron Oxide/Activated Carbon Magnetic Composites Prepared from Sugarcane Bagasse by Microwave Method. Environmental Technology, 42, 337-350.
https://doi.org/10.1080/09593330.2019.1627425
[10]  Liu, X., Tian, J., Li, Y., Sun, N., Mi, S., Xie, Y. and Chen, Z. (2019) Enhanced Dyes Adsorption from Wastewater via Fe3O4 Nanoparticles Functionalized Activated Carbon. Journal of Hazardous Materials, 373, 397-407.
https://doi.org/10.1016/j.jhazmat.2019.03.103
[11]  Oliveira, H. (2012) Chromium as an Environmental Pollutant: Insights on Induced Plant Toxicity. Journal of Botany, 2012, Article ID: 375843.
https://doi.org/10.1155/2012/375843
[12]  Politi, D. and Sidiras, D. (2020) Modified Spruce Sawdust for Sorption of Hexavalent Chromium in Batch Systems and Fixed-Bed Columns. Molecules, 25, Article No. 5156.
https://doi.org/10.3390/molecules25215156
[13]  Muhammad, A., Shah, A.U.H.A. and Bilal, S. (2020) Effective Adsorption of Hexavalent Chromium and Divalent Nickel Ions from Water through Polyaniline, Iron Oxide, and Their Composites. Applied Sciences, 10, Article No. 2882.
https://doi.org/10.3390/app10082882
[14]  Mojdeh, O., Mohamed, K.A., Wan, A.W.D. and Saeid, B. (2009) Removal of Hexavalent Chromium-Contaminated Water and Wastewater: A Review. Water Air and Soil Pollution, 200, 59-77.
https://doi.org/10.1007/s11270-008-9893-7
[15]  Ding, J., Pu, L., Wang, Y., Wu, B., Yu, A., Zhang, X., Pan, B., Zhang, Q. and Gao, G. (2018) Adsorption and Reduction of Cr(VI) Together with Cr(III) Sequestration by Polyaniline Confined in Pores of Polystyrene Beads. Environmental Science & Technology, 52, 12602-12611.
https://doi.org/10.1021/acs.est.8b02566
[16]  Oliveira, L.C.A., Rios, R.V.R.A., Fabris, J.D., Garg, V., Sapag, K. and Lago, R.M. (2002) Activated Carbon/Iron Oxide Magnetic Composites for the Adsorption of Contaminants in Water. Carbon, 20, 2177-2183.
https://doi.org/10.1016/S0008-6223(02)00076-3
[17]  Nethaji, S., Sivasamy, A. and Mandal, A.B. (2013) Preparation and Characterization of Corn Cob Activated Carbon Coated with Nano-Sized Magnetite Particles for the Removal of Cr(VI). Bioresource Technology, 134, 94-100.
https://doi.org/10.1016/j.biortech.2013.02.012
[18]  Ji, Z., Lin, H., Chen, Y.-F., Dong, Y.-B. and Imran, M. (2015) Corn Cob Modified by Lauric Acid and Ethanediol for Emulsified Oil Adsorption. Journal of Central South University, 22, 2096-2105.
https://doi.org/10.1007/s11771-015-2734-0
[19]  Allou, N.B., Saikia, J. and Goswamee, R.L. (2018) Use of Calcined Mg-Al Layered Double Hydroxides to Regulate Endocrine Disruptor Methylparaben in Excess as Adsorbent and as Control Releasing Agent in Normal Situations. Journal of Environmental Chemical Engineering, 6, 1189-1200.
https://doi.org/10.1016/j.jece.2017.12.015
[20]  Singh, D., Singh, S.K., Atar, N. and Krishna, V. (2016) Amino Acid Functionalized Magnetic Nanoparticles for Removal of Ni(II) from Aqueous Solution. Journal of the Taiwan Institute Chemical Engineers, 67, 148-160.
https://doi.org/10.1016/j.jtice.2016.06.017
[21]  Xu, P., Zeng, G.M., Huang, D.L., Yan, M., Chen, M., Lai, C., Jiang, H., Wu, H.P., Chen, G.M. and Wan, J. (2017) Fabrication of Reduced Glutathione Functionalized Iron Oxide Nanoparticles for Magnetic Removal of Pb(II) from Wastewater. Journal of the Taiwan Institute Chemical Engineers, 71, 165-173.
https://doi.org/10.1016/j.jtice.2016.11.031
[22]  Sun, X., Li, Q., Yang, L. and Liu, H. (2016) Removal of Chromium(VI) from Wastewater Using Weakly and Strongly Basic Magnetic Adsorbents: Adsorption/Desorption Property and Mechanism Comparative Studies. RSC Advances, 6, 18471-18482.
https://doi.org/10.1039/C5RA27028F

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