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热/机械稳定的锂金属负极的制备方法
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Abstract:
以金属锂化学为基础的可充电电池由于其具有超高容量和能量密度，有希望成为下一代的能源储存装置。然而，锂负极热耐受性较差、结构强度较低等原因，严重阻碍了高安全性和高能量密度的锂金属电池在当前和未来的广泛应用。在这篇综述中，我们从热稳定性和对外力的耐受性等方面严谨地讨论了稳固型金属锂负极制造的研究现状，总结了当前制造稳固型金属锂负极的方法，强调了稳固型锂负极制备过程对锂的能量密度产生的副作用。最后，我们提出了热稳定和机械稳定锂负极设计制造的未来趋势和挑战，及其在下一代电池中的广泛应用前景。
Rechargeable batteries based on metallic lithium chemistry are promising for next-generation energy storage due to their ultrahigh capacity and energy densities. However, the poor thermal tolerance, and low structure strength of lithium anode seriously hinder the widespread adoption of high-security and energy-dense lithium metal batteries in today and the future. In this review, we critically discuss the current status of research on robust lithium metal anode processing from the perspectives of thermal stability, and the tolerance for external forces; summarize recent strategies to fabricate a robust lithium metal anode; emphasize the side effect on the energy density of lithium during the robust anode preparation process. Finally, we proposed the future trends and challenges of the design and fabrication of thermal/mechanical-stable lithium anode and prospects toward their broad application in next-generation batteries.
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