All Title Author
Keywords Abstract

Publish in OALib Journal
ISSN: 2333-9721
APC: Only $99

ViewsDownloads

Relative Articles

More...

分子基磁致冷材料的研究进展
Recent Advances of Molecular-Based Magnetic Refrigeration Materials

DOI: 10.12677/NAT.2022.124027, PP. 270-282

Keywords: 磁致冷材料,过渡金属,稀土金属,过渡–稀土混金属,磁熵
Magnetic Refrigeration Materials
, Transition, Lanthanide, Transition-lanthanide, Magnetic entropy

Full-Text   Cite this paper   Add to My Lib

Abstract:

分子基磁致冷材料因其在信息存储、量子计算、磁热转换等领域的优良前景受到了广泛关注。分子基磁致冷磁性材料可以实现尺寸小到分子水平的低维磁结构,并且具有性质上的单分散性以及化学可修饰性,这也为理论研究提供了重要模型。因此,本论文从分子基磁致冷材料的基础理论和设计策略出发,将其分为过渡,稀土,以及稀土–过渡混金属三类,分别介绍近年来该材料在结构与性能方面取得的最新进展。
Molecular-based magnetic refrigeration materials have attracted wide attention because of their excellent prospects in information storage, quantum computing, magneto-thermal conversion and other fields. Molecular-based magnetic refrigeration materials can achieve low-dimensional magnetic structures as small as the molecular level, and have the properties of monodispersity and chemical modifiability, which also provides an important model for theoretical research. Therefore, based on the basic theory and design strategy of molecu-lar-based magnetic refrigeration materials, this paper divides them into three categories: transition, lanthanide, and transition-lanthanide, and introduces the latest progress in the structure and properties of the materials in recent years.

References

[1]  Gatteschi, D., Caneschi, A., Pardi, L., et al. (1994) Large Clusters of Metal Ions: The Transition from Molecular to Bulk Magnets. Science, 265, 1054-1058.
https://doi.org/10.1126/science.265.5175.1054
[2]  Leuenberger, M.N. and Loss, D. (2001) Quantum Computing in Molecular Magnets. Nature, 410, 789-793.
https://doi.org/10.1038/35071024
[3]  Gatteschi, D. and Sessoli, R. (2003) Quantum Tunneling of Magnetization and Related Phenomena in Molecular Materials. Angewandte Chemie International Edition, 42, 268-297.
https://doi.org/10.1002/anie.200390099
[4]  Bogani, L. and Wernsdorfer, W. (2008) Molecular Spintronics Using Single-Molecule Magnets. Nature Materials, 7, 179-186.
https://doi.org/10.1038/nmat2133
[5]  Haas, W.J.D. (1933) Extremely Low Temperatures. Nature, 132, 372-373.
https://doi.org/10.1038/132372a0
[6]  McMichael, R.D., Ritter, J.J. and Shull, R.D. (1993) Enhanced Magnetoca-loric Effect in Gd3Ga5?xFexO12. Journal of Applied Physics, 73, 6946-6948.
https://doi.org/10.1063/1.352443
[7]  Sessoli, R., Tsai, H.L., Folting, K., et al. (1993) High-Spin Molecules: [Mn12O12(O2CR)16(H2O)4]. Journal of the American Chemical Society, 115, 1804-1816.
https://doi.org/10.1021/ja00058a027
[8]  Thomas, L., Lionti, F., Ballou, R., et al. (1996) Macroscopic Quantum Tunnelling of Magnetization in a Single Crystal of Nanomagnets. Nature, 383, 145-147.
https://doi.org/10.1038/383145a0
[9]  Ren, M. and Zheng, L.M. (2015) Lanthanide-Based Single Molecule Mag-nets. Acta Chimica Sinica, 73, 1091-1113.
https://doi.org/10.6023/A15060376
[10]  Blachowicz, T. and Ehrmann, A. (2021) New Materials and Effects in Molecular Nanomagnets. Applied Sciences, 11, 7510-7515.
https://doi.org/10.3390/app11167510
[11]  Habib, F., Long, J., Lin, P.H., et al. (2012) Supramolecular Architectures for Controlling Slow Magnetic Relaxation in Field-Induced Single-Molecule Magnets. Chemical Science, 3, 2158-2164.
https://doi.org/10.1039/c2sc01029a
[12]  Ako, A.M., Hewitt, I.J., Mereacre, V., et al. (2006) A Ferromagnetically Coupled Mn19 Aggregate with a Record S = 83/2 Ground Spin State. Angewandte Chemie International Edition, 45, 4926-4929.
https://doi.org/10.1002/anie.200601467
[13]  Zadrozny, J.M., Xiao, D.J., Atanasov, M., et al. (2013) Magnetic Blocking in a Linear Iron(I) Complex. Nature Chemistry, 5, 577-581.
https://doi.org/10.1038/nchem.1630
[14]  Rinehart, J.D. and Long, J.R. (2011) Exploiting Single-Ion Anisotropy in the Design of f-Element Single-Molecule Magnets. Chemical Science, 2, 2078-2085.
https://doi.org/10.1039/c1sc00513h
[15]  Tishin, A.M. (1990) Magnetic Refrigeration in the Low-Temperature Range. Journal of Applied Physics, 68, 6480-6484.
https://doi.org/10.1063/1.347186
[16]  Sun, W.B., Yan, P.F., Jiang, S.D., et al. (2016) High Symmetry or Low Symmetry, That Is the Question-High Performance Dy(III) Single-Ion Magnets by Electrostatic Potential Design. Chem-ical Science, 7, 684-691.
https://doi.org/10.1039/C5SC02986D
[17]  Ishikawa, N., Sugita, M. and Ishikawa, T. (2003) Lanthanide Dou-ble-Decker Complexes Functioning as Magnets at the Single-Molecular Level. Journal of the American Chemical Society, 125, 8694-8695.
https://doi.org/10.1021/ja029629n
[18]  Candini, A., Klyatskaya, S., Ruben, M., et al. (2011) Graphene Spintronic Devices with Molecular Nanomagnets. National Science Review, 11, 2634-2639.
https://doi.org/10.1021/nl2006142
[19]  Kyatskaya, S., GalánMascarós, J.R., Bogani, L., et al. (2009) Anchoring of Rare-Earth-Based Single-Molecule Magnets on Single-Walled Carbon Nanotubes. Journal of the American Chemical Society, 131, 15143-15151.
https://doi.org/10.1021/ja906165e
[20]  Katoh, K., Komeda, T. and Yamashita, M. (2010) Surface Morphologies, Electronic Structures, and Kondo Effect of Lanthanide(III)-Phthalocyanine Molecules on Au(III) by Using STM, STS and FET Properties for Next Generation Devices. Dalton Transactions, 39, 4708-4723.
https://doi.org/10.1039/b926121d
[21]  Liu, J.-L., Chen, Y.-C., Guo, F.-S., et al. (2014) Recent Advances in the Design of Magnetic Molecules for Use as Cryogenic Magnetic Coolants. Coordination Chemistry Reviews, 281, 26-49.
https://doi.org/10.1016/j.ccr.2014.08.013
[22]  Nayak, S., Evangelisti, M., Powell, A.K. and Reedijk, J. (2010) Magnetothermal Studies of a Series of Coordination Clusters Built from Ferromagnetically Coupled {Mn(II)(4)Mn(III)(6)} Supertetrahedral Units. Chemistry, 16, 12865-12872.
https://doi.org/10.1002/chem.201001988
[23]  Chen, Y.C., Guo, F.S., Liu, J.L., et al. (2014) Switching of the Magnetocaloric Effect of Mn(II) Glycolate by Water Molecules. Chemistry, 20, 3029-3035.
https://doi.org/10.1002/chem.201304423
[24]  Shaw, R., Laye, R.H., Jones, L.F., et al. (2007) 1,2,3-Triazolate-Bridged Tetradecametallic Transition Metal Clusters [M14(L)6O6(OMe)18X6] (M = FeIII, CrIII and VIII/IV) and Related Compounds: Ground-State Spins Ranging from S = 0 to S = 25 and Spin-Enhanced Magnetocalor-ic Effect. Inorganic Chemistry, 46, 4968-4978.
https://doi.org/10.1021/ic070320k
[25]  Wang, J., Feng, M. and Akhtar, M.N. (2019) Recent Advance in Hetero-metallic Nanomagnets Based on TMxLn4?x Cubane Subunits. Coordination Chemistry Reviews, 387, 129-153.
https://doi.org/10.1016/j.ccr.2019.02.008
[26]  Sharples, J.W., Zheng, Y.Z. and Tuna, F. (2011) Lanthanide Discs Chill Well and Relax Slowly. Chemical Communications, 47, 7650-7652.
https://doi.org/10.1039/c1cc12252e
[27]  Zhou, M., Wu, L.-H., Wu, X.-Y., et al. (2021) Two Dinuclear GdIII Clus-ters Based on Isobutyric Acid and Nicotinic Acid with Large Magnetocaloric Effects. Journal of Molecular Structure, 1227, 119689-119654.
https://doi.org/10.1016/j.molstruc.2020.129689
[28]  Shi, Q.-H., Xue, C.-L., Fan, C.-J., et al. (2021) Magnetic Re-frigeration Property and Slow Magnetic Relaxation Behavior of Five Dinuclear Ln(III)-Based Compounds. Polyhedron, 194, 114938-114949.
https://doi.org/10.1016/j.poly.2020.114938
[29]  Wang, J., Wu, Z.-L., Yang, L.-R., et al. (2021) Two Lantha-nide-Based Dinuclear Clusters (Gd2 and Dy2) with Schiff Base Derivatives: Synthesis, Structures and Magnetic Proper-ties. Inorganica Chimica Acta, 514, 120015-120021.
https://doi.org/10.1016/j.ica.2020.120015
[30]  Chen, Y.-C., Prokle?ka, J., Xu, W.-J., et al. (2015) A Brilliant Cry-ogenic Magnetic Coolant: Magnetic and Magnetocaloric Study of Ferromagnetically Coupled GdF3. Journal of Materials Chemistry C, 3, 12206-12211.
https://doi.org/10.1039/C5TC02352A
[31]  Peng, J.B., Zhang, Q.C., Kong, X.J., et al. (2012) High-Nuclearity 3d-4f Clusters as Enhanced Magnetic Coolers and Molecular Magnets. Journal of the American Chemical Society, 134, 3314-3317.
https://doi.org/10.1021/ja209752z
[32]  Wang, P., Shannigrahi, S., Yakovlev, N.L., et al. (2012) Gen-eral One-Step Self-Assembly of Isostructural Intermetallic Co(II)(3)Ln(III) Cubane Aggregates. Inorganic Chemistry, 51, 12059-12061.
https://doi.org/10.1021/ic301527b
[33]  Wang, P., Shannigrahi, S., Yakovlev, N.L., et al. (2014) Magnetocaloric Effect of a Series of Remarkably Isostructural Intermetallic [Ni(II)3Ln(III)] Cubane Aggregates. Dalton Transactions, 43, 182-187.
https://doi.org/10.1039/C3DT52176A
[34]  Hooper, T.N., Inglis, R., Lorusso, G., et al. (2016) Structurally Flexible and Solution Stable [Ln4TM8(OH)8(L)8(O2CR)8 (MeOH)y](ClO4)4: A Playground for Magnetic Refrigeration. Inorganic Chemistry, 55, 10535-10546.
https://doi.org/10.1021/acs.inorgchem.6b01730
[35]  Lin, Q., Li, J., Dong, Y., et al. (2017) Lantern-Shaped 3d-4f High-Nuclearity Clusters with Magnetocaloric Effect. Dalton Transactions, 46, 9745-9749.
https://doi.org/10.1039/C7DT01978E
[36]  Zhao, X.-Q., Wang, J., Zhang, F.-H., et al. (2020) Significant Magne-tocaloric Effect in a Ferromagnetic {CrIII2GdIII3} Cluster. Polyhedron, 179, 114385-114390.
https://doi.org/10.1016/j.poly.2020.114385

Full-Text

comments powered by Disqus

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133

WeChat 1538708413