The influence of thermal treatment on the lux-ampere characteristics of polycrystalline films from the CdSexS1-x solid solution obtained by the method of thermal evaporation in a vacuum has been investigated. It is shown that at low illumination intensities L < 2 lx, the mobility μ of electrons increases with a power law μ ~ Lγ, first with the exponent γ > 1, then with γ ≈ 0.5, and their concentration n almost does not change. Starting from the intensity L > 12 - 15 lx, the electron concentration increases strongly n ~ Lβ from β ≈ 3.0, and the parameters n and μ reach relatively high values ~(1015 - 1016) sm-3 and ~(150 - 200) sm2/V·s, however further, at L > 50 lx, a weak dependence of n(L) and μ(L) with β, γ < 1.0 is found. The obtained experimental results are interpreted on the basis of a model of a semiconductor film with intergranular potential barriers when the concentration and barrier mechanisms of photoconductivity operate simultaneously.
References
[1]
Ayibjanov, M., Karimov, M.A., Saidov, M.S. and Yuldashev, N.Kh. (1996) Anomalnaya temperaturnaya zavisimosti infrakrasnoye gasheniye ravnovesnoy provodimostiv polikristallicheskix plenkax CdSe. Fizika Tverdogo Tela, 9, 1578-1584.
[2]
Karimov, M.A. and Yuldashev, N.X. (2004) Infrakrasniy fotopriyemnik izlucheniya na osnove legirovannoy polikristallicheskoy plenki CdSe. Uzbekskiy Fizicheskiy Jurnal, 4, 270-275.
[3]
Yuldashev, N.Kh. and Karimov, M.A. (2005) Lyuks-ampernaya xarakteristika plenochnix polikristallicheskix fotorezistorov iz CdSe s prodolnoy fotoprovodimostyu. Uzbekskiy Fizicheskiy Jurnal, 4, 254-259.
[4]
Polvonov, B.Z. and Yuldashev, N.Kh. (2016) Spectra of Low-Temperature Photolumines-Cence in Thin Polycrystalline CdTe Films. Semiconductors, 50, 1001-1004.
[5]
Rivkin, S.M. (1963) Fotoelektricheskiye yavleniya v poluprovodnikax. Fizmatgiz, Moskva.
[6]
Karimov, M.A. and Yuldashev, N.Kh. (2007) Short-Circuit Current Spectra of Photovoltaic CdTe and CdTe: In Films. Russian Physics Journal, 50, 71-74. https://doi.org/10.1007/s11182-007-0008-5
[7]
Lashkarev, V.S., Lyubchenko, L.K. and Sheynkman, M.K. (1981) Neravnovesniye prosessi v poluprovodnikax. Naukova Dumka, Kiyev.
[8]
Akhmadaliev, B.Zh., Yuldashev, N.Kh. and Yulchiev, I.I. (2018) Surface-Radiative Modes and Longitudinal Excitons in the Spectra of Exciton-Polariton Luminescence. Optics and Spectroscopy, 125, 343-352. https://doi.org/10.1134/S0030400X18090023
[9]
Tivanov, M., Ostretsov, E., Drozdov, N., Survilo, L., Fedotov, A., Trofimov, Yu. and Mazanik, A. (2007) Optical and Photoelectrical Properties of CdSexS1-x Films Produced by Screen-Printing Technology. Physica Status Solidi (b), 244, 1694-1699. https://doi.org/10.1002/pssb.200675137
[10]
Akhmadaliev, B.Zh., Polvonov, B.Z. and Yuldashev, N.Kh. (2014) Influence of Exciton Decay on the Polariton Luminescence Spectra of CdTe Crystal. Optics and Spectroscopy, 116, 244-248. https://doi.org/10.1134/S0030400X14020027
[11]
Meshkov, A.S., Ostretsov, E.F., Pogosov, W.V., Ryzhikov, I.A. and Trofimov. Yu.V. (2008) Photoconductivity of CdS-CdSe Granular Films: Influence of Microstructure. Semiconductor Science and Technology, 25, Article ID: 065013. https://doi.org/10.1088/0268-1242/25/6/065013
[12]
Karimov, M.A. and Yuldashev, N.Kh. (2007) Obliquely Deposited CdTe: In Films with Anomalous Photovoltaic Properties. Bulletin of the Russian Academy of Sciences: Physics, 71, 1151-1153. https://doi.org/10.3103/S1062873807080291
[13]
Abbas, N.K., Naji, I.S. and Abdulmajeed, A.A. (2013) Electrical Properties of Thermally Evaporated CdSexS1-x Thin Films. International Review of Physics (IREPHY), 7, 70-75.
[14]
Trofimov, Y.V., et al. (2012) Physicochemical Features of Dielectrical Nano-Barrier Layers in CdSexS1-x Films Formed by Screen Printing Method. Lithuanian Journal of Physics, 52, 219-223. https://doi.org/10.3952/physics.v52i3.2473
[15]
Abdinov, A.Sh., Djafarov, M.A. and Mamedova, S.A. (2006) Relaksasiya fotoprovodimosti ximicheski osajdennix plenok CdSe1-xTex. Bakinskiy Gosudarstvenniy Universitet. Fizika i Astronomiya, 2, 95-98.
[16]
Akhmadaliev, B.J., Polvonov, B.Z. and Yuldashev, N.Kh. (2016) On the Low-Temperature Photoluminescence and Photovoltaic Properties of Fine-Grained CdTe Films. Journal of Surface Investigation. X-ray, Synchrotron and Neutron Techniques, 10, 1173-1178. https://doi.org/10.1134/S1027451016050244
[17]
Imomalievich, R.T., Tolibjonovna, M.D. and Khaydarovich, Y.N. (2021) Photoelectric Phenomena in Thin Polycrystalline CdTe, CdSe, CdS Films under Mechanical Deformation. European Science Review, 11-12, 40-49. https://doi.org/10.29013/ESR-21-11.12-40-49
[18]
Mamatov, O.M. (2020) Preparation by Thermovacuum Evaporation of Film Heterostructure n-CdS/p-CdTe with Anomalous Photoelectric Properties. Scientific Technical Journal, 3, 6-10.
[19]
Movlonov, P.I., Yunusov, N., Otazhonov, S.M. and Rakhmonkulov, M.Kh. (2021) Effect of Heat Treatment on the Photovoltaic Properties of the SiO2-Te-CdTe Heterostructure. Science and World International Scientific Journal, 89, 22-27.