All Title Author
Keywords Abstract

Publish in OALib Journal
ISSN: 2333-9721
APC: Only $99


Relative Articles


Research Progress of 2D MOFs Based Electrocatalysts in Water Electrol

DOI: 10.12677/NAT.2022.124024, PP. 225-242

Keywords: 二维金属–有机框架,电催化,电解水,合成方法
Two-Dimensional Metal-Organic Frameworks
, Electrocatalysis, Water Splitting, Synthetic Methods

Full-Text   Cite this paper   Add to My Lib


Two-dimensional metal-organic frameworks (MOFs) materials have attracted the interest of researchers because of their excellent properties such as high specific sur-face area, porosity, good electrical conductivity and abundant active sites. The construction of two-dimensional nanostructures is an effective way to improve the catalytic performance of elec-trocatalysts, especially in water splitting as an electrocatalyst shows great application potential. At present, researchers have made extensive studies on the preparation of two-dimensional MOFs materials, and also well used two-dimensional MOFs materials as electrocatalysts for HER and OER reactions. In this paper, two kinds of synthesis methods of two-dimensional MOFs materials, top-down and bottom-up, as well as the advantages and disadvantages of each method are summa-rized, and the application of two-dimensional MOFs in electrolysis and hydropower catalysis is in-troduced. Finally, the challenges and current situation in electrocatalysis of two-dimensional MOFs materials are discussed, and the future development direction was prospected.


[1]  刘洋洋, 孙燕芳, 靳文, 等. 直接甲醇燃料电池阳极催化剂的研究进展[J]. 电源技术, 2019, 43(8): 1397-1402.
[2]  丁鑫, 张栋铭, 焦纬洲, 等. 直接甲醇燃料电池阳极催化剂研究进展[J]. 化工进展, 2021,40(9): 4918-4930.
[3]  张巧, 王剑平, 赵君, 等. 直接甲醇燃料电池阳极催化剂载体的研究进展[J]. 贵金属, 2021: 1-8.
[4]  罗远来, 梁振兴, 廖世军, 等. 直接甲醇燃料电池阳极催化剂研究进展[J]. 催化学报, 2010, 31(2): 141-149.
[5]  Yuan, X.L., Jiang, B., Cao, M.H., et al. (2022) Porous Pt Nanoframes Decorated with Bi(OH)3 as Highly Efficient and Stable Elec-trocatalyst for Ethanol Oxidation Reaction. Nano Research, 13, 265-272.
[6]  Gong, L.Y., Yang, Z.Y., Li, K., et al. (2018) Recent Development of Methanol Electrooxidation Catalysts for Direct Methanol Fuel Cell. Journal of Energy Chemistry, 27, 1618-1628.
[7]  Li, H.Y., Wu, X.S., Tao, X.L., et al. (2018) Direct Synthesis of Ultrathin Pt Nanowire Arrays as Catalysts for Methanol Oxidation. Small, 16, Article ID: 2001135.
[8]  Alisa, S.M., Zhang, G., Kisailus, D., et al. (2010) Porous Platinum Nanotubes for Oxygen Reduction and Methanol Oxidation Reactions. Advanced Functional Materials, 20, 3742-3746.
[9]  Yuan, X.L., Jiang, X.Q., Cao, M.H., et al. (2019) Intermetallic PtBi Core/Ultrathin Pt Shell Nanoplates for Efficient and Stable Methanol and Ethanol Electro-Oxidization. Nano Research, 12, 429-436.
[10]  Li, Z.Y., Jiang, X., Wang, X.R., et al. (2020) Concave PtCo Nanocrosses for Methanol Oxidation Reaction. Applied Catalysis B: Environmental, 277, Article ID: 119135.
[11]  Shi, Y.D., Zhu, W.X., Shi, H.X., et al. (2019) Mesocrystal PtRu Supported on Reduced Graphene Oxide as Catalysts for Methanol Oxidation Reaction. Journal of Colloid and Interface Science, 557, 729-736.
[12]  Kwon, S., Ham, D.J., Kim, T., et al. (2018) Active Methanol Oxida-tion Reaction by Enhanced CO Tolerance on Bimetallic Pt/Ir Electrocatalysts Using Electronic and Bifunctional Effects. ACS Applied Materials & Interfaces, 10, 39581-39589.
[13]  Yang, P.P., Yuan, X.L., Hu, H.C., et al. (2018) Solvothermal Synthesis of Alloyed PtNi Colloidal Nanocrystal Clusters (CNCs) with Enhanced Catalytic Activity for Methanol Oxidation. Advanced Functional Materials, 28, Article ID: 1704774.
[14]  Zhang, S., Zeng, Z.C., Li, Q.Q., et al. (2021) Lanthanide Electronic Perturbation in Pt-Ln (La, Ce, Pr and Nd) Alloys for Enhanced Methanol Oxidation Reaction Activity. Energy & Envi-ronmental Science, 14, 5911-5918.
[15]  Liang, W.K., Wang, Y.W., Zhao, L., et al. (2021) 3D Anisotropic Au@Pt-Pd Hemispherical Nanostructures as Efficient Electrocatalysts for Methanol, Ethanol, and Formic Acid Oxidation Reaction. Advanced Materials, 33, Article ID: 2100713.
[16]  Baronia, R., Goel, J., Tiwari, S., et al. (2017) Efficient Electro-Oxidation of Methanol Using PtCo Nanocatalysts Supported Reduced Graphene Oxide Matrix as Anode for DMFC. International Journal of Hydrogen Energy, 42, 10238-10247.
[17]  Shi, X.Q., Wen, Y., Guo, X.Y., et al. (2017) Dentritic CuPtPd Catalyst for Enhanced Electrochemical Oxidation of Methanol. ACS Applied Materials & Interfaces, 9, 25995-26000.
[18]  Zhang, J.X., Yuan, M.L., Zhao, T.K., et al. (2021) Cu-Incorporated PtBi Intermetallic Nanofiber Bundles Enhance Alcohol Oxidation Electrocatalysis with High CO Tolerance. Journal of Materials Chemistry A, 9, 20676-20684.
[19]  Zhang, J.X., Zhao, T.K., Yuan, M.L., et al. (2021) Trimetallic Synergy in Dendritic Intermetallic PtSnBi Nanoalloys for Promoting Electrocatalytic Alcohol Oxidation. Journal of Colloid and Interface Science, 602, 504-512.
[20]  Li, J.R., Jilani, S.Z., Lin, H.H., et al. (2019) Ternary CoPtAu Na-noparticles as a General Catalyst for Highly Efficient Electro-Oxidation of Liquid Fuels. Angewandte Chemie Interna-tional Edition, 58, 11527-11533.
[21]  Zhang, Y. and Mcginn, P.J. (2012) Combinatorial Screening for Methanol Oxidation Catalysts in Alloys of Pt, Cr, Co and V. Journal of Power Sources, 206, 29-36.
[22]  Cheng, N., Zhang, L., Jiang, H.Y., et al. (2019) Local-ly-Ordered PtNiPb Ternary Nano-Pompons as Efficient Bifunctional Oxygen Reduction and Methanol Oxidation Cata-lysts. Nanoscale, 11, 16945-16953.
[23]  Zeng, K.Z., Zhang, J.W., Gao, W.Q., et al. (2022) Surface-Decorated High-Entropy Alloy Catalysts with Significantly Boosted Activity and Stability. Advanced Functional Materials, 6, Arti-cle ID: 2204643.
[24]  Loffler, T., Ludwig, A., Rossmeisl, J., et al. (2021) What Makes High-Entropy Alloys Exceptional Electrocatalysts? Angewandte Chemie International Edition, 60, 26894-26903.
[25]  Li, H.D., Han, Y., Zhao, H., et al. (2020) Fast Site-to-Site Electron Transfer of High-Entropy Alloy Nanocatalyst Driving Redox Electrocatalysis. Nature Communications, 11, Article No. 5437.
[26]  Zhu, H., Zhu, Z.F., Hao, J.S., et al. (2022) High-Entropy Alloy Stabilized Active Ir for Highly Efficient Acidic Oxygen Evolution. Chemical Engineering Journal, 431, Article ID: 133251.
[27]  Jia, Z., Nomoto, K., Wang, Q., et al. (2021) A Self-Supported High-Entropy Metallic Glass with a Nanosponge Architecture for Efficient Hydrogen Evolution under Alkaline and Acidic Conditions. Advanced Functional Materials, 31, Article ID: 2101586.
[28]  Zhan, C.H., Xu, Y., Bu, L.Z., et al. (2021) Subnanometer High-Entropy Alloy Nanowires Enable Remarkable Hydrogen Oxidation Catalysis. Nature Communications, 12, Article No. 6261.
[29]  Wang, B., Yao, Y.F., Yu, X.W., et al. (2021) Under-standing the Enhanced Catalytic Activity of High Entropy Alloys: From Theory to Experiment. Journal of Materials Chemistry A, 9, 19410-19438.
[30]  Kumar Katiyar, N., Biswas, K., Yeh, J.W., et al. (2021) A Perspective on the Catalysis Using the High Entropy Alloys. Nano Energy, 88, Article ID: 106261.
[31]  Qin, J., Li, Z.Z., Leng, D.Y., et al. (2021) PtGd/Gd2O3 Al-loy/Metal Oxide Composite Catalyst for Methanol Oxidation Reaction. International Journal of Hydrogen Energy, 46, 25782-25789.
[32]  Huang, H.J., Zhu, J.X., Li, D.B., et al. (2017) Pt Nanoparticles Grown on 3D RuO2-Modified Graphene Architectures for Highly Efficient Methanol Oxidation. Journal of Materials Chemistry A, 5, 4560-4567.
[33]  Guo, D.J., Qiu, X.P., Zhu, W.T., et al. (2009) Synthesis of Sulfated ZrO2/MWCNT Composites as New Supports of Pt Catalysts for Direct Methanol Fuel Cell Application. Applied Cataly-sis B: Environmental, 89, 597-601.
[34]  Zhang, K.F., Qiu, J., Wu, J., et al. (2022) Morphological Tuning Engineering of Pt@TiO2/Graphene Catalysts with Optimal Active Surfaces of Support for Boosting Catalytic Perfor-mance for Methanol Oxidation. Journal of Materials Chemistry A, 10, 4254-4265.
[35]  Qiao, M., Wu, H., Meng, F.Y., et al. (2022) Defect-Rich, Highly Po-rous PtAg Nanoflowers with Superior Anti-Poisoning Ability for Efficient Methanol Oxidation Reaction. Small, 18, Ar-ticle ID: 2106643.
[36]  Xu, F., Cai, S.B., Lin, B.F., et al. (2022) Geometric Engineering of Porous PtCu Nanotubes with Ultrahigh Methanol Oxidation and Oxygen Reduction Capability. Small, 18, Article ID: 2107387.
[37]  Kwon, T., Jun, M., Kim, H.Y., et al. (2018) Ver-tex-Reinforced PtCuCo Ternary Nanoframes as Efficient and Stable Electrocatalysts for the Oxygen Reduction Reaction and the Methanol Oxidation Reaction. Advanced Functional Materials, 28, Article ID: 1706440.
[38]  Yuda, A., Ashok, A. and Kumar, A. (2022) A Comprehensive and Critical Review on Recent Progress in Anode Catalyst for Methanol Oxidation Reaction. Catalysis Reviews, 64, 126-228.
[39]  Sagado, J.R.C., Paganin, V.A., Gonzalez, E.R., et al. (2013) Characterization and Performance Evaluation of Pt-Ru Electrocatalysts Supported on Different Carbon Materials for Di-rect Methanol Fuel Cells. International Journal of Hydrogen Energy, 38, 910-920.
[40]  Abdel Hameed, R.M. and El-sherif, R.M. (2015) Microwave Irradiated Nickel Nanoparticles on Vulcan XC-72R Carbon Black for Methanol Oxidation Reaction in KOH Solution. Applied Catalysis B: Environmental, 162, 217-226.
[41]  Shanmugapriya, S., Kasturi, P.R., Zhu, P., et al. (2020) Hex-anedioic Acid Mediated in Situ Functionalization of Interconnected Graphitic 3D Carbon Nanofibers as Pt Support for Trifunctional Electrocatalysts. Sustainable Energy & Fuels, 4, 2808-2822.
[42]  Dum, J., Chen, B.L., Hu, Y., et al. (2018) Pt-Based Alloy Nanoparti-cles Embedded Electrospun Porous Carbon Nanofibers as Electrocatalysts for Methanol Oxidation Reaction. Journal of Alloys and Compounds, 747, 978-988.
[43]  Liu, G.Y., Bonakdarpour, A., Wang, X.D., et al. (2019) Anti-mony-Doped Tin Oxide Nanofibers as Catalyst Support Structures for the Methanol Oxidation Reaction in Direct Meth-anol Fuel Cells. Electrocatalysis, 10, 262-271.
[44]  Mu, X., Xu, Z.Q., Xie, Y.H., et al. (2017) Pt Nanoparticles Supported on Co Embedded Coal-Based Carbon Nanofiber for Enhanced Electrocatalytic Activity towards Methanol Electro-Oxidation. Journal of Alloys and Compounds, 711, 374-380.
[45]  Ding, J.J., Hu, W.L., Ma, L., et al. (2021) Facile Construction of Mesoporous Carbon Enclosed with NiCoPx Nanoparticles for Desirable Pt-Based Catalyst Support in Methanol Oxida-tion. Journal of Power Sources, 481, Article ID: 228888.
[46]  Zhang, C.W., Xu, L.B., Shan, N.N., et al. (2014) Enhanced Electrocatalytic Activity and Durability of Pt Particles Supported on Ordered Mesoporous Carbon Spheres. ACS Cataly-sis, 4, 1926-1930.
[47]  Zhang, Y.M., Liu, Y., Liu, W.H., et al. (2017) Synthesis of Honeycomb-Like Mesoporous Nitrogen-Doped Carbon Nanospheres as Pt Catalyst Supports for Methanol Oxidation in Alkaline Media. Applied Surface Science, 407, 64-71.
[48]  Yu, N.F., Shu, Z.W., Fu, G.G., et al. (2022) Den-drimer-Encapsulated PtSn Bimetallic Ultrafine Nanoparticles Supported on Graphitic Mesoporous Carbon as Efficient Electrocatalysts for Methanol Oxidation. Journal of Materials Research and Technology, 18, 1555-1565.
[49]  Zhang, X.L., Ma, J., Yan, R.W., et al. (2021) Pt-Ru/Polyaniline/Carbon Nanotube Composites with Three-Layer Tubular Structure for Efficient Methanol Oxidation. Journal of Alloys and Compounds, 867, Article ID: 159017.
[50]  Fan, J.J., Fan, Y.J., Wang, R.X., et al. (2017) A Novel Strategy for the Synthesis of Sulfur-Doped Carbon Nanotubes as a Highly Efficient Pt Catalyst Support toward the Methanol Oxidation Reaction. Journal of Materials Chemistry A, 5, 19467-19475.
[51]  Wang, Z.C., Zhou, S.Y., Liao, W., et al. (2022) Tuning Surface Com-position of Multiwalled Carbon Nanotubes Supported Pt-Co Bimetallic Nanoparticles for Boosting Methanol Oxidation Catalysis. International Journal of Hydrogen Energy, 47, 16056-16064.
[52]  Sekar, A., Metzger, N., Rajendrans, A., et al. (2022) PtRu Cat-alysts on Nitrogen-Doped Carbon Nanotubes with Conformal Hydrogenated TiO2 Shells for Methanol Oxidation. ACS Applied Nano Materials, 5, 3275-3288.


comments powered by Disqus

Contact Us


WhatsApp +8615387084133

WeChat 1538708413