全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

基于生物质碳材料的对硝基酚电化学传感器
p-Nitrophenol Electrochemical Sensor Based on Biomass Carbon Material

DOI: 10.12677/JAPC.2022.113018, PP. 159-166

Keywords: 多孔碳,电化学,传感器,对硝基酚
Porous Carbon
, Electrochemistry, Sensor, P-Nitrophenol

Full-Text   Cite this paper   Add to My Lib

Abstract:

采用焦糖爆米花制备多孔生物质碳并用于修饰玻碳电极,提出了一种对硝基酚的电化学传感器。通过对比扫速、pH等的影响,探索最佳测试条件。在1~200 μM之间对硝基酚的浓度与峰电流线性相关,检测限为0.23 μM。相对于其他一些对硝基酚的传感器,检测限稍高,性能稍差。原因可能是与爆米花本身结构有关,部分纤维素不能通过后处理清除干净,导致其电化学响应较弱。
A p-nitrophenol sensor (p-NP) was proposed by porous carbon materials (PCMPC) prepared from caramel popcorn. The optimal test conditions were investigated by comparing the effects of scanning rates, pH and so on. The lower detection limits were found to be 0.23 μM and the range of linear relationship was 1~200 μM. Compared with other p-nitrophenol sensors, its detection limit is higher and the performance is worse. It probably has something to do with the structure of the popcorn. Part of cellulose could not be cleaned by post-treatment, resulted in weak electrochemical response.

References

[1]  Saadati, F., Ghahramani, F., Shayanijam, H., Piri, F. and Yaftian, M.R. (2018) Synthesis and Characterization of Nanostructure Molecularly Imprinted Polyaniline/Graphene Oxide Composite as Highly Selective Electrochemical Sensor for Detection of p-Nitrophenol. Journal of the Taiwan Institute of Chemical Engineers, 86, 213-221.
https://doi.org/10.1016/j.jtice.2018.02.019
[2]  Ismail, M., Khan, M., Khan, S.B., Akhtar, K., Khan, M.A. and Asiri, A.M. (2018) Catalytic Reduction of Picric Acid, Nitrophenols and Organic Azo Dyes via Green Synthesized Plant Supported Ag Nanoparticles. Journal of Molecular Liquids, 268, 87-101.
https://doi.org/10.1016/j.molliq.2018.07.030
[3]  Li, X., Cui, Y.Y., Yang, C.X. and Yan, X.P. (2020) Synthesis of Carboxyl Functionalized Microporous Organic Network for Solid Phase Extraction Coupled with High-Performance Liquid Chromatography for the Determination of Phenols in Water Samples. Talanta, 208, 120434-120469.
https://doi.org/10.1016/j.talanta.2019.120434
[4]  Mine, M., Mizuguchi, H. and Takayanagi, T. (2020) Kinetic Analysis of Substrate Competition in Enzymatic Reactions with β-D-Galactosidase by Capillary Electrophoresis/Dynamic Frontal Analysis. Journal of Pharmaceutical and Biomedical Analysis, 188, 113390-113396.
https://doi.org/10.1016/j.jpba.2020.113390
[5]  Xiao, N., Liu, S.G., Mo, S., Li, N., Ju, Y.J., Ling, Y., Li, N.B. and Luo, H.Q. (2018) Highly Selective Detection of p-Nitrophenol Using Fluorescence Assay Based on Boron, Nitrogen Co-Doped Carbon Dots. Talanta, 184, 184-192.
https://doi.org/10.1016/j.talanta.2018.02.114
[6]  Xia, H., Zhang, W., Yang, Z., Dai, Z. and Yang, Y. (2021) Spectrophotometric Determination of p-Nitrophenol under ENP Interference. Journal of Analytical Methods in Chemistry, 2021, 6682722- 6682732.
https://doi.org/10.1155/2021/6682722
[7]  Zhou, Y., Zhao, J., Li, S., Guo, M. and Fan, Z. (2019) An Electrochemical Sensor for the Detection of p-Nitrophenol Based on a Cyclodextrin-Decorated Gold Nanoparticle-Mesoporous Carbon Hybrid. Analyst, 144, 4400-4406.
https://doi.org/10.1039/C9AN00722A
[8]  Chaudhary, S., Kumar, S., Kumar, S., Chaudhary, G.R., Mehta, S.K. and Umar, A. (2019) Ethylene Glycol Functionalized Gadolinium Oxide Nanoparticles as a Potential Electrochemical Sensing Platform for Hydrazine and p-Nitrophenol. Coatings, 9, 633-648.
https://doi.org/10.3390/coatings9100633
[9]  Anbumannan, V., Dinesh, M., Rajendra Kumar, R.T. and Suresh, K. (2019) Hierarchical α-MnO2 Wrapped MWCNTs Sensor for Low Level Detection of p-Nitrophenol in Water. Ceramics International, 45, 23097-23103.
https://doi.org/10.1016/j.ceramint.2019.08.002
[10]  Chen, X., Wang, X. and Fang, D. (2020) A Review on C1s XPS-Spectra for Some Kinds of Carbon Materials. Fullerenes, Nanotubes and Carbon Nanostructures, 28, 1048-1058.
https://doi.org/10.1080/1536383X.2020.1794851
[11]  Torrisi, L., Silipigni, L., Cutroneo, M. and Torrisi, A. (2020) Graphene Oxide as a Radiation Sensitive Material for XPS Dosimetry. Vacuum, 173, 109175-109183.
https://doi.org/10.1016/j.vacuum.2020.109175
[12]  Xue, J., Xiang, H., Wang, K., Zhang, X., Wang, S., Wang, X. and Cao, H. (2012) The Preparation of Carbon-Encapsulated Fe/Co Nanoparticles and Their Novel Applications as Bifunctional Catalysts to Promote the Redox Reaction for p-Nitrophenol. Journal of Materials Science, 47, 1737-1744.
https://doi.org/10.1007/s10853-011-5953-2

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133