All Title Author
Keywords Abstract

Publish in OALib Journal
ISSN: 2333-9721
APC: Only $99


Relative Articles


Research Progress of Oxygen Evolution Catalyst for Alkaline Electrolysis of Water with High Current

DOI: 10.12677/NAT.2022.123013, PP. 105-114

Keywords: 析氧反应,大电流催化剂,贵金属,非贵金属,碱性电解水
Oxygen Evolution Reaction
, High Current Catalyst, Precious Metals, Non-Precious Metals,Alkaline Electrolyzed Water

Full-Text   Cite this paper   Add to My Lib


Hydrogen production by electrolysis of water is an important method to produce hydrogen, which is crucial to the sustainable development of energy in the future. The high potential barrier of oxygen evolution reaction and the multi-electron transfer in the reaction process lead to the slow kinetic reaction rate. Loading oxygen evolution catalyst on the anode can reduce the energy consumption in the electrolysis process and improve the hydrogen production efficiency. In recent years, in order to reduce the cost of industrial hydrogen production, alkaline high-current electrolyzed water oxygen evolution catalyst has been widely concerned. Firstly, this paper introduces the principle of hydrogen production by electrolysis of water and the reaction mechanism of oxygen evolution in alkali electrolyte. Then, the research progress of as-reported alkaline high-current electrolysis of water oxygen evolution catalysts in recent years is summarized, including noble metal-based oxygen evolution catalysts and non-noble metal-based oxygen evolution catalysts. Finally, the development direction of high current oxygen evolution catalyst in the future is prospected.


[1]  李天太. “双碳目标”下传统化石能源与新能源发展趋势浅析[J]. 陕西教育(高教), 2022(3): 5-6.
[2]  孟凡, 张惠铃, 姬姗姗, 李若鹏, 徐昊, 张锦秋, 等. 高效电解水制氢发展现状与技术优化策略[J]. 黑龙江大学自然科学学报, 2021, 38(6): 702-713.
[3]  Han, L., Dong, S. and Wang, E. (2016) Transition-Metal (Co, Ni, and Fe)-Based Electrocat-alysts for the Water Oxidation Reaction. Advanced Materials, 28, 9266-9291.
[4]  陈彬, 谢和平, 刘涛, 兰铖, 林魁武, 章远. 碳中和背景下先进制氢原理与技术研究进展[J]. 工程科学与技术, 2022, 54(1): 106-116.
[5]  李子烨, 劳力云, 王谦. 制氢技术发展现状及新技术的应用进展[J]. 现代化工, 2021, 41(7): 86-89+94.
[6]  骆永伟, 朱亮, 王向飞, 唐兴昌, 赵小龙. 电解水制氢催化剂的研究与发展[J]. 金属功能材料, 2021, 28(3): 58-66.
[7]  宋兆阳, 贾立明, 白红鑫, 徐会青, 刘全杰, 杨阳. 非贵金属电解水催化剂改性研究进展[J]. 无机盐工业, 2021, 53(7): 36-43.
[8]  Li, Y., Zhou, L. and Guo, S. (2021) Noble Metal-Free Electrocatalytic Materials for Water Splitting in Alkaline Electrolyte. EnergyChem, 3, Article ID: 100053.
[9]  Zeng, M. and Li, Y. (2015) Recent Ad-vances in Heterogeneous Electrocatalysts for the Hydrogen Evolution Reaction. Journal of Materials Chemistry A, 3, 14942-14962.
[10]  Wu, D., Chen, D., Zhu, J. and Mu, S. (2021) Ultralow Ru Incorporated Amorphous Cobalt-Based Oxides for High-Cur- rent-Density Overall Water Splitting in Alkaline and Seawater Media. Small, 17, Article ID: 2102777.
[11]  Jiang, P., Huang, H., Diao, J., Gong, S., Chen, S., Lu, J., et al. (2019) Improving Electrocatalytic Activity of Iridium for Hydrogen Evolution at High Current Densities above 1000?mA?cm?2. Applied Catalysis B: Environmental, 258, Article ID: 117965.
[12]  Wu, J., Nie,Z., Xie, R., Hu, X., Yu, Y. and Yang, N. (2022) Self-Assembled Pt-CoFe Layered Double Hydroxides for Efficient Alkaline Water/Seawater Splitting by Spontaneous Redox Synthesis. Journal of Power Sources, 532, Article ID: 231353.
[13]  Wen, Q., Zhao, Y., Liu, Y., Li, H.Q. and Zhai, T.Y. (2022) Ultrahigh-Current-Density and Long-Term-Durability Electrocatalysts for Water Splitting. Small, 18, Article ID: 2104513.
[14]  Zhang, X., Li, J., Yang, Y., Zhang, S., Zhu, H., Zhu, X., et al. (2018) Co3O4/Fe0.33Co0.66P Interface Nanowire for Enhancing Water Oxidation Catalysis at High Current Density. Advanced Materials, 30, Article ID: 1803551.
[15]  Ming, G., Wang, D.Y., Chen C.C., Hwang. B.-J. and Dai, H. (2016) A Mini Review on Nickel-based Electrocatalysts for Alkaline Hydrogen Evolution Reaction. Nano Research, 9, 28-46.
[16]  Gao, M.Y., Zeng, J.R., Zhang, Q.B., Yang, C., Li, X.T., Hua, Y.X., et al. (2018) Scalable One-Step Electrochemical Deposition of Nanoporous Amorphous S-doped NiFe2O4/Ni3Fe Composite Films as Highly Efficient Electrocatalysts for Oxygen Evolution with Ultrahigh Stability. Journal of Materials Chemistry A, 6, 1551-1560.
[17]  Zhu, W., Chen, W., Yu, H., Zeng, Y., Ming, F., Liang, H., et al. (2020) NiCo/NiCo-OH and NiFe/NiFe-OH Core Shell Nanostructures for Water Splitting Electrocatalysis at Large Currents. Applied Catalysis B: Environmental, 278, Article ID: 119326.
[18]  Feng, C., Faheem, M.B., Fu, J., Xiao, Y., Li, C. and Li, Y. (2020) Fe-Based Electrocatalysts for Oxygen Evolution Reaction: Progress and Perspectives. ACS Catalysis, 10, 4019-4047.
[19]  Anantharaj, S., Kundu, S. and Noda, S. (2021) “The Fe Effect”: A Review Unveiling the Critical Roles of Fe in Enhancing OER Activity of Ni and Co Based Catalysts. Nano Energy, 80, Article ID: 105514.
[20]  Gong, M., Li, Y., Wang, H., Liang, Y., Wu, J.Z., Zhou, J., et al. (2013) An Advanced Ni-Fe Layered Double Hydroxide Electrocatalyst for Water Oxidation. Journal of the American Chemical Society, 135, 8452-8455.
[21]  Zhou, H., Yu, F., Sun, J., He, R., Chen, S., Chu, C.W., et al. (2017) Highly Active Catalyst Derived from a 3D Foam of Fe(PO3)2/Ni2P for Extremely Efficient Water Oxidation. Proceedings of the National Academy of Sciences of the United States of America, 114, 5607-5611.
[22]  Ren, J.T., Yuan, G.G., Weng, C.C., Chen, L. and Yuan, Z.Y. (2018) Uniquely Integrated Fe-doped Ni(OH)2 Nanosheets for Highly Efficient Oxygen and Hydrogen Evolution Reactions. Nanoscale, 10, 10620-10628.
[23]  Ye, Q., Li, L., Li, H., Gu, X., Han, B., Xu, X., et al. (2022) Qua-si-Parallel NiFe Layered Double Hydroxide Nanosheet Arrays for Large-Current-Density Oxygen Evolution Electroca-talysis. ChemSusChem, 15, Article ID: e202101873.
[24]  Tang, T., Jiang, W.J., Niu, S., Liu, N., Luo, H., Chen, Y.Y., et al. (2017) Electronic and Morphological Dual Modulation of Cobalt Carbonate Hydroxides by Mn Doping Toward Highly Efficient and Stable Bifunctional Electrocatalysts for Overall Water Splitting. Journal of the American Chemical Society, 139, 8320-8328.
[25]  Liu, H., Xi, C., Xin, J., Zhang, G., Zhang, S., Zhang, Z., et al. (2021) Free-Standing Nanoporous NiMnFeMo Alloy: An Efficient Non-Precious Metal Electrocatalyst for Water splitting. Chemical Engineering Journal, 404, Article ID: 126530.
[26]  Qin, C., Ye, Z., Ma, G. and Li, D. (2018) Study on the Stability of CoxM3?xO4 (M = Ni, Mn and Ce) Nanowire Array Electrodes for Electrochemical Oxygen Evolution at Large Current Densities. Journal of the Electrochemical Society, 165, A3496-A3503.
[27]  Zhang, N., Gao, Y., Mei, Y., Liu, J., Song, W. and Yu, Y. (2019) CuS-Ni3S2 Grown in Situ from Three-dimensional Porous Bimetallic Foam for Efficient Oxygen Evolution. Inorganic Chemistry Frontiers, 6, 293-302.
[28]  Liu, P., Chen, B., Liang, C., Yao, W., Cui, Y., Hu, S., et al. (2021) Tip-Enhanced Electric Field: A New Mechanism Promoting Mass Transfer in Oxygen Evolution Reactions. Advanced Materials, 33, Article ID: 2007377.
[29]  Zou, X., Liu, Y., Li, G.-D., Li, W., Li, H.-W., Wang, D., et al. (2017) Ultrafast Formation of Amorphous Bimetallic Hydroxide Films on 3D Conductive Sulfide Nanoarrays for Large-Current-Density Oxygen Evolution Electrocatalysis. Advanced Materials, 29, Article ID: 1700404.
[30]  Cheng, X., Pan, Z., Lei, C., Jin, Y., Yang, B., Li, Z., et al. (2019) A Strongly Coupled 3D Ternary Fe2O3@Ni2P/Ni- (PO3)2 Hybrid for Enhanced Electrocatalytic Oxygen Evolution at Ul-tra-High Current Densities. Journal of Materials Chemistry A, 7, 965-971.
[31]  Yan, G., Li, G., Tan, H., Gu, Y. and Li, Y. (2020) Spinel-Type Ternary Multimetal Hybrid Oxides with Porous Hierarchical Structure Grown on Ni Foam as Large-Current-Density Water Oxi-dation Electrocatalyst. Journal of Alloys and Compounds, 838, Article ID: 155662.


comments powered by Disqus

Contact Us


WhatsApp +8615387084133

WeChat 1538708413