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过氧化苯甲酰促进的双硫化物合成研究
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Abstract:
本文发展了以硫醇、硫酚类化合物为原料，过氧化苯甲酰为自由基引发剂，在无水乙醇中室温下发生自由基反应，获得了14个由硫酚、硫醚类化合物偶联的双硫化物，产率51%~99%，目标产物均为已知化合物，其结构经1H NMR确证。
The development of thiol, thiophenolic compounds as raw materials, benzoyl peroxide as an additive, free radical reaction in anhydrous ethanol at room temperature, 14 disulfides coupled with thiophenol and thioether compounds were obtained in a yield of 51%~99%, the target products are all known compounds, and the structure was confirmed by 1H NMR.
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