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含铜配合物CuL合成及湿敏性能研究
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Abstract:
本文通过氨三乙酸和乙酸铜为原料成功合成了一例含铜配合物材料(CuL),单晶衍射表明该材料为零维的单核结构。CuL分子内存在大量羧基氧原子与结晶水分子,通过氢键作用构成三维超分子网络结构。湿敏性能研究发现该配合物材料具有较好的湿度敏感特性,在湿敏传感器方面具有潜在的应用价值。
In this paper, a copper containing complex material (CuL) was successfully synthesized from ami-notriacetic acid and copper acetate. Single crystal diffraction showed that the material had a zero dimensional mononuclear structure. There are a large number of carboxyl oxygen atoms and crystalline water molecules in CuL molecule, which form a three-dimensional supramolecular network structure through hydrogen bonding. It is found that the complex material has good humidity sensitivity and has potential application value in humidity sensor.
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