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羟基(对甲苯磺酰氧基)碘苯的制备与应用
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Abstract:
羟基(对甲苯磺酰氧基)碘苯作为一种安全、有效、污染小的高价碘化合物，近年广泛应用于有机化学与药物化学的研究中。本课题组一直从事高价碘氧化剂的制备与应用研究，其中对高价碘化合物中的亚碘酰苯、二酰氧碘苯、羟基(对甲苯磺酰氧)碘苯做了大量的研究工作。本文结合自己课题组的研究成果综述了羟基(对甲苯磺酰氧基)碘苯以及衍生物的制备方法与实际应用。
Hydroxy(sulfonyloxy)iodoarenes, as a safe, effective and low-polluting hypervalent iodine compounds, have been widely used in the research of organic chemistry and medicinal chemistry in recent years. Our research group has been engaged in the preparation and application of hypervalent iodine compounds. In particular, we have done a lot of research on iodosylbenzene, bisacyloxyiodobenzenes and hydroxy(sulfonyloxy)iodoarenes in hypervalent iodine compounds. In this paper, the preparation methods and practical applications of hydroxy (p-toluenesulfonyloxy) iodobenzene and derivatives are reviewed based on the research results of our group.
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