|
钯基纳米材料的可控制备及其催化乙醇氧化研究进展
|
Abstract:
直接乙醇燃料电池(DEFCs)由于乙醇(C2H5OH)能量密度高、燃料来源广泛且价格便宜等优点,已经成为未来新能源电动汽车和便携式电源等的最佳选择之一。铂(Pt)基纳米材料是DEFCs阳极催化反应中应用最广泛的催化剂之一,但活性低、储量少等问题阻碍了其商业化应用。因此,开发非Pt基电催化剂对于DEFCs的发展起着至关重要的作用。近年来,钯(Pd)基纳米催化剂因具有与Pt相近的电子结构和晶体结构,在乙醇氧化反应(EOR)中备受关注。本文主要介绍Pd基纳米材料液相可控制备的研究进展,并基于材料的结构、形貌和组分探究其对催化乙醇氧化机制的影响。
Direct ethanol fuel cell (DEFCs) has been considered as one of the most promising energy conversion devices for new energy electric vehicles and portable power sources. This is because ethanol (C2H5OH) possesses many advantages as a fuel, including high energy density, wide fuel sources and low price. Platinum (Pt)-based nanomaterials are one of the most widely used catalysts in anodic catalytic reaction, but its low activity and reserves have hindered their commercial application. Therefore, it is critical approach to design and prepare non-Pt based electrocatalysts for the devel-opment of DEFCs. In recent years, palladium (Pd)-based electrocatalysts have attracted more atten-tion in ethanol oxidation reaction (EOR) because of its similar electronic and crystal structure with Pt. This review mainly focuses on the research progress of liquid phase controllable preparations of Pd-based nanomaterials, and the influence on the catalytic oxidation mechanism of ethanol was also investigated based on the structure, morphology and composition of the materials.
[1] | 吴志鹏, 钟传建. 钯基氧还原和乙醇氧化反应电催化剂: 关于结构和机理研究的一些近期见解[J]. 电化学, 2021, 27(2): 144-156. |
[2] | Huang, Q. (2012) Fuel Cells Challenges and New Opportunities. Sustainable Energy, 2, 89-96.
https://doi.org/10.12677/SE.2012.24015 |
[3] | Zhang, H., Cai, K., Wang, P., Huang, Z., et al. (2017) Graphene Oxide as a Stabilizer for “Clean” Synthesis of High-Performance Pd-Based Nanotubes Electrocatalysts. ACS Sustainable Chemistry & Engineering, 5, 5191-5199.
https://doi.org/10.1021/acssuschemeng.7b00544 |
[4] | Zhang, Y., Yuan, X.L., Lyu, F.L., Wang, X.C., et al. (2020) Facile One-Step Synthesis of PdPb Nanochains for High-Performance Electrocatalytic Ethanol Oxidation. Rare Metals, 39, 792-799.
https://doi.org/10.1007/s12598-020-01442-0 |
[5] | 卓业争, 徐常威. 乙醇在铂和钯电极上的电化学氧化比较[J]. 物理化学进展, 2012, 1(1): 1-5. |
[6] | Akhairi, M.A.F. and Kamarudin, S.K. (2016) Catalysts in Direct Ethanol Fuel Cell (DEFC): An Overview. International Journal of Hydrogen Energy, 41, 4214-4228. https://doi.org/10.1016/j.ijhydene.2015.12.145 |
[7] | Yu, Y., Xin, H.L., Hovden, R., Wang, D., et al. (2012) Three-Dimensional Tracking and Visualization of Hundreds of Pt-Co Fuel Cell Nanocatalysts during Electrochemical Aging. Nano Letters, 12, 4417-4423.
https://doi.org/10.1021/nl203920s |
[8] | Chen, C., Kang, Y., Huo, Z., Zhu, Z., et al. (2014) Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces. Science, 343, 1339-1343. https://doi.org/10.1126/science.1249061 |
[9] | 李贵贤, 祁建军, 王东亮, 等. 直接甲醇燃料电池阳极催化剂研究现状及展望[J]. 化学工程与技术, 2021, 11(2): 66-75. |
[10] | Chen, Q., Yang, Y., Cao, Z., Kuang, Q., et al. (2016) Excavated Cubic Platinum-Tin Alloy Nanocrystals Constructed from Ultrathin Nanosheets with Enhanced Electrocatalytic Activity. Angewandte Chemie International Edition, 55, 9021-9026. https://doi.org/10.1002/anie.201602592 |
[11] | Kim, Y., Noh, Y., Lim, E.J., Lee, S., et al. (2014) Star-Shaped Pd@Pt Core-Shell Catalysts Supported on Reduced Graphene Oxide with Superior Electrocatalytic Performance. Journal of Materials Chemistry A, 2, 6976-6986.
https://doi.org/10.1039/C4TA00070F |
[12] | Wu, Z., Gao, S., Chen, L., Jiang, D., et al. (2017) Electrically Insulated Epoxy Nanocomposites Reinforced with Synergistic Core-Shell SiO2@MWCNTs and Montmorillonite Bifillers. Macromolecular Chemistry and Physics, 218, 357-366. https://doi.org/10.1002/macp.201700357 |
[13] | Guo, F., Li, Y., Fan, B., Liu, Y., et al. (2018) Carbon- and Binder-Free Core-Shell Nanowire Arrays for Efficient Ethanol Electro-Oxidation in Alkaline Medium. ACS Applied Materials & Interfaces, 10, 4705-4714.
https://doi.org/10.1021/acsami.7b16615 |
[14] | Tan, J.L., De Jesus, A.M., Chua, S.L., Sanetuntikul, J., et al. (2017) Preparation and Characterization of Palladium-Nickel on Graphene Oxide Support as Anode Catalyst for Alkaline Direct Ethanol Fuel Cell. Applied Catalysis A: General, 531, 29-35. https://doi.org/10.1016/j.apcata.2016.11.034 |
[15] | Yin, J., Shan, S., Ng, M.S., Yang, L., et al. (2013) Catalytic and Electrocatalytic Oxidation of Ethanol over Palladium-Based Nanoalloy Catalysts. Langmuir, 29, 9249-9258. https://doi.org/10.1021/la401839m |
[16] | Kang, M., Bae, Y.S. and Lee, C.H. (2005) Effect of Heat Treatment of Activated Carbon Supports on the Loading and Activity of Pt Catalyst. Carbon, 43, 1512-1516. https://doi.org/10.1016/j.carbon.2005.01.035 |
[17] | Zhang, Q., Jiang, L., Wang, H., Liu, J., et al. (2018) Hollow Graphitized Carbon Nanocage Supported Pd Catalyst with Excellent Electrocatalytic Activity for Ethanol Oxidation. ACS Sustainable Chemistry & Engineering, 6, 7507-7514.
https://doi.org/10.1021/acssuschemeng.8b00208 |
[18] | Liu, M., Zhang, R. and Chen, W. (2014) Graphene-Supported Nanoelectrocatalysts for Fuel Cells: Synthesis, Properties, and Applications. Chemical Reviews, 114, 5117-5160. https://doi.org/10.1021/cr400523y |
[19] | Sun, X., Song, P., Zhang, Y., Liu, C., et al. (2013) A Class of High Performance Metal-Free Oxygen Reduction Electrocatalysts Based on Cheap Carbon Blacks. Scientific Reports, 3, 2505-2510. https://doi.org/10.1038/srep02505 |
[20] | Kumari, N. and Singh, R. (2016) Nanocomposites of Nitrogen-Doped Graphene and Cobalt Tungsten Oxide as Efficient Electrode Materials for Application in Electrochemical Devices. AIMS Materials Science, 3, 1456-1473.
https://doi.org/10.3934/matersci.2016.4.1456 |
[21] | Goswami, C., Hazarika, K.K. and Bharali, P. (2018) Transition Metal Oxide Nanocatalysts for Oxygen Reduction Reaction. Materials Science for Energy Technologies, 1, 117-128. https://doi.org/10.1016/j.mset.2018.06.005 |
[22] | Zhang, P., Gong, Y., Li, H., Chen, Z., et al. (2013) Solvent-Free Aerobic Oxidation of Hydrocarbons and Alcohols with Pd@N-Doped Carbon from Glucose. Nature Communications, 4, 1593-1604.
https://doi.org/10.1038/ncomms2586 |
[23] | Yao, C., Zhang, Q., Su, Y., Xu, L., et al. (2019) Palladium Nanoparticles Encapsulated into Hollow N-Doped Graphene Microspheres as Electrocatalyst for Ethanol Oxidation Reaction. ACS Applied Nano Materials, 2, 1898-1908.
https://doi.org/10.1021/acsanm.8b02294 |
[24] | Kusada, K. and Kitagawa, H. (2016) A Route for Phase Control in Metal Nanoparticles: A Potential Strategy to Create Advanced Materials. Advanced Materials, 28, 1129-1142. https://doi.org/10.1002/adma.201502881 |
[25] | Feng, Y., Bin, D., Zhang, K., Ren, F., et al. (2016) One-Step Synthesis of Nitrogen-Doped Graphene Supported PdSn Bimetallic Catalysts for Ethanol Oxidation in Alkaline Media. RSC Advances, 6, 19314-19321.
https://doi.org/10.1039/C5RA26994F |
[26] | Liu, M., Lu, Y. and Chen, W. (2013) PdAg Nanorings Supported on Graphene Nanosheets: Highly Methanol-Tolerant Cathode Electrocatalyst for Alkaline Fuel Cells. Advanced Functional Materials, 23, 1289-1296.
https://doi.org/10.1002/adfm.201202225 |
[27] | Hong, W., Wang, J. and Wang, E. (2014) Facile Synthesis of Highly Active PdAu Nanowire Networks as Self-Supported Electrocatalyst for Ethanol Electrooxidation. ACS Applied Materials & Interfaces, 6, 9481-9487.
https://doi.org/10.1021/am501859k |
[28] | Wang, D., Xin, H.L., Yu, Y., Wang, H., et al. (2010) Pt-Decorated PdCo@Pd/C Core-Shell Nanoparticles with Enhanced Stability and Electrocatalytic Activity for the Oxygen Reduction Reaction. Journal of the American Chemical Society, 132, 17664-17666. https://doi.org/10.1021/ja107874u |
[29] | Ren, F., Wang, H., Zhai, C., Zhu, M., et al. (2014) Clean Method for the Synthesis of Reduced Graphene Oxide-Supported PtPd Alloys with High Electrocatalytic Activity for Ethanol Oxidation in Alkaline Medium. ACS Applied Materials & Interfaces, 6, 3607-3614. https://doi.org/10.1021/am405846h |
[30] | Wang, A.L., He, X.J., Lu, X.F., Xu, H., et al. (2015) Palladium-Cobalt Nanotube Arrays Supported on Carbon Fiber Cloth as High-Performance Flexible Electrocatalysts for Ethanol Oxidation. Angewandte Chemie International Edition, 54, 3669-3673. https://doi.org/10.1002/anie.201410792 |
[31] | Hong, W., Wang, J. and Wang, E. (2014) Synthesis of Porous PdAg Nanoparticles with Enhanced Electrocatalytic Activity. Electrochemistry Communications, 40, 63-66. https://doi.org/10.1016/j.elecom.2013.12.026 |
[32] | Lu, Y. and Chen, W. (2010) Nanoneedle-Covered Pd-Ag Nanotubes: High Electrocatalytic Activity for Formic Acid Oxidation. The Journal of Physical Chemistry C, 114, 21190-21200. https://doi.org/10.1021/jp107768n |
[33] | Kim, K.-J., Chong, X., Kreider, P.B., Ma, G., et al. (2015) Plasmonics-Enhanced Metal-Organic Framework Nanoporous Films for Highly Sensitive Near-Infrared Absorption. Journal of Materials Chemistry C, 3, 2763-2767.
https://doi.org/10.1039/C4TC02846E |
[34] | Fu, S., Zhu, C., Du, D. and Lin, Y. (2015) Facile One-Step Synthesis of Three-Dimensional Pd-Ag Bimetallic Alloy Networks and Their Electrocatalytic Activity toward Ethanol Oxidation. ACS Applied Materials & Interfaces, 7, 13842-13848. https://doi.org/10.1021/acsami.5b01963 |
[35] | Zhao, F., Li, C., Yuan, Q., Yang, F., et al. (2019) Trimetallic Palladium-Copper-Cobalt Alloy Wavy Nanowires Improve Ethanol Electrooxidation in Alkaline Medium. Nanoscale, 11, 19448-19454.
https://doi.org/10.1039/C9NR05120A |
[36] | Lv, H., Sun, L., Zou, L., Xu, D., et al. (2019) Size-Dependent Synthesis and Catalytic Activities of Trimetallic PdAgCu Mesoporous Nanospheres in Ethanol Electrooxidation. Chemical Science, 10, 1986-1993.
https://doi.org/10.1039/C8SC04696D |
[37] | Shu, Y., Zheng, Y., Ying, Y., Yu, G., et al. (2020) Metal and Metal Oxide Interaction in Hollow CuO/Pd Catalyst Boosting Ethanol Electrooxidation. Journal of the Electrochemical Society, 167, Article ID: 064508.
https://doi.org/10.1149/1945-7111/ab7ffa |
[38] | He, H., Chen, J., Zhang, D., Li, F., et al. (2018) Modulating the Electrocatalytic Performance of Palladium with the Electronic Metal-Support Interaction: A Case Study on Oxygen Evolution Reaction. ACS Catalysis, 8, 6617-6626.
https://doi.org/10.1021/acscatal.8b00460 |
[39] | Chen, Z., Liu, Y., Liu, C., Zhang, J., et al. (2020) Engineering the Metal/Oxide Interface of Pd Nanowire@CuOx Electrocatalysts for Efficient Alcohol Oxidation Reaction. Small, 16, Article ID: 1904964.
https://doi.org/10.1002/smll.201904964 |
[40] | Li, B., Fan, H., Cheng, M., Song, Y., et al. (2018) Porous Pt-NiOxNanostructures with Ultrasmall Building Blocks and Enhanced Electrocatalytic Activity for the Ethanol Oxidation Reaction. RSC Advances, 8, 698-705.
https://doi.org/10.1039/C7RA11575J |
[41] | Li, C., Wen, H., Tang, P.P., Wen, X.P., et al. (2018) Effects of Ni(OH)2 Morphology on the Catalytic Performance of Pd/Ni(OH)2/Ni Foam Hybrid Catalyst toward Ethanol Electrooxidation. ACS Applied Energy Materials, 1, 6040-6046.
https://doi.org/10.1021/acsaem.8b01095 |
[42] | Huang, W., Ma, X.Y., Wang, H., Feng, R., et al. (2017) Promoting Effect of Ni(OH)2 on Palladium Nanocrystals Leads to Greatly Improved Operation Durability for Electrocatalytic Ethanol Oxidation in Alkaline Solution. Advanced Materials, 29, Article ID: 1703057. https://doi.org/10.1002/adma.201703057 |
[43] | Yuan, X., Zhang, Y., Cao, M., Zhou, T., et al. (2019) Bi(OH)3/PdBi Composite Nanochains as Highly Active and Durable Electrocatalysts for Ethanol Oxidation. Nano Letters, 19, 4752-4759.
https://doi.org/10.1021/acs.nanolett.9b01843 |