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基于席夫碱配体的多核过渡金属配合物的研究进展
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Abstract:
多核过渡金属配合物中存在多个中心金属原子，这些金属原子之间会相互影响相互作用，产生一些协同作用，从而表现出单核过渡金属配合物所不具备的性质，再加上结构灵活、衍生物众多与应用广泛的席夫碱作为配体，这就使得多核过渡金属配合物的应用前景十分广阔。本文首先介绍了席夫碱配体的类型以及多核过渡金属配合物的合成表征方法，然后根据不同应用方向，将文献中基于席夫碱的多核过渡金属配合物，分为催化材料、磁性材料、荧光材料及其他材料，并对其结构和性质进行综述，并探讨结构与性质间的相互关系，为多核过渡金属配合物的发展及应用奠定基础。
Polynuclear transition metal complexes containing multiple metal centers will generate interac-tions between the metal atoms, resulting in some synergy. This is the characterization of polynu-clear complexes compared to mononuclear complexes. Polynuclear transition metal complexes with Schiff- based ligands have been widely used due to the flexible structure, numerous derivatives and a wide range of application. First, the kinds of Schiff-based ligands and the synthetic characteriza-tion methods of polynuclear transition metal complexes are presented, and then according to the different applications, the Schiff-based metal transition complexes are divided into four categories: catalytic materials, magnetic materials, fluorescent materials and others. The structures and prop-erties of polynuclear transition metal complexes are described in detail, and the relationships be-tween structure and properties are explored, attempting to lay a foundation for the development and application of polynuclear transition metal complexes.
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