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量子点荧光探针技术在有机磷农药分析中应用进展
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Abstract:
有机磷农药残留进入人体内后会使人产生严重的神经功能紊乱甚至死亡，现今，有机磷农药品种繁多，也逐渐迈向超高效低残留的高效环保型的发展趋势，在环境和农产品的残留很低。因此，有必要建立高灵敏度、特异性强的检测方法以应对苛刻的检测条件。荧光检测分析法灵敏度高且具有高选择性，分析简便、仪器设备简单，在有机磷农药检测中极具应用潜力。量子点在分析领域中的应用是近些年领域研究的热点之一。因此，本文综合概述了量子点及其作为荧光探针在有机磷农药残留检测中的应用。
Organophosphorus pesticide residues in the human body will cause serious neurological disorders, sometimes leading to death. Nowadays, there are many varieties of organophosphorus pesticides, and they are gradually moving towards the development trend of ultra-efficient and low-residue high-efficiency environmental protection type, and the residues in the environment and agricultural products are very low. Therefore, it is necessary to establish a highly sensitive and specific detection method for the detection of organophosphorus pesticides. Fluorescence detection analysis has the advantages of high sensitivity and selectivity, simple analysis and simple equipment, which has great potential in the detection of organophosphorus pesticides. The application of quantum dots in the field of analysis is one of the hotspots in recent years. In this paper, application of quantum dots as fluorescent probes in the detection of organophosphorus pesticide residues was summarized.
| [1] | 屈天尧, 王德海, 吴晓波, 朱小江, 杨虹. 气相色谱法快速检测粮谷中的有机磷类、有机氮类和氨基甲酸酯类农药残留[J]. 农药科学与管理, 2009, 30(6): 36-40. |
| [2] | Zhao, F., He, J., Li, X., et al. (2020) Smart Plant-Wearable Biosensor for In-Situ Pesticide Analysis. Biosensors and Bioelectronics, 170, Article ID: 112636. https://doi.org/10.1016/j.bios.2020.112636 |
| [3] | Chen, G., Liu, G., Jia, H., et al. (2021) A Sensitive Bio-Barcode Immunoassay Based on Bimetallic Au@Pt Nanozyme for Detection of Organophosphate Pesticides in Various Agro-Products. Food Chemistry, 362, Article ID: 130118.
https://doi.org/10.1016/j.foodchem.2021.130118 |
| [4] | Zhang, C., Jiang, Z., Jin, M., et al. (2020) Fluorescence Immunoassay for Multiplex Detection of Organophosphate Pesticides in Agro-Products Based on Signal Amplification of Gold Nanoparticles and Oligonucleotides. Food Chemistry, 326, Article ID: 126813. https://doi.org/10.1016/j.foodchem.2020.126813 |
| [5] | Fernandes, V.C., Freitas, M., Oliveira, J.M., et al. (2018) Magnetic Dispersive Micro Solid-Phase Extraction and Gas Chromatography Determination of Organophosphorus Pesticides in Strawberries. Journal of Chromatography: A, 1566, 1-12. https://doi.org/10.1016/j.chroma.2018.06.045 |
| [6] | Arias, P.G., Héctor, C.A., Pichon, V., et al. (2020) Selective Solid-Phase Extraction of Organophosphorus Pesticides and Their Oxon-Derivatives from Water Samples Using Molecularly Imprinted Polymer Followed by High-Performance Liquid Chromatography with UV Detection. Journal of Chromatography: A, 1626, Article ID: 461346.
https://doi.org/10.1016/j.chroma.2020.461346 |
| [7] | Winterhalter, P., Siegert, M., Eyer, F., et al. (2018) A Toolbox for Microbore Liquid Chromatography Tandem-High-Resolution Mass Spectrometry Analysis of Albumin-Adducts as Novel Biomarkers of Organophosphorus Pesticide Poisoning. Toxicology Letters, 292, 46-54. https://doi.org/10.1016/j.toxlet.2018.04.025 |
| [8] | Nan, J.X., Wang, J., Piao, X.F., et al. (2015) Novel and Rapid Method for Determination of Organophosphorus Pesticide Residues In edible Fungus Using Direct Gas Purge Microsyringe Extraction Coupled On-Line with Gas Chromatography-Mass Spectrometry. Talanta, 142, 64-71. https://doi.org/10.1016/j.talanta.2015.04.035 |
| [9] | Cacho, J.I., Campillo, N., Vi？as, P., et al. (2018) In Situ Ionic Liquid Dispersive Liquid-Liquid Microextraction Coupled to Gas Chromatography-Mass Spectrometry for the Determination of Organophosphorus Pesticides. Journal of Chromatography: A, 1559, 95-101. https://doi.org/10.1016/j.chroma.2017.12.059 |
| [10] | Saraji, M., Jafari, M.T. and Mossaddegh, M. (2016) Carbon Nanotubes@Silicon Dioxide Nanohybrids Coating for Solid-Phase Microextraction of Organophosphorus Pesticides Followed by Gas Chromatography-Corona Discharge Ion Mobility Spectrometric Detection. Journal of Chromatography A, 1429, 30-39.
https://doi.org/10.1016/j.chroma.2015.12.008 |
| [11] | Gaviria-Arroyave, M.I., Cano, J.B. and Pe？uela, G.A. (2020) Nanomaterial-Based Fluorescent Biosensors for Monitoring Environmental Pollutants: A Critical Review. Talanta, 2, Article ID: 100006.
https://doi.org/10.1016/j.talo.2020.100006 |
| [12] | Yan, X., Li, H. and Su, X. (2018) Review of Optical Sensors for Pesticides. TrAC Trends in Analytical Chemistry, 103, 1-20. https://doi.org/10.1016/j.trac.2018.03.004 |
| [13] | 穆晋, 杨巾栏, 张大伟, 贾琼. 荧光金属纳米团簇的制备及其在环境污染物检测中的应用研究进展[J]. 分析化学, 2021, 49(3), 319-329. |
| [14] | Snee, P.T. (2020) Semiconductor Quantum Dot FRET: Untangling Energy Transfer Mechanisms in Bioanalytical Assays. TrAC Trends in Analytical Chemistry, 123, Article ID: 115750. https://doi.org/10.1016/j.trac.2019.115750 |
| [15] | Ji, X., Wang, W. and Mattoussi, H. (2016) Controlling the Spectroscopic Properties of Quantum Dots via Energy Transfer and Charge Transfer Interactions: Concepts and Applications. Nano Today, 11, 98-121.
https://doi.org/10.1016/j.nantod.2015.09.004 |
| [16] | Lim, S.Y., Shen, W. and Gao, Z. (2015) Carbon Quantum Dots and Their Applications. Chemical Society Reviews, 44, 362-381. https://doi.org/10.1039/C4CS00269E |
| [17] | Li, H., Lu, G., Su, X., et al. (2018) Carbon Dot-Based Bioplatform for Dual Colorimetric and Fluorometric Sensing of Organophosphate Pesticides. Sens. Sensors and Actuators B: Chemical, 260, 563-570.
https://doi.org/10.1016/j.snb.2017.12.170 |
| [18] | Chun, G.N., Jiang, X., Zheng, X.F., et al. (2016) Fluorescence Resonance Energy Transfer-Based Biosensor Composed of Nitrogen-Doped Carbon Dots and Gold Nanoparticles for the Highly Sensitive Detection of Organophosphorus Pesticides. Analytical Sciences, 32, 951-956. |
| [19] | Wu, X., Wang, P., Hou, S., et al. (2019) Fluorescence Sensor for Facile and Visual Detection of Organophosphorus Pesticides Using AIE Fluorogens-SiO2-MnO2 Sandwich Nanocomposites. Talanta, 198, 8-14.
https://doi.org/10.1016/j.talanta.2019.01.082 |
| [20] | Xu, X.Y., Yan, B. and Lian, X. (2018) Wearable Glove Sensor for Non-Invasive Organophosphorus Pesticide Detection Based on a Double-Signal Fluorescence Strategy. Nanoscale, 10, 13722-13729.
https://doi.org/10.1039/C8NR03352H |
| [21] | Chen, Y., Qin, X., Yuan, C., et al. (2020) Double Responsive Analysis of Carbaryl Pesticide Based on Carbon Quantum Dots and Au Nanoparticles. Dyes and Pigments, 181, Article ID: 108529.
https://doi.org/10.1016/j.dyepig.2020.108529 |
| [22] | Wei, J.C., Yang, Y., Dong, J.Y., et al. (2019) Fluorometric Determination of Pesticides and Organophosphates Using Nanoceria as a Phosphatase Mimic and an Inner Filter Effect on Carbon Nanodots. Microchimica Acta, 186, 66-75.
https://doi.org/10.1007/s00604-018-3175-x |
| [23] | Caballero-Díaz, E., Benítez-Martínez, S. and Valcarcel, M. (2017) Rapid and Simple Nanosensor by Combination of Graphene Quantum Dots and Enzymatic Inhibition Mechanisms. Sensors and Actuators B: Chemical, 240, 90-99.
https://doi.org/10.1016/j.snb.2016.08.153 |
| [24] | Wang, D., Wang, P., Liu, D., et al. (2019) Fluorometric Atrazine Assay Based on the Use of Nitrogen-Doped Graphene Quantum Dots and on Inhibition of the Activity of Tyrosinase. Microchimica Acta, 186, 527-530.
https://doi.org/10.1007/s00604-019-3648-6 |
| [25] | Sahub, C., Tuntulani, T., Nhujak, T., et al. (2018) Effective Biosensor Based on Graphene Quantum Dots via enZymatic Reaction for Directly Photoluminescence Detection of Organophosphate Pesticide. Sensors and Actuators B: Chemical, 258, 88-97. https://doi.org/10.1016/j.snb.2017.11.072 |
| [26] | Qu, Z., Li, N., Na, W., et al. (2019) A Novel Fluorescence “Turn Off-On” Nanosensor for Sensitivity Detection Acid Phosphatase and Inhibitor Based on Glutathione Functionalized Graphene Quantum Dots. Talanta, 192, 61-68.
https://doi.org/10.1016/j.talanta.2018.09.009 |
| [27] | Saberi, Z., Rezaei, B. and Ensafi, A.A. (2019) Fluorometric Label-Free Aptasensor for Detection of the Pesticide Acetamiprid by Using Cationic Carbon Dots Prepared with Cetrimonium Bromide. Microchimica Acta, 186, 273-276.
https://doi.org/10.1007/s00604-019-3378-9 |
| [28] | Wang, J., Wu, Y., Zhou, P., et al. (2018) A Novel Fluorescent Aptasensor for Ultrasensitive and Selective Detection of Acetamiprid Pesticide Based on the Inner Filter Effect between Gold Nanoparticles and Carbon Dots. Analyst, 143, 5151-5160. https://doi.org/10.1039/C8AN01166D |
| [29] | Lu, X. and Fan, Z. (2020) RecJf Exonuclease-Assisted Fluorescent Self-Assembly Aptasensor for Supersensitive Detection of Pesticides in Food. Journal of Luminescence, 226, Article ID: 117469.
https://doi.org/10.1016/j.jlumin.2020.117469 |
| [30] | Zhang, C., Lin, B., Cao, Y., et al. (2017) Fluorescence Determination of Omethoate Based on a Dual Strategy for Improving Sensitivity. Journal of Agricultural and Food Chemistry, 65, 3065-3073.
https://doi.org/10.1021/acs.jafc.7b00166 |
| [31] | Arvand, M. and Mirroshandel, A.A. (2017) Highly-Sensitive Aptasensor Based on Fluorescence Resonance Energy Transfer between L-Cysteine Capped ZnS Quantum Dots and Graphene Oxide Sheets for the Determination of Edifenphos Fungicide. Biosensors and Bioelectronics, 96, 324-331. https://doi.org/10.1016/j.bios.2017.05.028 |
| [32] | Bala, R., Swami, A., Tabujew, I., et al. (2018) Ultra-Sensitive Detection of Malathion Using Quantum Dots-Polymer Based Fluorescence Aptasensor. Biosensors and Bioelectronics, 104, 45-49. https://doi.org/10.1016/j.bios.2017.12.034 |
| [33] | Li, S., Luo, J., Yin, G., et al. (2015) Selective Determination of Dimethoate via Fluorescence Resonance Energy Transfer between Carbon Dots and a Dye-Doped Molecularly Imprinted Polymer. Sensors and Actuators B: Chemical, 206, 14-21. https://doi.org/10.1016/j.snb.2014.09.038 |
| [34] | Wu, M., Fan, Y., Li, J., et al. (2019) Vinyl Phosphate Functionalized, Magnetic, Molecularly-Imprinted Polymeric Microspheres Enrichment and Carbon Dots Fluorescence-Detection of Organophosphorus Pesticide Residues. Polymers, 11, Article ID: 1770. https://doi.org/10.3390/polym11111770 |
| [35] | Liu, Y., Cao, N., Gui, W., et al. (2018) Nitrogen-Doped Graphene Quantum Dots-Based Fluorescence Molecularly Imprinted Sensor for Thiacloprid Detection. Talanta, 183, 339-344. https://doi.org/10.1016/j.talanta.2018.01.063 |
| [36] | Khaledian, S., Noroozi-Aghideh, A., Kahrizi, D., et al. (2021) Rapid Detection of Diazinon as an Organophosphorus Poison in Real Samples Using Fluorescence Carbon Dots. Inorganic Chemistry Communications, 130, Article ID: 108676. https://doi.org/10.1016/j.inoche.2021.108676 |
| [37] | Ghosh, S., Gul, A.R., Park, C.Y., et al. (2021) Facile Synthesis of Carbon Dots from Tagetes Erecta as a Precursor for Determination of Chlorpyrifos via Fluorescence Turn-Off and Quinalphos via Fluorescence Turn-On Mechanisms. Chemosphere, 279, Article ID: 130515. https://doi.org/10.1016/j.chemosphere.2021.130515 |
| [38] | Peng, J., Yin, W., Shi, J., et al. (2019) Magnesium and Nitrogen Co-Doped Carbon Dots as Flfluorescent Probes for Quenchometric Determination of Paraoxon Using Pralidoxime as a Linker. Microchimica Acta, 186, 24-33.
https://doi.org/10.1007/s00604-018-3147-1 |
| [39] | Jimenez-Lopez, J., Llorent-Martinez, E.J., Ortega-Barrales, P., et al. (2020) Graphene Quantum Dots-Silver Nanoparticles as a Novel Sensitive and Selective Luminescence Probe for the Detection of Glyphosate in Food Samples. Talanta, 207, Article ID: 120344. https://doi.org/10.1016/j.talanta.2019.120344 |
| [40] | Shahdost-fard, F., Fahimi-Kashani, N. and Hormozi-nezhad, M.R. (2021) A Ratiometric Fluorescence Nanoprobe Using CdTe QDs for Fast Detection of Carbaryl Insecticide in Apple. Talanta, 221, Article ID: 121467.
https://doi.org/10.1016/j.talanta.2020.121467. |
