|
|
基于红薯基活性炭的电化学性能研究以及充放电特性模拟
|
Abstract:
基于红薯基制备活性炭，组装成超级电容器并借助电化学工作站对其电化学性能进行了测试，结果表明红薯基超级电容器的比电容可达237F/g。通过改进的高阶RC电路超级电容器模型，对其恒定电流充放电特性进行模拟，结果表明该模型能够精确描述恒流充放电过程中电压随时间的变化，总体来说具有较强的实用性。
Based on the activated carbon prepared from sweet potato, the supercapacitor was assembled and its electrochemical performance was tested by electrochemical workstation. The results show that the specific capacitance of the supercapacitor can reach 237F/g. By improving the supercapacitor model of high-order RC circuit, the constant current charging and discharging characteristics are simulated. The results show that the model can accurately describe the change of voltage with time in the process of constant current charging and discharging, and has strong practicability in general.
| [1] | 范壮军. 超级电容器概述[J]. 物理化学学报, 2020, 36(2): 97-99. |
| [2] | 刘春娜. 超级电容器应用展望[J]. 电源技术, 2010(9): 979-980. |
| [3] | 董小妹. 生物质碳作为超级电容器电极材料的研究进展[J]. 辽宁化工, 2017, 46(6): 603-605. |
| [4] | Spyker, R.L. and Nelms, R.M. (2000) Classical Equivalent Circuit Parameters for a Double-Layer Capac-itor. IEEE Transactions on Aerospace and Electronic Systems, 36, 829-836. https://doi.org/10.1109/7.869502 |
| [5] | Zubieta, L. and Bonert, R. (2000) Characterization of Double-Layer Capaci-tors for Power Electronics Applications. IEEE Transactions on Industry Applications, 36, 199-205. https://doi.org/10.1109/28.821816 |
| [6] | Bohlen, O., Kowal, J. and Sauer, D.U. (2007) Ageing Behaviour of Electrochemical Double Layer Capacitors: Part I. Experimental Study and Ageing Model. Journal of Power Sources, 172, 468-475.
https://doi.org/10.1016/j.jpowsour.2007.07.021 |
| [7] | 赵洋, 梁海泉, 张逸成. 电化学超级电容器建模研究现状与展望[J]. 电工技术学报, 2012, 27(3): 188-194. |
| [8] | Marie-Francoise, J.N. Gualous, H. and Berthon, A. (2006) Supercapacitor Thermal- and Electrical-Behaviour Modeling Using ANN. IEE Proceedings of the Electric Power Applications, 153, 255-262.
https://doi.org/10.1049/ip-epa:20050096 |
| [9] | Farsi, H. and Gobal, F. (2007) Artificial Neural Network Simulator for Supercapacitor Performance Prediction. Computational Materials Science, 39, 678-683. https://doi.org/10.1016/j.commatsci.2006.08.024 |
| [10] | 盖晓东, 杨世彦, 雷磊, 等. 改进的超级电容建模方法及应用[J]. 北京航空航天大学学报, 2010, 36(2): 172-175. |
