The objective of this study was to evaluate the effect of blends of
different oxygenated additives on gasoline in SI engine Otto cycle. The
formulations analyzed were: pure gasoline (type A), common gasoline (type C),
gasoline type A + 15% (v/v) oxygenated additives (ethanol, ethyl octanoate,
ethyl oleate). The experiments were performed using engine Branco 4-stroke and
2-cylinder, electric dynamometer, exhaust system, control unit composed of
Multi-K unit, variable selector and load cell, stroboscope tachometer, fuel
supply system and stopwatch. The rotation was conserved at 4400 rpm and wheel
power varied from 3 kW to 12 kW, with intervals of 3 kW to obtain hourly
consumption curves and brake specific fuel consumption. Even esters and ethanol
having lower heat of combustion, hourly consumption was similar to pure
gasoline (type A). In relation to the brake specific fuel consumption,
increasing the wheel power had a better conversion of the mass of fuel burned
into energy. Thus, this study showed that the mixture of gasoline and esters
(ethyl octanoate and ethyl oleate) presented good efficiency in terms of
consumption. This research contributes to the needs and to the current studies in which industries started to add renewable
products to petroleum-derived fuels; in order to obtain more sustainable
fuels at lower costs.
References
[1]
IEA (2014) Key World Energy Statistics. Internacional Energy Agency. https://www.oecd-ilibrary.org/energy/key-world-energy-statistics-2014_key_energ_stat-2014-en;jsessionid=UyE0R76K7HOCxMUkQY-L_-Hf.ip-10-240-5-49
[2]
Szklo, A.S., Uller, V.C. and Bonfá, M.H.P. (2012) Fundamentos do refino de petróleo: Tecnologia e economia. Interciência, Rio de Janeiro.
[3]
Cardoso, L.C. (2012) Petróleo: do poço ao posto. Qualitymark Editora, Rio de Janeiro.
[4]
Lob, A., Buenafe, R. and Nurredin, M.A. (1998) Determination of Oxygenates in Gasoline by FTIR. Fuel, 77, 1861-1864. https://doi.org/10.1016/S0016-2361(98)00103-3
[5]
Menezes, E.W., Cataluña, R., Samios, D. and Silva, R. (2006) Addition of an Azeotropic ETBE/Ethanol Mixture in Eurosuper-Type Gasolines. Fuel, 85, 2567-2577. https://doi.org/10.1016/j.fuel.2006.04.014
[6]
MAPA (2015) Ministério da Agricultura, Pecuária e Abastecimento. Diário Oficial da União, Portaria N. 75, 05 de março de 2015, Brasil.
[7]
Canakci, M., Ozsezen, N.A., Alptekin, E. and Eyidogan, M. (2013) Impact of Alcoholegasoline Fuel Blends on the Exhaust Emission of an SI Engine. Renewable Energy, 52, 111-117. https://doi.org/10.1016/j.renene.2012.09.062
[8]
Clark, C.R., Dutcher, J.S., McClellan, R.O., Naman, T.M. and Seizinger, D.E. (1983) Influence of Ethanol and Methanol Gasoline Blends on the Mutagenicity of Particulate Exhaust Extracts. Archives of Environmental Contamination and Toxicology, 12, 311-317. https://doi.org/10.1007/BF01059408
[9]
Koç, M., Sekmen, Y., Topgül, T. and Yücesu, H.S. (2009) The Effects of Ethanol-Unleaded Gasoline Blends on Engine Performance and Exhaust Emissions in a Sparkignition Engine. Renewable Energy, 34, 2101-2106. https://doi.org/10.1016/j.renene.2009.01.018
[10]
Rovai, F.F. (2005) Desgaste e corrosão de bombas de combustível com misturas de álcool e gasohol. Master Thesis, Escola Politécnica da Universidade de São Paulo, São Paulo.
[11]
Li, D.G., Zhen, H., Lŭ, X.C., Zhang, W.-G. and Yang, J.-G. (2005) Physico-Chemical Properties of Ethanol-Diesel Blend Fuel and Its Effect on Performance and Emissions of Diesel Engines. Renewable Energy, 30, 967-976. https://doi.org/10.1016/j.renene.2004.07.010
[12]
Sena, S.R.C., Barros Neto, E.L. and Pereira, C.G. (2019) Effect of Ethyl Octanoate and Ethyl Oleate on the Properties of Gasoline Fuel Mixture. Energy Fuels, 33, 9429-9436. https://doi.org/10.1021/acs.energyfuels.9b01282
[13]
Sena, S.R.C., Barros Neto, E.L., Pereira, C.G. (2019) Evaluation of the Lubrication of Ethyl Oleate and Ethyl Octanoate as Gasoline Additive. Brazilian Journal of Petroleum and Gas, 13, 111-118. https://doi.org/10.5419/bjpg2019-0011
[14]
Nicolau, A., Mariath, R.M., Martini, E.A., Martini, D.S. and Samios, D. (2010) The Polymerization Products of Epoxidized Oleic Acid and Epoxidized Methyl Oleate with cis-1,2-cyclohexanedicarboxylic Anhydride and Triethylamine as the Initiator: Chemical Structures, Thermal and Electrical Properties. Materials Science and Engineering, 30, 951-962. https://doi.org/10.1016/j.msec.2010.04.014
[15]
Vogel, A.I. (1986) Química Orgânica. Editora da Universidade de São Paulo, São Paulo.
[16]
Branco. Manual de instruções. Motor B4T-20.0 H. https://www.branco.com.br/la/pt_br/suporte/manuais.html
[17]
Fernandes, M.R. (2011) Formulação de novos combustíveis base diesel: Avaliação de desempenho e emissões. Ph.D. Thesis, Universidade Federal do Rio Grande do Norte, Natal.
[18]
Uchôa, I.M.A. (2015) Combustíveis base diesel microemulsionados com glicerina: formulação e avaliação de desempenho. Master Thesis, Universidade Federal do Rio Grande do Norte, Natal.
[19]
Dantas Neto, A.A., Fernandes, M.R., Barros Neto, E.L., Castro Dantas, T.N. and Moura, M.C.P.A. (2011) Alternative Fuels Composed by Blends of Nonionic Surfactant with Diesel and Water: Engine Performance and Emissions. Brazilian Journal of Chemical Engineering, 28, 521-531. https://doi.org/10.1590/S0104-66322011000300017
[20]
Wang, S.Y., Wang, Z., Liu, M.M., Xu, Y., Zhang, X.J. and Chen, G.Q. (2010) Properties of a New Gasoline Oxygenate Blend Component: 3-Hydroxybutyrate Methyl ester Produced from Bacterial Poly-3-Hydroxybutyrate. Biomass and Bioenergy, 34, 1216-1222. https://doi.org/10.1016/j.biombioe.2010.03.020
[21]
Jenkins, R.W., Munro, M., Nash, S. and Chuck, C. J. (2013) Potential Renewable Oxygenated Biofuels for the Aviation and Road Transport Sectors. Fuel, 103, 593-599. https://doi.org/10.1016/j.fuel.2012.08.019
[22]
Pelaez-Samaniego, M.R., Mesa-Pérez, J., Cortez, L.A.B., Rocha, J.D., Sanchez, C.G. and Marín, H. (2011) Use of Blends of Gasoline with Biomass Pyrolysis-Oil Derived Fractions as Fuels in an Otto Engine. Energy for Sustainable Development, 15, 376-381. https://doi.org/10.1016/j.esd.2011.06.001