Characterization of AAm/4-Styrenesulfonic Acid Sodium Salt/PEG Hydrogels Crosslinked by PEGDA as Highly Swollen Adsorbents for the Effective Removal of Janus Green B from Aqueous Solutions
In this study, it has been investigated that the
incorporation of poly(ethylene glycol) and
4-styrenesulfonic acid sodium salt into acrylamide hydrogel during free radical
solution polymerization synthesis for novel highly swollen adsorbents and for
the effective removal of some potential pollutants from aqueous solutions such
as cationic dyes. Poly(ethylene glycol)diacrylate was used as a multifunctional
crosslinker. The main purpose of this study was to combine both monomers and a
polymer in a new polymeric system. Dye sorption properties of the polymeric
hydrogels were investigated by using cationic dye such as Janus Green B.
Swelling and sorption studies were carried out at 25°C. For structural characterization, FT-IR analysis and SEM studies were
applied. To determine the sorption behaviors of Janus Green B, some sorption parameters such as dye removal
capacity, adsorption percentage,and partition coefficient of the polymeric hydrogels
were investigated.
References
[1]
Hassan, T., Salam, A., Khan, A., Khan, S.U., Khanzada, H., Wasim, M., Khan, M.O. and Kim, I.S. (2021) Functional Nanocomposites and Their Potential Applications: A Review. Journal of Polymer Research, 28, 36. https://doi.org/10.1007/s10965-021-02408-1
[2]
Jaspal, D. and Malviya, A. (2020) Composites for Wastewater Purification: A Review. Chemosphere, 246, Article ID: 125788. https://doi.org/10.1016/j.chemosphere.2019.125788
[3]
Karadağ, E., Öztürk, Z.D.K., Üzüm, Ö.B. and Kundakcı, S. (2019) Swelling Performance Studies of Acrylamide/Potassium 3-Sulfopropyl Methacrylate/Sodium Alginate/Bentonite Biohybrid Sorbent Hydrogels in Binary Mixtures of Water-Solvent. Journal of Encapsulation and Adsorption Sciences, 9, 35-61. https://doi.org/10.4236/jeas.2019.91003
[4]
Akharame, M.O., Fatoki, O.S., Opeolu, B.O., Olorunfemi, D.I. and Oputu, O.U. (2018) Polymeric Nanocomposites (PNCs) for Wastewater Remediation: An Overview. Polymer-Plastics Technology and Engineering, 57, 1801-1827. https://doi.org/10.1080/03602559.2018.1434666
[5]
Urbano, B. and Rivas, B.L. (2011) Poly(sodium 4-styrene sulfonate) and Poly(2-acrylamidoglycolic acid) Nanocomposite Hydrogels: Montmorillonite Effect on Water Absorption, Thermal, and Rheological Properties. Polymer Bulletin, 67, 1823-1836. https://doi.org/10.1007/s00289-011-0511-2
[6]
Kundakcı, S., Öğüt, H.G., Üzüm, Ö.B. and Karadağ, E. (2011) Equilibrium Swelling Characterization and Dye Uptake Studies of Acrylamide-co-methylenesuccinic Acid Hydrogels and Semi-IPN’s with PEG. Polymer-Plastics Technology and Engineering, 50, 947-956. https://doi.org/10.1080/03602559.2011.553862
[7]
Mohan, Y.M., Sudhakar, K., Murty, K.P.S. and Raju, K.M. (2006) Swelling Properties of Chemically Crosslinked Poly(acrylamide-co-maleic acid) Hydrogels. International Journal of Polymeric Materials, 55, 513-536. https://doi.org/10.1080/00914030500208246
[8]
Şahiner, N., Godbey, W.T., McPerson, G.L. and John, V.T. (2006) Microgel, Nanogel and Hydrogel-Hydrogel Semi-IPN Composites for Biomedical Applications: Synthesis and Characterization. Colloid and Polymer Science, 284, 1121-1129. https://doi.org/10.1007/s00396-006-1489-4
[9]
Kosmala, J.D., Henthorn, D.B. and Brannon-Peppas, L. (2000) Preparation of Interpenetrating Network of Gelatin and Dextran as Degradable Biomaterials. Biomaterials, 21, 2019-2023. https://doi.org/10.1016/S0142-9612(00)00057-0
[10]
Şahiner, N. (2007) Colloidal Nanocomposite Hydrogel Particles. Colloid and Polymer Science, 285, 413-421. https://doi.org/10.1007/s00396-006-1583-7
[11]
Sperling, L.H. (1994) Interpenetrating Polymer Networks: An Overwiew. Advances in Chemistry, American Chemical Society, Washington DC, 1-37. https://doi.org/10.1021/ba-1994-0239.ch001
[12]
Üzüm, Ö.B. and Karadağ, E. (2010) Equilibrium Swelling Studies of Chemically Crosslinked Highly Swollen Acrylamide-Sodium Acrylate Hydrogels in Various Water-Solvent Mixtures. Polymer-Plastics Technology and Engineering, 49, 609-616. https://doi.org/10.1080/03602551003664537
[13]
Üzüm, Ö.B., Kundakcı, S. and Karadağ, E. (2009) Equilibrium Swelling Studies of Highly Swollen Acrylamide/Thiosinamine Hydrogels. Polymer-Plastics Technology and Engineering, 48, 152-157. https://doi.org/10.1080/03602550802577338
[14]
Wang, Y., Zeng, Li., Ren, X., Song, H. and Wang, A. (2010) Removal of Methyl Violet from Aqueous Solutions Using Poly(acrylic acid-co-acrylamide)/Attapulgite Composite. Journal of Environmental Sciences, 22, 7-14. https://doi.org/10.1016/S1001-0742(09)60068-1
[15]
Üzüm, Ö.B. and Karadağ, E. (2006) Synthetic Polymeric Absorbent for Dye Based on Chemically Crosslinked Acrylamide/Mesaconic Acid Hydrogels. Journal of Applied Polymer Science, 101, 405-413. https://doi.org/10.1002/app.22248
[16]
Li, W., Zhao, H., Teasdale, P.R., John, R. and Zhang, S. (2002) Synthesis and Characterisation of a Polyacrylamide-Polyacrylic Acid Copolymer Hydrogel for Environmental Analysis of Cu and Cd. Reactive & Functional Polymers, 52, 31-41. https://doi.org/10.1016/S1381-5148(02)00055-X
[17]
İnam, R., Çaykara, T. and Kantoğlu, Ö. (2003) Polarographic Determination of Uranyl Adsorption onto Poly(acrylamide-g-ethylenediaminetetraacetic acid) Hydrogels in the Presence of Cadmium and Lead. Nuclear Instruments and Methods in Physics Research Section B, 208, 400-404. https://doi.org/10.1016/S0168-583X(03)01110-8
[18]
Rivas, B.L. and Munoz, C. (2009) Synthesis and Metal Ion Adsorption Properties of Poly(4-sodium styrene sulfonate-co-acrylic acid). Journal of Applied Polymer Science, 114, 1587-1592. https://doi.org/10.1002/app.30722
[19]
Karadağ, E., Kundakcı, S. and Üzüm, Ö.B. (2009) Water Sorption and Dye Uptake Studies of Highly Swollen AAm/AMPS Hydrogels and Semi-IPN’s with PEG. Polymer-Plastics Technology and Engineering, 48, 1217-1229. https://doi.org/10.1080/03602550903159044
[20]
Krsko, P. and Libera, M. (2005) Biointeractive Hydrogels. Materials Today, 8, 36-44. https://doi.org/10.1016/S1369-7021(05)71223-2
[21]
Serra, L., Domenech, J. and Peppas, N.A. (2006) Design of Poly(ethylene glycol)-Tethered Copolymers as Novel Mucoadhesive Drug Delivery Systems. European Journal of Pharmaceutics and Biopharmaceutics, 63, 11-18. https://doi.org/10.1016/j.ejpb.2005.10.011
[22]
Üzüm, Ö.B. and Karadağ, E. (2011) Dye Sorption and Water Uptake Properties of Crosslinked Acrylamide/Sodium Methacrylate Copolymers and Semi-Interpenetrating Polymer Networks Composed of PEG. Separation Science and Technology, 46, 489-499. https://doi.org/10.1080/01496395.2010.513697
[23]
Skoog, D.A. and Leary, J.J. (1992) Principles of Instrumental Analysis. Saunders College Publishing, Philadelphia, 279.
[24]
Lee, S.J., Kim, S.S. and Lee, Y.M. (2000) Interpenetrating Polymer Network Hydrogels Based an Poly(ethylene glycol) Macromer and Chitosan. Carbohydrate Polymers, 41, 197-205. https://doi.org/10.1016/S0144-8617(99)00088-0
[25]
Kim, S.J., Park, S.J. and Kim, S.I. (2003) Synthesis and Characterization of Interpenetrating Polymer Network Hydrogels Composed of Poly(vinyl alcohol) and Poly(Nisopropylacrylamide). Reactive & Functional Polymers, 55, 61-67. https://doi.org/10.1016/S1381-5148(02)00215-8
[26]
Azizian, S. (2004) Kinetic Models of Sorption: A Theoretical Analysis. Journal of Colloid and Interface Science, 276, 47-52. https://doi.org/10.1016/j.jcis.2004.03.048
[27]
Saraydin, D., Karadağ, E., Işıkver, Y., Şahiner, N. and Güven, O. (2004) The Influence of Preparation Methods on the Swelling and Network Properties of Acrylamide Hydrogels with Crosslinkers. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 41, 421-433. https://doi.org/10.1081/MA-120028476
[28]
Peppas, N.A. and Franson, N.M. (1983) The Swelling Interface Number as a Criterion for Prediction of Diffusional Solute Release Mechanisms in Swellable Polymers. Journal of Polymer Science, 21, 983-997. https://doi.org/10.1002/pol.1983.180210614
[29]
Am Ende, M.T. and Peppas, N.A. (1997) Transport of Ionizable Drugs and Proteins in Crosslinked Poly(acrylic acid) and Poly(acrylic acid-co-2-hydroxyethyl methacrylate) Hydrogels. II. Diffusion and Release Studies. Journal of Controlled Release, 48, 47-56. https://doi.org/10.1016/S0168-3659(97)00032-1
[30]
Dengre, R., Bajpai, M. and Bajpai, S.K. (2000) Release of Vitamin B12 from Poly(N-vinyl-2-pyrrolidione)-crosslinked Polyacrylamide Hydrogels. Journal of Applied Polymer Science, 76, 1706-1714. https://doi.org/10.1002/(SICI)1097-4628(20000613)76:11<1706::AID-APP12>3.0.CO;2-W
[31]
Çaykara, T., Kiper, S. and Demirel, G. (2006) Thermosensitive Poly(Nisopropilacrylamide-co-acrylamide) Hydrogels: Synthesis, Swelling and Interaction with Ionic Surfactants. European Polymer Journal, 42, 348-355. https://doi.org/10.1016/j.eurpolymj.2005.07.006
[32]
Schwarte, L.M. and Peppas, N.A. (1998) Novel Poly(ethylene glycol)-Grafted Cationic Hydrogels: Preparation, Characterization and Diffusive Properties. Polymer, 39, 6057-6066. https://doi.org/10.1016/S0032-3861(98)00087-1
[33]
Şahiner, N., Saraydın, D., Karadağ, E. and Güven, O. (1998) Swelling and Dye Adsorption Properties of Radiation Induced N-vinyl-2-pyrrolidone/Acrylonitrile Hydrogels. Polymer Bulletin, 41, 371-378. https://doi.org/10.1007/s002890050376
