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-  2018 

Extraordinary Porous Few-Layer Carbons of High Capacitance from Pechini Combustion of Magnesium Nitrate Gel

DOI: https://doi.org/10.1021/acsami.7b11042

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Abstract:

Highly capacitive carbons are viewed as promising commercial materials for supercapacitors, but few species satisfy the requirements of high capacitance and low cost. Here, we demonstrate an extraordinary porous few-layer carbon by facile Pechini combustion of magnesium nitrate gel, which combined salicylic acid as a complexing agent with magnesium nitrate as an inorganic metal salt. The as-synthesized carbon material delivers a capacitance of 415 F g–1, mostly stemming from a large specific surface area (~1312 m2 g–1), a fluent channel for transport of the electrolyte, as well as electrochemical redox reactions at O,N-associated active sites. Such porous few-layer carbons may accelerate the adoption of carbon-based supercapacitors for commercial high-power energy storage applications

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