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-  2019 

Redox-Neutral ortho Functionalization of Aryl Boroxines via Palladium/Norbornene Cooperative Catalysis

DOI: https://doi.org/10.1016/j.chempr.2019.02.005

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Abstract:

? First redox-neutral direct ortho functionalization of aryl boroxines ? Proton as the second electrophile coupled at the ipso position ? Avoiding stoichiometric bases in the Pd/NBE catalysis ? Orthogonal chemoselectivity between aryl iodide and boroxine moietie

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