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-  2019 

Boosting Aqueous Batteries by Conversion-Intercalation Graphite Cathode Chemistry

DOI: https://doi.org/10.1016/j.joule.2019.04.007

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Abstract:

In their recent publication in Nature, Kang Xu, Chunsheng Wang, and co-authors reported for the first time on a novel halogen conversion-intercalation graphite cathode chemistry for the development of high-energy aqueous batteries. As evidenced by experimental works and modeling, a densely packed stage-1 graphite intercalation compound (GIC) with a stoichiometry of C 3.5[Br 0.5Cl 0.5] is reversibly formed in a water-in-bisalt (WiBS) electrolyte, enabling an outstandingly high specific cathode capacity of 243 mAh g ?1 at an average potential of 4.2 V versus Li/Li +

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