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- 2018
复合型防老剂对树脂级低顺式聚丁二烯橡胶性能的影响Keywords: [防老剂,低顺式聚丁二烯橡胶,氧化诱导期,微凝胶含量,耐热氧老化性能, 防老剂,低顺式聚丁二烯橡胶,氧化诱导期,微凝胶含量,耐热氧老化性能,antioxidant,low cis-1,4-polybutadiene rubber,oxidative induction period,microgel content,thermal oxidative aging resistance] Abstract: 研究9种防老剂单用和并用对树脂级低顺式聚丁二烯橡胶(LCBR)性能的影响。结果表明:在9种防老剂中,单独使用防老剂1010、防老剂1520和西尼尔6308的防老化效果较好;复合使用防老剂时,防老剂1010/TNPP和防老剂1520/TNPP并用体系的防老化效果较好;当防老剂1010/TNPP并用比为80/20或防老剂1520/TNPP并用比为70/30时,LCBR的耐热氧老化性能最佳;防老剂1010/TNPP和防老剂1520/TNPP并用体系均能提高改性树脂HIPS和ABS的物理性能。;Effects of single and combination use of nine kinds of antioxidants on the properties of low cis-1,4-polybutadiene rubber(LCBR)were investigated. The results showed that,in the nine kinds of antioxidants,the anti-aging effects of antioxidant 1010,1520 and 6308 were good when being used alone,and the anti-aging effects of the antioxidant 1010/TNPP and antioxidant 1520/TNPP systems were good when being used in combination. When the blending ratios of antioxidant 1010/TNPP and antioxidant 1520/TNPP were 80/20 and 70/30,respectively,the thermal oxidative aging property of LCBR was the best. Antioxidant 1010/TNPP and antioxidant 1520/TNPP systems could improve the physical properties of HIPS and ABS modification resins
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