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- 2017
原位自由基聚合法氧化石墨烯接枝聚氨酯的制备及其对EVA的改性研究Keywords: [原位自由基聚合,氧化石墨烯,聚氨酯,乙烯-醋酸乙烯无规共聚物,表面接枝,改性, 原位自由基聚合,氧化石墨烯,聚氨酯,乙烯-醋酸乙烯无规共聚物,表面接枝,改性,in-situ radical polymerization,graphene oxide,polyurethane,ethylene vinyl acetate,surface grafting,modification] Abstract: 采用硅烷偶联剂KH570功能化氧化石墨烯(GO),再通过原位自由基聚合法在GO表面接枝聚氨酯(PU),得到GO接枝PU(GO-g-PU)复合纳米片,以其对乙烯-醋酸乙烯无规共聚物(EVA)进行改性。结果表明:GO-g-PU复合纳米片能均匀分散在EVA基体中,GO-g-PU/EVA纳米复合材料的物理性能与热稳定性能均优于EVA和GO/EVA复合材料。;Polyurethane(PU) was grafted onto the surfaces of graphene oxide(GO) which was functionalized by a silane coupling agent KH570 via in-situ radical polymerization,the synthesized products GO-g-PU composited nanosheets were used to modify ethylene vinyl acetate(EVA).The results showed that GO-g-PU composited nanosheets could uniformly disperse in the EVA matrix,the physical properties and thermal stability of GO-g-PU/EVA composites were superior to those of EVA and GO/EVA composites
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