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OALib Journal期刊
ISSN: 2333-9721
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-  2016 

纳米复合粒子GO-g-PS改性SBS复合材料性能的研究

Keywords: [氧化石墨烯,聚苯乙烯,苯乙烯-丁二烯-苯乙烯嵌段共聚物,接枝改性,热稳定性,动态力学性能, 氧化石墨烯,聚苯乙烯,苯乙烯-丁二烯-苯乙烯嵌段共聚物,接枝改性,热稳定性,动态力学性能,graphene oxide,polystyrene,SBS,grafting modification,thermal stability,dynamic me-chanical property]

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Abstract:

通过原位自由基聚合法在氧化石墨烯(GO)表面接枝聚苯乙烯(PS),制备纳米复合粒子GO-g-PS,并以此对苯乙烯-丁二烯-苯乙烯三嵌段共聚物(SBS)进行改性,研究其对SBS物理性能、热稳定性和动态力学性能的影响。结果表明:PS成功接枝到GO表面,生成GO-g-PS;当GO-g-PS质量分数为0.03时,GO-g-PS改性SBS复合材料的拉伸强度和拉断伸长率较高;与SBS和GO改性SBS复合材料相比,GO-g-PS改性SBS复合材料的物理性能、热稳定性和高温峰玻璃化温度均提高。;GO-g-PS nanoparticles were prepared by grafting polystyrene(PS)onto the surface of graphene oxide(GO) by in-situ free radical polymerization,and the obtained GO-g-PS nanoparticle was applied to modify styrene-butadiene-styrene block copolymer(SBS).The physical properties,thermal stability and dynamic mechanical properties of GO-g-PS modified SBS composites were investigated.The results showed that PS was grafted onto the surface of GO.When the mass fraction of GO-g-PS was 0.03,the tensile strength and elongation at break of GO-g-PS modified SBS composites were higher.Compared with SBS and GO modified SBS composites,the physical properties,thermal stability and glass transition temperature in the high temperature region of GO-g-PS modified SBS composites were improved

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