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Photocatalytic and Antimicrobial Properties of [AgTiO2]:[Clay] Nanocomposite Prepared with Clay Different Ratios

DOI: 10.4236/mrc.2020.94004, PP. 47-61

Keywords: Photocatalysis, Antimicrobial Activity, Organic Pollutant, Clay, Wastewater

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Abstract:

This work aimed to synthesis a novel material that would be able to efficiently remove both organic and microbiological pollutants from wastewater. Through the hydrothermal process, we first doped titanium dioxide, a semiconductor possessing excellent photocatalytic properties with silver nanoparticles having good antibacterial properties. The obtained material was then associated with clay known for its good adsorbent properties to form [AgTiO2]:[clay] type nanocomposites. The different mass composition of [AgTiO2]:[clay] considered in this work were 1:1; 1:0.5; 1:0.1; 1:0.05 and 1:0.01. The prepared nanocomposites were characterized by means of XRD, FTIR and SEM techniques. Results revealed the presence of TiO2 anatase and Ag on the surface of the clay mainly composed of kaolinite and quartz. The photocatalytic activities of the nanocomposites were tested in the presence of synthetic Orange II (25 mg/L) wastewater under visible light irradiation. The experiments demonstrated that organic pollutants were effectively photodegraded when the proportion of clay in the mixture (AgTiO2)-(Clay) was inferior or equaled to 50%. The use of commercial TiO2, for comparison purpose, showed a lower degradation efficiency of the Orange II solution (η < 30%). The antibacterial properties of the nanocomposites [AgTiO2]:[clay] were also assessed in the presence of two types of bacteria E. coli (Gram negative) and S. aureus (Gram positive). The antibacterial activities of the nanocomposites were characterized with and without UV irradiation. In dark conditions, the antibacterial activities of nanocomposites (AgTiO2)-(Clay) against S. aureus gradually increased with increasing the clay amount. Under visible light irradiation, the nanocomposites showed a significant antimicrobial activity against E. coli and S. aureus.

References

[1]  Ajakaye, O.G. and Ibukunoluwa, M.R. (2019) Prevalence and Risk of Malaria, Anemia and Malnutrition among Children in IDPs Camp in Edo State, Nigeria. Parasite Epidemiology and Control, 8, e00127.
https://doi.org/10.1016/j.parepi.2019.e00127
[2]  Mathur, P. and Singh, S. (2013) Multidrug Resistance in Bacteria: A Serious Patient Safety Challenge for India. Journal of Laboratory Physicians, 5, 5-10.
https://doi.org/10.4103/0974-2727.115898
[3]  Sedighi, M., Vaez, H., Moghoofeie, M., Hadifar, S., Oryan, G. and Faghri, J. (2015) Molecular Detection of Metallo-β-Lactamase Gene blaVIM-1 in Imipenem-Resistant Pseudomonas aeruginosa Strains Isolated from Hospitalized Patients in the Hospitals of Isfahan. Advanced Biomedical Research, 4, 57.
https://doi.org/10.4103/2277-9175.151872
[4]  Rai, M., Yadav, A. and Gade, A. (2009) Silver Nanoparticles as a New Generation of Antimicrobials. Biotechnology Advances, 27, 76-83.
https://doi.org/10.1016/j.biotechadv.2008.09.002
[5]  Abate, H.K., Kidane, S.Z., Feyessa, Y.M. and Gebrehawariat, E.G. (2019) Mortality in Children with Severe Acute Malnutrition. Clinical Nutrition ESPEN, 33, 98-104.
https://doi.org/10.1016/j.clnesp.2019.07.001
[6]  Nasr, M., Tawfik, A., Ookawara, S. and Suzuki, M. (2013) Environmental and Economic Aspects of Hydrogen and Methane Production from Starch Wastewater Industry. Journal of Water and Environment Technology, 11, 463-475.
https://doi.org/10.2965/jwet.2013.463
[7]  Legrini, O., Oliveros, E. and Braun, A.M. (1993) Photochemical Processes for Water Treatment. Chemical Reviews, 93, 671-698.
https://doi.org/10.1021/cr00018a003
[8]  Schiavello, M. (1997) Heterogeneous Photocatalysis. 3rd Edition, John Wiley and Sons, Hoboken.
[9]  Vincenzo, A., Marta, L., Leonardo, P. and Javier, S. (2006) The Combination of Heterogeneous Photocatalysis with Chemical and Physical Operations: A Tool for Improving the Photoprocess Performance. Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 7, 127-144.
https://doi.org/10.1016/j.jphotochemrev.2006.12.001
[10]  Huh, A.J. and Kwon, Y.J. (2011) “Nanoantibiotics”: A New Paradigm for Treating Infectious Diseases Using Nanomaterials in the Antibiotics Resistant Era. Journal of Controlled Release, 156, 128-145.
https://doi.org/10.1016/j.jconrel.2011.07.002
[11]  Kim, J.S., Kuk, E., Yu, K.N., Kim, J.-H., Park, S.J., Lee, H.J., Kim, S.H., Park, Y.K., Park, Y.H. and Hwang, C.-Y. (2007) Antimicrobial Effects of Silver Nanoparticles. Nanomedicine: Nanotechnology, Biology and Medicine, 3, 95-101.
https://doi.org/10.1016/j.nano.2006.12.001
[12]  Tran, Q.H. and Le, A.-T. (2013) Silver Nanoparticles: Synthesis, Properties, Toxicology, Applications and Perspectives. Advances in Natural Sciences: Nanoscience and Nanotechnology, 4, Article ID: 033001.
https://doi.org/10.1088/2043-6262/4/3/033001
[13]  Sre, P.R., Reka, M., Poovazhagi, R., Kumar, M.A. and Murugesan, K. (2015) Antibacterial and Cytotoxic Effect of Biologically Synthesized Silver Nanoparticles Using Aqueous Root Extract of Erythrina indica Lam. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 135, 1137-1144.
https://doi.org/10.1016/j.saa.2014.08.019
[14]  Kong, H. and Jang, J. (2008) Antibacterial Properties of Novel Poly(methyl methacrylate) Nanofiber Containing Silver Nanoparticles. Langmuir, 24, 2051-2056.
https://doi.org/10.1021/la703085e
[15]  Jang, B., Badger, J.C., Elasri, M.O. and Mathias, L.J. (2007) Antibacterial Fluoromicas: A Novel Delivery Medium. Applied Clay Science, 38, 57-63.
https://doi.org/10.1016/j.clay.2007.01.002
[16]  Viana, M., Mohallem, N., Miquita, D., Balzuweit, K. and Silva-Pinto, E. (2013) Preparation of Amorphous and Crystalline Ag/TiO2 Nanocomposite Thin Films. Applied Surface Science, 265, 130-136.
https://doi.org/10.1016/j.apsusc.2012.10.151
[17]  Sun, J., Liu, N., Zhai, S., Xiao, Z., An, Q. and Huang, D. (2014) Gold-Titania/Proto- nated Zeolite Nanocomposite Photocatalysts for Methyl Orange Degradation under Ultraviolet and Visible Irradiation. Materials Science in Semiconductor Processing, 25, 286-293. https://doi.org/10.1016/j.mssp.2014.01.003
[18]  Yu, B., Leung, K.M., Guo, Q., Lau, W.M. and Yang, J. (2011) Synthesis of Ag-TiO2 Composite Nano Thin Film for Antimicrobial Application. Nanotechnology, 22, Article ID: 115603. https://doi.org/10.1088/0957-4484/22/11/115603
[19]  Younas, H., Qazi, I.A., Hashmi, I., Awan, M.A., Mahmood, A. and Qayyum, H.A. (2014) Visible Light Photocatalytic Water Disinfection and Its Kinetics Using Ag-Doped Titania Nanoparticles. Environmental Science and Pollution Research, 21, 740-752.
https://doi.org/10.1007/s11356-013-1980-7
[20]  Guillaume, P., Chelaru, A., Visa, M. and Lassiné, O. (2018) Titanium Oxide-Clay as Adsorbent and Photocatalysts for Wastewater Treatment. Journal of Memberane Science & Technology, 8, 176-186.
[21]  García-Serrano, J., Gómez-Hernández, E., Ocampo-Fernández, M. and Pal, U. (2009) Effect of Ag Doping on the Crystallization and Phase Transition of TiO2 Nanoparticles. Current Applied Physics, 9, 1097-1105.
https://doi.org/10.1016/j.cap.2008.12.008
[22]  Konan, K.L., Peyratout, C., Bonnet, J.-P., Smith, A., Jacquet, A., Magnoux, P. and Ayrault, P. (2007) Surface Properties of Kaolin and Illite Suspensions in Concentrated Calcium Hydroxide Medium. Journal of Colloid and Interface Science, 307, 101-108. https://doi.org/10.1016/j.jcis.2006.10.085
[23]  Wang, Y., Huang, Y., Ho, W., Zhang, L., Zou, Z. and Lee, S. (2009) Biomolecule-Controlled Hydrothermal Synthesis of C-N-S-Tridoped TiO2 Nanocrystalline Photocatalysts for NO Removal under Simulated Solar Light Irradiation. Journal of Hazardous Materials, 169, 77-87. https://doi.org/10.1016/j.jhazmat.2009.03.071
[24]  Pohan, A., Goure-Doubi, H., Kouyate, A., Nasir, M., Visa, M. and Ouattara, L. (2019) Hydrothermal Sol-Gel TiO2 Nanoparticles Fixed to Clay and Its Photocatalytic Application for the Degradation of Methyl Orange. Mediterranean Journal of Chemistry, 9, 125-132. https://doi.org/10.13171/mjc92190918430ap
[25]  Hsieh, C.-T., Fan, W.-S., Chen, W.-Y. and Lin, J.-Y. (2009) Adsorption and Visible-Light-Derived Photocatalytic Kinetics of Organic Dye on Co-Doped Titania Nanotubes Prepared by Hydrothermal Synthesis. Separation and Purification Technology, 67, 312-318. https://doi.org/10.1016/j.seppur.2009.03.041
[26]  Baiju, K., Shajesh, P., Wunderlich, W., Mukundan, P., Kumar, S.R. and Warrier, K. (2007) Effect of Tantalum Addition on Anatase Phase Stability and Photoactivity of Aqueous Sol-Gel Derived Mesoporous Titania. Journal of Molecular Catalysis A: Chemical, 276, 41-46. https://doi.org/10.1016/j.molcata.2007.06.017
[27]  Srivatsa, K., Bera, M. and Basu, A. (2008) Pure Brookite Titania Crystals with Large Surface Area Deposited by Plasma Enhanced Chemical Vapour Deposition Technique. Thin Solid Films, 516, 7443-7446.
https://doi.org/10.1016/j.tsf.2008.02.002
[28]  Rao, K.V.S., Lavédrine, B. and Boule, P. (2003) Influence of Metallic Species on TiO2 for the Photocatalytic Degradation of Dyes and Dye Intermediates. Journal of Photochemistry and Photobiology A: Chemistry, 154, 189-193.
https://doi.org/10.1016/S1010-6030(02)00299-X
[29]  Brown, L., Wolf, J.M., Prados-Rosales, R. and Casadevall, A. (2015) Through the Wall: Extracellular Vesicles in Gram-Positive Bacteria, Mycobacteria and Fungi. Nature Reviews Microbiology, 13, 620-630.
https://doi.org/10.1038/nrmicro3480
[30]  Schatz, A., Bugle, E. and Waksman, S.A. (1944) Streptomycin, a Substance Exhibiting Antibiotic Activity against Gram-Positive and Gram-Negative Bacteria. Proceedings of the Society for Experimental Biology and Medicine, 55, 66-69.
https://doi.org/10.3181/00379727-55-14461
[31]  Fujishima, A., Rao, T.N. and Tryk, D.A. (2000) Titanium Dioxide Photocatalysis. Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 1, 1-21.
https://doi.org/10.1016/S1389-5567(00)00002-2
[32]  Mills, A. and Le Hunte, S. (1997) An Overview of Semiconductor Photocatalysis. Journal of Photochemistry and Photobiology A: Chemistry, 108, 1-35.
https://doi.org/10.1016/S1010-6030(97)00118-4
[33]  Zhou, X., Liu, G., Yu, J. and Fan, W. (2012) Surface Plasmon Resonance-Mediated Photocatalysis by Noble Metal-Based Composites under Visible Light. Journal of Materials Chemistry, 22, 21337-21354.
https://doi.org/10.1039/c2jm31902k

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