Natural wastes as particle filler for poly(lactic acid)

The paper describes the production and the mechanical characteristics of composites made completely of renewable raw materials. Several wastes or by-products from agro-industrial production namely hemp hurd, alfalfa, and grape stem were analyzed with respect to their thermal stability, morphological, and chemical composition in an attempt to validate their use in composites. Such natural particle fillers were used in the range of 10–50？wt% in combination with poly(lactic acid) by melt blending to obtain fully bio-based composites. These fillers were responsible for a noteworthy increase in the storage modulus. Furthermore, two micromechanical models (Voigt and Halpin–Tsai) were used to mathematically fitted the experimental data, and then the unknown moduli were extrapolated and compared with other natural fillers. Finally, the flexural strength of the bio-composites and the adhesion evaluation by exploiting Pukanszky’s model were carried out. As a result, the hemp hurd in the form of chips was the best investigated filler, which showed the highest calculated modulus of 10.5？GPa (Voigt) and the best filler–matrix interaction with “B” (Pukanszky’s coefficient) of 2.10. This information can be useful when comparison and selection of a suitable filler among the natural fillers are required