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Peculiarities in the Director Reorientation and the NMR Spectra Evolution in a Nematic Liquid Crystals under the Effect of Crossed Electric and Magnetic Fields

DOI: https://doi.org/10.3390/cryst9050262

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Abstract:

The illustrative description of the field-induced peculiarities of the director reorientation in the microsized nematic volumes under the effect of crossed magnetic B and electric E fields have been proposed. The most interesting feature of such configuration is that the nematic phase becomes unstable after applying the strong E . The theoretical analysis of the reorientational dynamics of the director field provides an evidence for the appearance of the spatially periodic patterns in response to applied large E directed at an angle α to B . The feature of this approach is that the periodic distortions arise spontaneously from a homogeneously aligned nematic sample that ultimately induces a faster response than in the uniform mode. The nonuniform rotational modes involve additional internal elastic distortions of the conservative nematic system and, as a result, these deformations decrease of the viscous contribution U vis to the total energy U of the nematic phase. In turn, that decreasing of U vis leads to decrease of the effective rotational viscosity coefficient γ eff ( α ) . That is, a lower value of γ eff ( α ) , which is less than one in the bulk nematic phase, gives the less relaxation time τ on ( α ) ~ γ eff ( α ) , when α is bigger than the threshold value α th . The results obtained by Deuterium NMR spectroscopy confirm theoretically obtained dependencies of τ on ( α ) on α . View Full-Tex

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