Indium Tin-Oxide Wrapped 3D rGO and TiO2 Composites: Development, Characterization, and Enhancing Photocatalytic Activity for Methylene Blue

A hybrid material of indium tin-oxide (ITO) wrapped titanium dioxide and reduced graphene oxide (ITO-rGO and TiO 2) was prepared using a facile hydrothermal technique. TiO 2 nanorods were in situ grown on the surface of rGO (rGO and TiO 2), and which was then assembled onto ITO substrate layer by layer with formation of a 3D structure. ITO-rGO and TiO 2 exhibit low charge transfer resistance at the electrode-electrolyte interface and have good photoresponsive ability. Methylene blue (MB) can be effectively adsorbed and enriched onto ITO-rGO and TiO 2 surface. The adsorption kinetics and thermodynamics of ITO-rGO and TiO 2 were evaluated, showing that the exothermic and entropy-driven reaction were the main thermodynamic processes, and the Langmuir isotherm was the ideal model for adsorption fitting. Meanwhile, ITO greatly improved degradation of rGO and TiO 2 because electrons can be collected by ITO before recombination and MB can easily enter into the 3D structure of rGO and TiO 2. The highest photodegradation rate of MB reached 93.40% for ITO-rGO and TiO 2 at pH 9. Additionally, ITO-rGO and TiO 2 successfully solved the problems of being difficult to recycle and causing secondary pollution of traditional TiO 2 catalysts. Therefore, ITO-rGO and TiO 2 may be a potential photocatalyst for degrading organic pollutants in water. View Full-Tex