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Monitoring and Modelling the Trends of Primary and Secondary Air Pollution Precursors: The Case of the State of Kuwait

DOI: 10.1155/2010/879836

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Abstract:

Since the beginning of the industrial revolution, processes of different scales have contributed greatly to the pollution and waste load on the environment. More specifically, airborne pollutants associated with chemical processes have contributed greatly on the ecosystem and populations health. In this communication, we review recent activities and trends of primary and secondary air pollutants in the state of Kuwait, a country associated with petroleum, petrochemical, and other industrial pollution. Trends of pollutants and impact on human health have been studied and categorized based on recent literature. More attention was paid to areas known to researchers as either precursor sensitive (i.e., nitrogen oxides (N ), volatile organic compounds (VOCs)) or adjacent to upstream- or downstream-related activities. Environmental monitoring and modelling techniques relevant to this study are also reviewed. Two case studies that link recent data with models associated with industrial sectors are also demonstrated, focusing mainly on chemical mass balance (CMB) and Gaussian line source modelling. It is concluded that a number of the monitoring stations and regulations placed by the Kuwait Environment Public Authority (KUEPA) need up-to-date revisions and better network placement, in agreement with previous findings. 1. Introduction It is of paramount importance to monitor and study the behaviour of primary and secondary precursors of air pollution, to establish a better understanding of their trends and impact on the surrounding environment. Human-related activities result in a number of airborne chemicals (i.e., primary pollutants), which include methane ( ) and nonmethane hydrocarbons (collectively known as total hydrocarbons-THC), total sulphur, nitrogen oxides and hydrogen sulphide (S , N , H2S), carbon mono- and dioxide (CO and CO2), BTEX (C6H6, C6H5CH3, C6H5C2H5 and C6H4(CH3)2), and other heavy metals (e.g., Hg, Pb, etc.). The interaction of such chemicals with the surrounding environment and the effect of photochemical reactions in the atmosphere results in what is known as secondary pollutants, a valid example of which is ozone (O3). Urban air pollution photochemistry is somewhat unique, and has been a matter of debate for a number of years amongst researchers [1–6]. One of the main characteristics of urban air pollution is the oxidation of SO2 and NO2 and their conversion to particulate sulphate ( ) and gaseous and particulate nitrates (NO3). Moreover, the rate of the conversion of N to NO3 affects ozone formation and the fate of the N in the

References

[1]  J. H. Seinfeld, Air Pollution: Physical and Chemical Fundamentals, McGraw–Hill, New York, NY, USA, 1st edition, 1975.
[2]  K. Wark, C. F. Warner, and W. T. Davis, Air Pollution: Its Origin and Control, Prentice Hall, New York, NY, USA, 3rd edition, 1998.
[3]  A. E. Gildemeister, P. K. Hopke, and E. Kim, “Sources of fine urban particulate matter in Detroit, MI,” Chemosphere, vol. 69, no. 7, pp. 1064–1074, 2007.
[4]  Y. Wen and Z. Lian, “Influence of air conditioners utilization on urban thermal environment,” Applied Thermal Engineering, vol. 29, no. 4, pp. 670–675, 2009.
[5]  J. Fenger, “Air pollution in the last 50 years—from local to global,” Atmospheric Environment, vol. 43, no. 1, pp. 13–22, 2009.
[6]  V. Ramanathan and Y. Feng, “Air pollution, greenhouse gases and climate change: global and regional perspectives,” Atmospheric Environment, vol. 43, no. 1, pp. 37–50, 2009.
[7]  K. Matsumoto and H. Tanaka, “Formation and dissociation of atmospheric particulate nitrate and chloride: an approach based on phase equilibrium,” Atmospheric Environment, vol. 30, no. 4, pp. 639–648, 1996.
[8]  EIA. United States Energy Information Administration-EIA, “Kuwait energy data statistics and analysis: oil, gas, electricity and coal,” Final report, 2008.
[9]  OPEC, “World oil outlook,” Organization of the Petroleum Exporting Countries (OPEC), 2009.
[10]  S. M. Al-Salem and A. R. Khan, “Comparative assessment of ambient air quality in two urban areas adjacent to petroleum downstream/upstream facilities in Kuwait,” Brazilian Journal of Chemical Engineering, vol. 25, no. 4, pp. 683–696, 2008.
[11]  R. S. Ettouney, S. A. Abdul-Wahab, and A. S. Elkilani, “Emissions inventory, ISCST, and neural network modelling of air pollution in Kuwait,” International Journal of Environmental Studies, vol. 66, no. 2, pp. 193–206, 2009.
[12]  M. S. Al-Rashidi, V. Nassehi, and R. J. Wakeman, “Investigation of the efficiency of existing air pollution monitoring sites in the state of Kuwait,” Environmental Pollution, vol. 138, no. 2, pp. 219–229, 2005.
[13]  S. A. Abdul-Wahab, “Two case studies of air pollution from Oman and Kuwait,” International Journal of Environmental Studies, vol. 66, no. 2, pp. 179–191, 2009.
[14]  H. O. Gao, “Day of week effects on diurnal ozone/NOx cycles and transportation emissions in Southern California,” Transportation Research Part D, vol. 12, no. 4, pp. 292–305, 2007.
[15]  J. H. Seinfeld and S.N. Pandis, Atmospheric Chemistry and Physics, from Air Pollution to Climate Change, John Wiley & Sons, New York, NY, USA, 1997.
[16]  S. A. Abdul-Wahab, W. Bouhamra, H. Ettouney, B. Sowerby, and B. D. Crittenden, “Predicting ozone levels: a statistical model for predicting ozone levels in the Shuaiba Industrial Area, Kuwait,” Environmental Science and Pollution Research, vol. 3, no. 4, pp. 195–204, 1996.
[17]  S. A. Abdul-Wahab, W. Bouhamra, H. Ettouney, B. Sowerby, and B. D. Crittenden, “Analysis of air pollution at Shuaiba Industrial Area in Kuwait,” Toxicological and Environmental Chemistry, vol. 78, no. 3-4, pp. 213–232, 2000.
[18]  S. A. Abdul-Wahab, W. Bouhamra, H. Ettouney, B. Sowerby, and B. D. Crittenden, “Analysis of ozone pollution in the Shuaiba Industrial Area in Kuwait,” International Journal of Environmental Studies, vol. 57, no. 2, pp. 207–224, 2000.
[19]  H. O. Al Jeran and A. R. Khan, “The effect of air pollution on ozone layer thickness in troposphere over the state of Kuwait,” American Journal of Environmental Sciences, vol. 5, no. 3, pp. 230–237, 2009.
[20]  B. Brunekreef and S. T. Holgate, “Air pollution and health,” The Lancet, vol. 360, no. 9341, pp. 1233–1242, 2002.
[21]  C. J. Saitanis and M. G. Karandinos, “Effects of ozone on tobacco (Nicotiana tabacum L.) Varieties,” Journal of Agronomy and Crop Science, vol. 188, no. 1, pp. 51–58, 2002.
[22]  C. Nali, C. Pucciariello, and G. Lorenzini, “Ozone distribution in central Italy and its effect on crop productivity,” Agriculture, Ecosystems and Environment, vol. 90, no. 3, pp. 277–289, 2002.
[23]  Y. Zi-wei, J. Gui-bin, and X. Heng-zhen, “Distribution of ozone and other air pollutants in forests of the Carpathian Mountains in central Europe,” Environmental Pollution, vol. 116, no. 1, pp. 3–25, 2002.
[24]  A.-N. Riga-Karandinos and C. Saitanis, “Comparative assessment of ambient air quality in two typical Mediterranean coastal cities in Greece,” Chemosphere, vol. 59, no. 8, pp. 1125–1136, 2005.
[25]  J. A. Bernstein, N. Alexis, and N. Alexis, “Health effects of air pollution,” Journal of Allergy and Clinical Immunology, vol. 114, no. 5, pp. 1116–1123, 2004.
[26]  M. A. Al-Ghawaby, A. S. Gulam, H. H. Kandil, M. M. Al-Ghanim, and R. Usha, “The effect of air pollution during Kuwait oil well fires on children's chest,” in Proceedings of the International Conference on the Effects of Iraqi Aggression on the State of Kuwait, p. 139, ApriL 1994.
[27]  S. M. Al-Salem and W. S. Bouhamrah, “Ambient concentrations of benzene and other VOCs at typical industrial sites in Kuwait and their cancer risk assessment,” Research Journal of Chemistry & Environment, vol. 10, no. 3, pp. 42–46, 2006.
[28]  S. M. Al-Salem and A. Al-Fadhlee, “Ambient levels of primary and secondary pollutants in a residential area: population risk and hazard index calculation over a three years study period,” American Journal of Environmental Sciences, vol. 3, no. 4, pp. 225–229, 2007.
[29]  A.R. Khan and S. M. Al-Salem, “Influence of ambient levels of nitrogen oxides on male/female birth rates in Al-Ahmadi governorate (state of Kuwait),” in Proceedings of the 5th International Health, Safety, Environment & Loss Prevention Professional Development Conference & Exposition, Kuwait City, State of Kuwait, March, 2009.
[30]  R. H. White, C. H. Stineman, J. M. Symons, P. N. Breysse, S. R. Kim, M. L. Bell, and J. M. Samet, “Premature mortality in the Kingdom of Saudi Arabia associated with particulate matter air pollution from the 1991 Gulf War,” Human and Ecological Risk Assessment, vol. 14, no. 4, pp. 645–664, 2008.
[31]  J. L. Lange, D. A. Schwartz, B. N. Doebbeling, J. M. Heller, and P. S. Thorne, “Exposures to the Kuwait oil fires and their association with asthma and bronchitis among gulf war veterans,” Environmental Health Perspectives, vol. 110, no. 11, pp. 1141–1146, 2002.
[32]  Y. M. Sebzali and S. M. Al-Salem, “Estimation of six primary airborne pollutants in Al-Mansoriah residential area (Kuwait) using neural network training,” in Proceedings of the 5th International Health, Safety, Environment & Loss Prevention Professional Development Conference & Exposition, March 2009, Kuwait City, State of Kuwait.
[33]  A. Khan and S. M. Al-Salem, “Seasonal variation effect on airborne pollutants in an urban area of the state of Kuwait,” Journal of Environmental Research & Development, vol. 1, no. 3, pp. 215–218, 2007.
[34]  S. M. Al-Salem, “The influence of meteorological parameters on the patterns left by n-CH4 and CO gases on concentration roses executed as an environmental source determining technique,” Asian Journal of Water, Environment & Pollution, vol. 5, no. 4, pp. 31–41, 2008.
[35]  S. M. Al-Salem, A. A. Al-Fadhlee, and A. R. Khan, “Ambient air quality assessment of Al-Mansoriah residential area in the state of Kuwait,” The Journal of Engineering Research, vol. 6, no. 2, pp. 52–63, 2009.
[36]  E. Albassam, A. Khan, and V. Popov, “Management of air quality in the vicinity of congested area in Kuwait,” Environmental Monitoring and Assessment, vol. 157, no. 1-4, pp. 539–555, 2009.
[37]  A. Khan and S. M. Al-Salem, “Primary and secondary pollutants monitoring around an urban area in flie state of Kuwait: a three years study,” Research Journal of Chemistry and Environment, vol. 11, no. 3, pp. 77–81, 2007.
[38]  H. Al-Adwani, A. Elkilani, and W. Bouhamra, “Monitoring and modeling the effect of fuel change on air quality in a typical heavy traffic residential area in Kuwait,” Environmental Engineering Science, vol. 21, no. 6, pp. 678–690, 2004.
[39]  A. A. Ramadan, “Air quality assessment in Southern Kuwait using diffusive passive samplers,” Environmental Monitoring and Assessment, vol. 160, no. 1–4, pp. 413–423, 2009.
[40]  G. W. Fuller and D. Green, “Evidence for increasing concentrations of primary PM10 in London,” Atmospheric Environment, vol. 40, no. 32, pp. 6134–6145, 2006.
[41]  X. Querol, A. Alastuey, and A. Alastuey, “Speciation and origin of PM10 and PM2.5 in selected European cities,” Atmospheric Environment, vol. 38, no. 38, pp. 6547–6555, 2004.
[42]  M. R. Heal, L. R. Hibbs, R. M. Agius, and I. J. Beverland, “Total and water-soluble trace metal content of urban background PM 10, PM2.5 and black smoke in Edinburgh, UK,” Atmospheric Environment, vol. 39, no. 8, pp. 1417–1430, 2005.
[43]  S. M. Al-Salem, “An overview of the PM10 pollution problem in Fahaheel urban area, Kuwait,” Emirates Journal of Engineering Research, vol. 13, no. 3, pp. 1–9, 2008.
[44]  J. P. Engelbrecht, E. V. McDonald, J. A. Gillies, R. K. M. Jayanty, G. Casuccio, and A. W. Gertler, “Characterizing mineral dusts and other aerosols from the Middle East—part 1: ambient sampling,” Inhalation Toxicology, vol. 21, no. 4, pp. 297–326, 2009.
[45]  R. C. Balling Jr., R. S. Cerveny, and C. D. Idso, “Does the urban CO2 dome of Phoenix, Arizona contribute to its heat island?” Geophysical Research Letters, vol. 28, no. 24, pp. 4599–4601, 2001.
[46]  H. A. Nasrallah, R. C. Balling Jr., S. M. Madi, and L. Al-Ansari, “Temporal variations in atmospheric concentrations in Kuwait City, Kuwait with comparisons to Phoenix, Arizona, USA,” Environmental Pollution, vol. 121, no. 2, pp. 301–305, 2003.
[47]  P. Li, X. B. Feng, G. L. Qiu, L. H. Shang, and Z. G. Li, “Mercury pollution in Asia: a review of the contaminated sites,” Journal of Hazardous Materials, vol. 168, no. 2-3, pp. 591–601, 2009.
[48]  N. A. BuTayban and M. R. Preston, “The distribution and inventory of total and methyl mercury in Kuwait Bay,” Marine Pollution Bulletin, vol. 49, no. 11-12, pp. 930–937, 2004.
[49]  KUEPA, Kuwait Environment Public Authority. Kuwait Al-Youm Appendix 533, KUEPA rules and regulations, law 210/2001, 2001.
[50]  S. M. Al-Salem, Methane dispersion modelling and source determination around Fahaheel urban area, M.S. thesis, College of Graduate Studies, Chemical Engineering Department, Kuwait University, Kuwait City, Kuwait, 2007.
[51]  S. A. Abdul-Wahab, W. Bouhamra, H. Ettouney, B. Sowerby, and B. Crittenden, “Prediction of air pollution around heavily industrialised areas: use of the industrial source complex short-term model with emissions from a large number of sources,” Environmental Protection Bulletin, no. 58, pp. 3–13, 1999.
[52]  S. A. Abdul-Wahab, S. M. Al-Alawi, and A. El-Zawahry, “Patterns of SO2 emissions: a refinery case study,” Environmental Modelling and Software, vol. 17, no. 6, pp. 563–570, 2002.
[53]  R. R. Draxler, D. A. Gillette, J. S. Kirkpatrick, and J. Heller, “Estimating PM10 air concentrations from dust storms in Iraq, Kuwait and Saudi Arabia,” Atmospheric Environment, vol. 35, no. 25, pp. 4315–4330, 2001.
[54]  W. F. Christensen and R. F. Gunst, “Measurement error models in chemical mass balance analysis of air quality data,” Atmospheric Environment, vol. 38, no. 5, pp. 733–744, 2004.
[55]  W. F. Christensen, “Chemical mass balance analysis of air quality data when unknown pollution sources are present,” Atmospheric Environment, vol. 38, no. 26, pp. 4305–4317, 2004.
[56]  M.-C. Su, E. R. Christensen, and J. F. Karls, “Determination of PAH sources in dated sediments from Green Bay, Wisconsin, by a chemical mass balance model,” Environmental Pollution, vol. 99, no. 3, pp. 411–419, 1998.
[57]  A. K. Gupta, K. Karar, and A. Srivastava, “Chemical mass balance source apportionment of PM10 and TSP in residential and industrial sites of an urban region of Kolkata, India,” Journal of Hazardous Materials, vol. 142, no. 1-2, pp. 279–287, 2007.
[58]  S. M. Al-Salem, A. A. Al-Haddad, and A. R. Khan, “Primary pollutants monitoring and modeling using Chemical Mass Balance (CMB) around Fahaheel residential area,” American Journal of Environmental Sciences, vol. 4, no. 1, pp. 13–21, 2008.
[59]  S. M. Al-Salem and A. A. Al-Haddad, “Pollutants monitoring and source determining: effect of oil refineries on a residential area,” in Proceedings of the 2nd International Conference on Scientific Computing to Computational Engineering (IC-SCCE '06), D. T. Tsahalis, Ed., Athens, Greece, July 2006.
[60]  S. M. Al-Salem and A. R. Khan, “Methane dispersion modelling and source determination around urban areas in Kuwait,” in Proceedings of the 1st International Conference & Exhibition on Green Industry, Manama, Kingdom of Bahrain, November 2006.
[61]  E. El-Bassam and A. Khan, “Air pollution and road traffic in Kuwait,” in Proceedings of the Urban Transport X, Urban Transport and the Environment in the 21st Century, C. A. Brebbia and L. C. Wadha, Eds., pp. 741–750, WIT Press, Dresden, Germany, May 2004.
[62]  S. Al-Hajraf, D. Al-Ajmi, A. R. Khan, H. Tang, A. Wahner, and D. Klemp, “Air quality assessment of Ali Sabah Al-Salem,” KISR Report EC031C, Urban Community, 2005.

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