全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

Synthesis and Structural Investigations of Ag-Added Ba -CuO Mixed Oxide for Gas Sensing

DOI: 10.1155/2011/592075

Full-Text   Cite this paper   Add to My Lib

Abstract:

Compositions having the general formula BaTiO3- ?wt% Ag, where , and 2 have been prepared by solid state ceramic processing and sintered at 500 and for 5?h. Thermogravimetric analysis (TGA), X-ray powder diffraction (XRD), infrared absorption spectra (IR), and scanning electron microscopy (SEM) were used to characterize the obtained sensor pellets. It was found that no solid state reaction took place between BaTiO3 and CuO during sintering process. The sensitivity of the prepared sensors to CO2 gas increases with increasing sintering temperature and Ag content. The correlation between Ag content at different sintering temperature and structure characterization is discussed. 1. Introduction Atmospheric pollution is defined as a status containing gases, offensive odors, and particles that are harmful to human, animals, vegetables, or living environments above the regulation limits in specific regions [1]. A severe phenomenon of the environment is global warming. This phenomenon is considered to be related to the aspect that the concentration of carbon dioxide in the atmosphere is increasing. The ideal chemical gas sensor must be chemically selective, reversible, fast response, highly sensitive, no contaminating, no poisoning, simple using, small size, simple fabrication, relative temperature insensitivity, low noise and low manufacturing costs [2]. While in all the mentioned cases it would be valuable to have a low-cost sensor. Nonexpensive and robust detection systems are required for air quality, food control, and early fire detection. Gas sensors monitoring CO2 concentrations are used in fields such as agricultural industries, biotechnological processes, air conditioning, medical services, housing, and environmental observation [3]. Most of the currently available sensing systems are based on optical detection, which makes them expensive. Some cheaper electrochemical sensors have also been developed, but their fabrication process is still complicated. Moreover, in the presence of humidity, these sensors reduce drastically their response to CO2. In this situation, solid-state gas sensors based on semiconductor metal oxides may be a promising alternative, since they offer good sensor properties and can be easily mass-produced. Semiconductor gas sensors based on the capacitance or resistance change of the sensor are good candidates to reach a reliable and cheap sensor for CO2. The gases’ adsorption or their reaction on the surfaces of the semiconducting materials induces the change in the density of the conducting electrons in the polycrystalline sensor

References

[1]  D. D. Lee, “Environmental gas sensors,” IEEE Sensors Journal, vol. 1, no. 3, pp. 214–224, 2001.
[2]  A. Mandelis and C. Christofiedes, Physics Chemistry and Technology of Solid State Gas Sensor Devices, Academic Press, Toronto, Canada, 1993.
[3]  M. S. Lee and J. U. Meyer, “New process for fabricating CO2-sensing layers based on BaTiO3 and additives,” Sensors and Actuators, B, vol. 68, no. 1, pp. 293–299, 2000.
[4]  D. H. Kim, J. Y. Yoon, H. C. Park, and K. H. Kim, “CO2-sensing characteristics of SnO2 thick film by coating lanthanum oxide,” Sensors and Actuators, B, vol. 62, no. 1, pp. 61–66, 2000.
[5]  N. Mizuno, T. Yoshioka, K. Kato, and M. Iwamoto, “CO2-sensing characteristics of SnO2 element modified by La2O3,” Sensors and Actuators B, vol. 13, no. 1–3, pp. 473–475, 1993.
[6]  E. H. A. Diagne and M. Lumbreras, “Elaboration and characterization of tin oxide-lanthanum oxide mixed layers prepared by the electrostatic spray pyrolysis technique,” Sensors and Actuators, B, vol. 78, no. 1-3, pp. 98–105, 2001.
[7]  A. M. El-Sayet, F. M. Ismail, and S. M. Yakout, “Electrical conductivity and sensitive characteristics of Ag-added BaTiO3-CuO mixed oxide for CO2 gas sensing,” Journal of Materials Science and Technology, vol. 27, no. 1, pp. 35–40, 2011.
[8]  B. Liao, Q. Wei, K. Wang, and Y. Liu, “Study on CuO-BaTiO3 semiconductor CO2 sensor,” Sensors and Actuators, B, vol. 80, no. 3, pp. 208–214, 2001.
[9]  T. Ishihara, K. Kometani, Y. Mizuhara, and Y. Takita, “Application of a mixed oxide capacitor to the selective carbon dioxide sensor,” Journal of the Electrochemical Society, vol. 139, no. 10, pp. 2881–2885, 1992.
[10]  W. Chen and J. Zhang, “Ag nanoparticles hosted in monolithic mesoporous silica by thermal decomposition method,” Scripta Materialia, vol. 49, no. 4, pp. 321–325, 2003.
[11]  B. V. L’vov and V. L. Ugolkov, “Kinetics and mechanism of free-surface decomposition of solid and melted AgNO3 and Cd(NO3)2 analyzed thermogravimetrically by the third-law method,” Thermochimica Acta, vol. 424, no. 1-2, pp. 7–13, 2004.
[12]  R. T. Mara, G. B. B. M. Sutherland, and H. V. Tyrell, “Infrared spectrum of barium titanate,” Physical Review, vol. 96, no. 3, pp. 801–802, 1954.
[13]  J. Wang, Q. Lin, R. Zhou, and B. Xu, “Humidity sensors based on composite material of nano-BaTiO3 and polymer RMX,” Sensors and Actuators, B, vol. 81, no. 2-3, pp. 248–253, 2002.
[14]  G. Kliche and Z. V. Popovic, “Far-infrared spectroscopic investigations on CuO,” Physical Review B, vol. 42, no. 16, pp. 10060–10066, 1990.
[15]  Z. Wang, Q. Liu, J. Yu, T. Wu, and G. Wang, “Surface structure and catalytic behavior of silica-supported copper catalysts prepared by impregnation and sol-gel methods,” Applied Catalysis A, vol. 239, no. 1-2, pp. 87–94, 2003.
[16]  M. Parodi, “Etude de quelques borates et de quelques oxydes dans l'infrarouge lointain,” Comptes Rendus, vol. 204, p. 1111, 1937.
[17]  T. Ishihara, K. Kometani, Y. Mizuhara, and Y. Takita, “Mixed oxide capacitor of CuO—BaTiO3 as a new type CO2 gas sensor,” Journal of the American Ceramic Society, vol. 75, no. 3, pp. 613–618, 1992.
[18]  D. Majumdar, H. D. Glicksman, and T. T. Kodas, “Generation and sintering characteristics of silver-copper (II) oxide composite powders made by spray pyrolysis,” Powder Technology, vol. 110, no. 1-2, pp. 76–81, 2000.
[19]  Z. Jiao, F. Chen, R. Su, X. Huang, W. Liu, and J. Liu, “Study on the characteristics of Ag doped CuO-BaTiO3CO2 sensors,” Sensors, vol. 2, no. 9, pp. 366–373, 2002.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133