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Interpretation of Adsorption Thermodynamics and Kinetics

DOI: 10.4236/ojpc.2020.103010, PP. 166-182

Keywords: Gibbs Free Energy, Entropy Change, Adsorption Density, Sticking Probability, Activation Energy, Pseudo-Second-Order Kinetic Model, Elovich Model, Brouers-Sotolongo Fractal Kinetic Model

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Abstract:

A complete study of adsorption processes will be less complete if the structure and dynamics of its different elements and how they interact is not well captured. Therefore, the extensive study of adsorption thermodynamics in conjunction with adsorption kinetics is inevitable. Measurable thermodynamic properties such as temperature equilibrium constant and their non-measurable counterparts such as Gibbs free energy change, enthalpy, entropy etc. are very important design variables usually deployed for the evaluation and prediction of the mechanism of adsorption processes.

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