It is proposed a representation of the basic laws (i.e. the zeroth, first, second and third laws) in thermodynamics for quantum systems in the pure and mixed ensembles, respectively. We show that the basic laws are represented by parameters that specify respective quantum states. The parameters are the elements of the thermodynamic state space Mθ and the state space Mϑ of the mixed ensemble for quantum systems. The introduction of such parameters is based on a probabilistic nature of quantum theory. Consistency between quantum theory and classical thermodynamics is preserved throughout the formulation for the representation of the thermodynamical laws in quantum systems (quantum thermodynamics). The present theory gives the mathematical foundations of quantum thermodynamics.
References
[1]
Fermi, E. (1956) Thermodynamics, Dover, New York.
[2]
Callen, H.B. (1985) Thermodynamics and an Introduction to Thermostatics. 2nd Edition, Wiley, New York.
[3]
Lieb, E.H. and Yngvason, J. (1999) Physics Reports, 310, 1-96. https://doi.org/10.1016/S0370-1573(98)00082-9
[4]
von Neumann, J.L. (1932) Mathematische Grundlagen der Quantenmechanik, Springer, Berlin. In: Beyer, E.T., Ed., (1955) Mathematical Foundations of Quantum Mechanics, Princeton University Press, Princeton.
[5]
Peres, A. (1993) Quantum Theory: Concepts and Methods. Kluwer-Academic, Boston.
[6]
Wehrl, A. (1978) Reviews of Modern Physics, 50, 221. https://doi.org/10.1103/RevModPhys.50.221
[7]
Partovi, M.H. (1989) Physics Letters A, 137, 440-444. https://doi.org/10.1016/0375-9601(89)90221-1
[8]
Bender, C.M., Brody, D.C. and Meister, B.K. (2000) Journal of Physics A, 33, 4427-4436. https://doi.org/10.1088/0305-4470/33/24/302
[9]
Suzuki, A. and Taira, H. (2018) Journal of Modern Physics, 9, 2420-2436. https://doi.org/10.4236/jmp.2018.914155
[10]
Isham, C. J. (1995) Lectures on Quantum Theory: Mathematical and Structural Foundations, Imperial College Press, London. https://doi.org/10.1142/p001