Nanocellulose is a new class of derivatives of cellulose, which is characterized by high crystallinity, surface area, degree of dispersion, ability to decomposition by microorganisms and etc. There is high attention solving problems of obtaining nanocellulose and its application as high quality filler for polymers, biodegradable materials, additives for papers, clotting dispersion and etc. Obtaining of particles of nanosized nanostructure on the base cellulose, studying of processes of their formation, properties and creation nanotechnology on this basis give the chance to obtain materials with unique properties. In this work nanocellulose was obtained from cotton cellulose by hydrolysis with sulfuric acid, ultrasonic dispersion and microwave irradiation. The properties and structure of nanocellulose are investigated by AFM, IR-spectroscopic, X-ray methods. Nanocellulose has rod-like shape with sizes 50 - 300 nm in length and 10 - 40 nm in diameters and spherical shape with sizes 50 - 300 nm depending on the synthesis conditions of obtaining. Quantum-chemical methods have been used to calculate the electronic characteristics of nanocellulose; the change in the energy difference between HOMO and LUMO is shown, showing the change in reactivity and the manifestation of specific properties.
References
[1]
Habibi, Y., Lucia, L.A. and Rojas, O.J. (2010) Cellulose Nanocrystals Chemistry, Self-Assembly, and Applications. Chemical Reviews, 110, 3479-3500. https://doi.org/10.1021/cr900339w
[2]
Ioelovich, M. and Figovsky, O. (2010) Structure and Properties of Nanoparticles Used in Paper Compositions. Mechanics Composite Materials, 46, 637-647. https://doi.org/10.1007/s11029-010-9160-z
[3]
Rebouillat, S. and Pla, F. (2013) State of the Art Manufacturing and Engineering of Nanocellulose: A Review of Available Data and Industrial Applications. Journal of Biomaterials and Nanobiotechnology, 4, 165-188. https://doi.org/10.4236/jbnb.2013.42022
[4]
Lu, Y., Tekinalp, H.L., Eberle, C.C., Peter, W., Naskar, A.K. and Ozcan, S. (2014) Nanocellulose in Polymer Composites and Biomedical Application. Tappi Journal, 13, 47-54.
[5]
Yuldoshov, Sh.A., Atakhanov, A.A., Sarymsakov, A.A. and Rashidova, S.Sh. (2015) Investigation of Reaction Activity of Cellulose and Its Products of Acid Hydrolysis. Macromolecules: An Indian Journal, 11, 51-57.
[6]
Nazir, M.S., Wahjoedi, B.A., Yussof, A.W. and Abdullah, M.A. (2013) Eco-Friendly Extraction and Characterization of Cellulose from Oil Palm Empty Fruit Bunches. BioResource, 8, 2161-2172. https://doi.org/10.15376/biores.8.2.2161-2172
[7]
Kong, W., Plant, T., Simonsen, J. and Evans, G. (2006) Cellulose Nanocrystal Electro-Optic Devices. Journal of Applied Physics, 97, Article ID: 053101.
[8]
Wang, M.S. (2011) Surface Modification and Characterization of Nano Crystalline Cellulose. M.Sc. Sci. Thesis, Chalmers University of Technology, Goteborg.
[9]
Moon, R.J., Martini, A., Nairn, J. and Simonsenf, J. (2011) Cellulose Nanomaterials Review: Structure, Properties and Nanocomposites. Chemical Society Reviews, 40, 3941-3994. https://doi.org/10.1039/c0cs00108b
[10]
Elazzouzi-Hafraoui, S., Nishiyama, Y., Putaux, J.-L., Heux, L., Dubreuil, F. and Rochas, C. (2008) The Shape and Size Distribution of Crystalline Nanoparticles Prepared by Acid Hydrolysis of Native Cellulose. Biomacromolecules, 9, 57-65. https://doi.org/10.1021/bm700769p
[11]
Zaini, L.H., Jonoobi, M., Tahir, P.Md. and Karimi, S. (2013) Isolation and Characterization of Cellulose Whiskers from Kenaf Bast Fibers. Journal of Biomaterials and Nanotechnology, 4, 37-44. https://doi.org/10.4236/jbnb.2013.41006
[12]
Yu, M., Yang, R., Huang, L., Cao, X., Yang, F. and Liu, D. (2012) Preparation and Characterization of Bamboo Nanocrystalline Cellulose. Bioresources, 7, 1802-1812. https://doi.org/10.15376/biores.7.2.1802-1812
[13]
Li, W., Wang, R. and Liu, S. (2011) Nanocrystalline Cellulose Prepared from Softwood Kraft Pulp via Ultrasonic-Assisted Acid Hydrolysis. BioResources, 6, 4271-4281.
[14]
Janardhnan, S. and Sain, M.M. (2011) Targeted Disruption of Hydroxyl Chemistry and Crystallinity in Natural Fibers for the Isolation of Cellulose Nano-Fibers via Enzymatic Treatment. BioResources, 6, 1242-1250.
[15]
Wang, Y., Wei, X., Li, J., Wang, F., Wang, Q. and Kong, L. (2013) Homogeneous Isolation of Nanocellulose by High Pressure Homogenization. Journal of Material Science and Chemical Engineering, 1, 49-52. https://doi.org/10.4236/msce.2013.15010
[16]
Bondeson, D., Mathew, A. and Oksman, K. (2006) Optimization of the Isolation of Nanocrystals from Microcrystalline Cellulose by Acid Hydrolysis. Cellulose, 13, 171-180. https://doi.org/10.1007/s10570-006-9061-4
[17]
Segal, L., Creely, J.J., Martin, A.E. and Conrad, C.M. (1959) An Empirical Method for Estimating the Degree of Crystallinity of Native Cellulose Using the X-Ray Difractometer. Textile Research Journal, 29, 786-794. https://doi.org/10.1177/004051755902901003