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Exciton Energy Transfer in Hybrid Organics—Semiconductor Nanostructure

DOI: 10.4236/snl.2019.92002, PP. 17-33

Keywords: Hybrid Heterostructure, Frenkel Exciton, Exciton Energy

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Abstract:

We consider a hybrid heterostructure containing an inorganic quantum well in close proximity with organic material as overlayer. The resonant optical pumping of Frenkel exciton can lead to an efficient indirect pumping of Wannier excitons. As organic material in such a hybrid structure, we consider crystalline tetracene. In tetracene, the singlet exciton energy is close to twice the one of triplet exciton state and singlet exciton fission into two triplets can be efficient. This process in tetracene is thermally activated and we investigate here how the temperature-dependent exciton energy transfer affects the functional properties of hybrid organic-inorganic nanostructures. We have obtained the exact analytical solution of diffusion equation for organics at different temperatures defining different diffusion lengths of excitons. The effectiveness of energy transfer in hybrid with tetracene was calculated by definite method for two selected temperatures that open possibility to operate in full region of temperatures. Temperature dependence of energy transfer opens a new possibility to turn on and off the indirect pumping due to energy transfer from the organic subsystem to the inorganic subsystem.

References

[1]  Agranovich, V.M., Gartstein, Y.N. and Litinskaya, M. (2011) Hybrid Resonant Organic-Inorganic Nanostructures for Optoelectronic Applications. Chemical Reviews, 111, 5179-5124.
https://doi.org/10.1021/cr100156x
[2]  Blumstengel, S., Sadofev, S., Xu, C., Puls, J. and Henneberger, F. (2006) Converting Wannier into Frenkel Excitons in an Inorganic/Organic Hybrid Semiconductor Nanostructure. Physical Review Letters, 97, Article ID: 247401.
https://doi.org/10.1103/PhysRevLett.97.237401
[3]  Acherman, M., Petruska, M.A., Kos, S., et al. (2004) Energy-Transfer Pumping of Semiconductor Nanocrystals Using an Epitaxial Quantum Well. Nature, 429, 642-646.
https://doi.org/10.1038/nature02571
[4]  Agranovich, V.M., Basko, D.M. and La Rocca, G.C. (2012) Efficient Optical Pumping of Organic-Inorganic Heterostructures for Nonlinear Optics. Chemical Review B, 86, Article ID: 165204.
https://doi.org/10.1103/PhysRevB.86.165204
[5]  Blumenstegel, S., Sadofev, S., Pulset, J., et al. (2009) An Inorganic/Organic Semiconductor “Sandwich” Structure Grown by Molecular Beam Epitaxy. Advanced Materials, 21, 4850-4853.
https://doi.org/10.1002/adma.200900703
[6]  Itskos, G., Heliotis, G., Lagoudakis, P.G., et al. (2007) Efficient Dipole-Dipole Coupling of Mott-Wannier and Frenkel Excitons in (Ga, In)N Quantum Well/Polyfluorene Semiconductor Heterostructures. Chemical Review B, 76, 035344.
https://doi.org/10.1103/PhysRevB.76.035344
[7]  Zhang, Q., Atay, T., Tischler, J.R., et al. (2007) Highly Efficient Resonant Coupling of Optical Excitations in Hybrid Organic/Inorganic Semiconductor Nanostructures. Nature Nanotechnology, 2, 555-559.
https://doi.org/10.1038/nnano.2007.253
[8]  Laubel, G. and Baessler, H. (1970) Diffusion of Singlet Excitons in Tetracene Crystals. Molecular Crystals and Liquid Crystals, 12, 47-56.
https://doi.org/10.1080/15421407008082759
[9]  Agranovich, V.M., Dubovskiy, O.A., La Rocca, G.C. (2014) Singlets and Triplets in Hybrid Nanodevices. JETP Letters, 99, 323-326.
https://doi.org/10.1134/S0021364014060022

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