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Catalytic Removal of NOx by Cerium-modified Zirconium Composite Oxide

DOI: 10.4236/gep.2019.76006, PP. 66-82

Keywords: Composite Oxide, Rare Earth, Tail Gas Treatment, Catalyst, NOx

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Abstract:

Diesel engines have been widely used due to their high thermal efficiency, good environmental adaptability, wide power adjustment range, convenient maintenance and long service life. However, the application of diesel engines is also facing a serious problem; that is, the emission of nitrogen oxides and particulate matter is serious. For marine diesel engine emission requirements, MARPOL Convention Annex VI imposes strict restrictions on the emission of atmospheric pollutants. The limit emission of nitrogen oxides in the Tier III emission standards mandated by IMO is 3.4 g/kWh. Therefore, in order to meet the requirements of international conventions and countries and regions, it is necessary to control the emissions of diesel engines. The NOx in the exhaust gas is mostly a thermal type of nitrogen oxide which is produced under high temperature and high pressure conditions formed during compression and combustion strokes. The diesel engine relies on the compression energy of the mixture to ignite, and the good injection atomization effect is not achieved. The distribution of the detonation point is not uniform, and local high temperature points are generated in some areas, which increases the NOx formation. The main means of reducing NOx emissions are organic internal control and post-treatment. However, the use of internal control technology to reduce the internal temperature of the machine will deteriorate the fuel combustion conditions, so that the fuel cannot be completely burned, and the emissions of incomplete combustion products such as PM and CO increase. It is difficult to achieve NOx reduction by simply relying on the internal control technology, so it is necessary to use post-processing technology. The combined use of different emission reduction technologies is also a hot topic in emissions control research. The post-treatment methods for NOx emission reduction include direct catalytic decomposition, selective non-catalytic reduction, selective catalytic reduction, lean-burn adsorption catalytic reduction, and low-temperature plasma assisted technology. The current research and application schemes in the industry are SCR selectivity. Catalytic reduction and LNT lean combustion adsorption reduction. In this paper, the partial

References

[1]  Dong, H., & Shuai, S. (2007). The Latest Development and Development Trend of Diesel Exhaust after Treatment Technology. Small Internal Combustion Engines and Motorcycles, 36, 87-92.
[2]  Fornasiero, P., Di Monte, R., Rao, G. R. et al. (1995). Rh-Loaded CeO2-ZrO2 Solid-Solution as Highly Efficient Oxygen Exchangers: Dependence of the Reduction Behavior and the Oxygen Storage Capacity on the Structural-Properties. Journal of Catalysis, 151, 168-177.
https://doi.org/10.1006/jcat.1995.1019
[3]  Gao, S., Qu, J., Lu, C. et al. (2001). Development Status of Foreign Diesel Engine Emission Regulations and Emission Control Technologies. Journal of Shandong Institute of Engineering, 15, 38-42.
[4]  Gao, Z., & Dai, H. (2011). Practical Catalysis. Beijing: Chemical Industry Press.
[5]  Li, D., Zhang, H., Zhang, H., Guo, Q., & Cao, M. (2006). Research and Application Progress of Perovskite Type Composite Oxide. Materials Review, No. S1, 296-299.
[6]  Liu J. (2009). Nanocatalysts in Diesel Vehicle Exhaust Gas Purification. Summary of the 5th National Conference on Environmental Chemistry, Environmental Chemistry Committee of China Chemical Society, Chinese Chemical Society Environmental Chemistry Committee, Chinese Chemical Society, 2.
[7]  Tsyganok, A. I., Inaba, M., Tsunoda, T. et al. (2004). Combined Partial Oxidation and Dry Reforming of Methane to Synthesis GAI over Noble Metals Supported on Mg-Al Mixed Oxide. Applied Catalysis A: General, 275, 149-155.
https://doi.org/10.1016/j.apcata.2004.07.030
[8]  Wang, W., Mao, D., Wu, G., & Guo, X. (2008). Preparation and Application of Copper/Zirconium Oxide Catalysts. Chemical Industry Progress, 27, 47-52.
[9]  Wang, Z., & Shi, Q. (2006). Preparation and Characterization of Rare Earth Modified Cerium Zirconium Solid Solution. Journal of Catalysis, 23, 12-16.
[10]  Xu, Z. et al. (2009). Development of Diesel Particulate Filter for Marine Diesel Engine: Characteristics of PM Collection in Electrostatic-Cyclone DPF. Marine Engineering 44, 304-309.
https://doi.org/10.5988/jime.44.304
[11]  Yoshida, D., Hatanaka, Y., & Kifune, H. (2006). Development of Marine Diesel Particulate Filter by Means of High Frequency Induction Heating. Marine Engineering, 41, 889-894.
[12]  Zhan, W., Cai, G., Xiao, Y. et al. (2007). Relationship between Oxygen Storage Performance and Structure of CexZr1-xO2 Solid Solution. Spectroscopy and Spectral Analysis, 27, 2266-2269.
[13]  Zhang, G., Han, L., Zhao, Z., & Liu, J. (2008). Research Progress of Four-Way Catalytic Purification Technology for Diesel Vehicle Exhaust Gas. Journal of Catalysis, 22, 62-66.
[14]  Zhao, M., Wang, J., & Shen, M. (2007). Effect of Specific Surface Area and Bulk Structure of Cerium-Zirconium Solid Solution on Oxygen Storage and Storage Performance. In Proceedings of the 4th National Conference on Rare Earth Catalysis (pp. 82-91). Wuxi.

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