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Precise Determination of Uranium Isotopes in Suez Canal Sediment

DOI: 10.4236/jasmi.2019.92004, PP. 30-41

Keywords: Sediment, Uranium, Isotopic Ratios, Natural Radioactivity, Suez Canal, Egypt

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Abstract:

The streambed sediments of the Suez Canal have been analyzed for determining the natural radionuclides and long-lived radionuclides such as uranium by gamma and alpha spectrometric techniques. The specific activities of 238U series, 232Th series and 40K (Bq/kg) were measured by gamma spectrometry based on Hyper-Pure Germanium detector (HPGe). The average specific activities of 226Ra(238U) series, 232Th series and 40K were ranged from 3.04 ± 1.10 to 14.70 ± 1.24 Bq/kg, from 1.12 ± 0.66 to 16.10 ± 1.30 and from 77 ± 4.90 to 350.50 ± 8.90 Bq/kg respectively. The concentration of 238U and 234U in the streambed sediments are ranged from 3.24 ± 0.21 to 13.34 ± 0.61 ppm and from 3.18 ± 0.02 to 13.77 ± 0.03 ppm in dry weight respectively. 234U/238U ratios of the sediments are relatively lower than unity in many locations indicating the preferential uranium leaching process. The results with the high ratios for 234U/238U were observed in the sediment collected from Port Said. This may be attributed to the sorption of uranium by sediment which has a relatively high content of organic matter. The geochemical behavior of sediment, the chemistry of uranium and the flow rates of water are considered as the most important factors controlling uranium isotopic composition of the streambed sediment. The result of radioactivity in sediment samples can be used to distinguish any future changes due to non-nuclear industries on the Suez Canal area.

References

[1]  Hassan, H.B. (2016) Effect of Suez Canal Marine Sediment on Sorption of Cesium. Journal of Nuclear Technology in Applied Science, 4, 113-121.
[2]  Emara, M.M., Farid, N.A., El-Sabagh, E.A. and Ahmed, O.E. (2013) Physico-Chemical Study of Surface Seawater inThe Northwestern Gulf of Suez. Egyptian Journal of Chemistry, 56, 345-365. https://doi.org/10.21608/ejchem.2013.1117
[3]  Sabek, G. (1987) Assessment of the Impact from Transporting Radioactive Materials in the Suez Canal. International Atomic Energy Agency, Report No. R-4292-F.
[4]  El-Tahawy, M.S., Farouk, M.A., Ibrahiem, N.M. and El-Mongey, S.A.M. (1994) Natural and Artificial Radionuclides in the Suez Canal Bottom Sediments and Stream Water. Radiation Physics and Chemistry, 44, 87-89. https://doi.org/10.1016/0969-806X(94)90110-4
[5]  Anderson, R.F. (1987) Redox Behaviors of Uranium in an Anoxic Marine Basin. Uranium, 3, 145-164.
[6]  Huh, C.A., Zahnle, D.L., Small, L.F. and Noshkin, V.E. (1987) Budgets and Behaviors of Uranium and Thorium Series Isotopes in Santa Monica Basin Sediments. Geochimica et Cosmochimica Acta, 51, 1743-1754. https://doi.org/10.1016/0016-7037(87)90352-8
[7]  Francois, R. (1988) A Study on the Regulation of the Concentrations of Some Trace Metals (Rb, Sr, Zn, Pb, Cu, V, Cr, Ni, Mn and Mo) in Saanich Inlet Sediments, British Columbia. Marine Geology, 83, 285-308. https://doi.org/10.1016/0025-3227(88)90063-1
[8]  Garcia-Talavera, M. (2003) Evaluation of the Sustainability of Various γ Lines for the γ Spectrometric Determination of 238U in Environmental Samples. Applied Radiation and Isotopes, 59, 165-173. https://doi.org/10.1016/S0969-8043(03)00153-2
[9]  Saidou Francois, B., Jean-Pascal, L., Kwato Njock, M.G. and Pascal, F. (2008) A Comparison of Alpha and Gamma Spectrometry for Environmental Natural Radioactivity Surveys. Applied Radiation and Isotopes, 66, 215-222. https://doi.org/10.1016/j.apradiso.2007.07.034
[10]  Fleisher, M.Q., Anderson, R.F. and LeHuray, A.P. (1986) Uranium Deposition in Ocean Margin Sediments. Eos, Transactions, American Geophysical Union, AGU67, 1070.
[11]  Zheng, Y., Anderson, R., Geen, A. and Fleisher, M.Q. (2002) Remobilization of Authigenic Uranium in Marine Sediments by Bioturbation. Geochimica et Cosmochimica Acta, 66, 1759-1772. https://doi.org/10.1016/S0016-7037(01)00886-9
[12]  Klinkhammer, G.P. and Palmer, M.R. (1991) Uranium in the Oceans: Where It Goes and Why. Geochim. Cosmochim. Geochimica et Cosmochimica Acta, 55, 1799-1806.
https://doi.org/10.1016/0016-7037(91)90024-Y
[13]  Koide, M. and Goldberg, E.D. (1983) Uranium Isotopes in the Greenland Ice-Sheet. Earth and Planetary Science Letters, 65, 245-248. https://doi.org/10.1016/0012-821X(83)90163-2
[14]  Greeman, D.J., Jester, W.A. and Rose, A.W. (1990) Form and Behavior of Radium, Uranium and Thorium in Central Pennsylvania Soils Derived from Dolomite. Geophysical Research Letters, 17, 833-836. https://doi.org/10.1029/GL017i006p00833
[15]  Barnes, C.E. and Cochran, J.K. (1990) Uranium Removal in Oceanic Sediments and the Oceanic U balance. Earth and Planetary Science Letters, 97, 94-101.
https://doi.org/10.1016/0012-821X(90)90101-3
[16]  Copenhaver, S.A., Krishnaswami, S., Turekian, K.K. and Shaw, H. (1992) 238U and 232Th Series Nuclides in Ground Water from the J-13 Well at the Nevada Test Site; Implications for the Ion Retardation. Geophysical Research Letters, 19, 1383-1386.
https://doi.org/10.1029/92GL01437
[17]  Sarin, M.M., Krishnaswami, S., Somayajulu, B.L.K. and Moore, W.S. (1990) Chemistry of Uranium, Thorium, and Radium Isotopes in the Ganga-Brahmaputra River System: Weathering Processes and Fluxes to the Bay of Bengal. Geochimica et Cosmochimica Acta, 54, 1387-1396. https://doi.org/10.1016/0016-7037(90)90163-F
[18]  The Suez Canal zone of Egypt (2017) Map of World Web.
https://www.mapsofworld.com/egypt/suez-canal.html
[19]  CANBERRA LabSOCSTM Integration Services C49168-08/2016.
http://www.canberra.com/services
[20]  Lenka, P., Jha, S.K., Gothankar, S., Tripathi, RM. and Puranik, V.D. (2009) Suitable Gammaenergy for Gamma-Spectrometric Determination of 238U in Surface Soilsamples of a High Rainfall Area in India. Journal of Environmental Radioactivity, 100, 509-514. https://doi.org/10.1016/j.jenvrad.2009.03.015
[21]  Papachristodoulou, C.A., Assimakopoulos, P.A., Patronis, N.E. and Ioannides, K.G. (2003) Use of HPGe Gamma-Ray Spectrometry to Assessthe Isotopic Composition of Uranium in Soils. Journal of Environmental Radioactivity, 64, 195-203.
https://doi.org/10.1016/S0265-931X(02)00049-8
[22]  Juhani, S. (2001) Natural Uranium as a Tracer in Radionuclide Geosphere Transport Studies. Report Series in Radiochemistry, Helsinki University, Helsinki.
[23]  Jukka, L. and Hou. X. (2010) Chemistry and Analysis of Radionuclides, Laboratory Techniques and Methodology. Wiley, Hoboken, NJ, 69-71.
[24]  Currie, L.A. (1968) Limits for Qualitative Detection and Quantitative Determination. Application to Radiochemistry. Journal of Analytical Chemistry, 40, 586-593.
https://doi.org/10.1021/ac60259a007
[25]  Waleed, M.A., Hanan, M.D., Ayman, M.E., Wesam, N.E. and Reda, M.A. (2015) Determination of Radioactivity Levels of Both Natural and Anthropogenic Radionuclides in Suez Canal. International Journal of Environmental Science, 4, 150-157.
[26]  El Mamoney, M.H. and Khater, A.E.M. (2004) Environmental Characterization and Radioecological Impacts of Non-Nuclear Industries on the Red Sea Coast. Journal of Environmental Radioactivity, 73, 151-168. https://doi.org/10.1016/j.jenvrad.2003.08.008
[27]  United Nations Scientific Committee on the Effects of Atomic Radiation, (UNSCEAR) (2000) Sources and Effects of Ionizing Radiation. Report to General Assembly, with Scientific Annexes, United Nation, New York.
[28]  Lasheen, Y.F., EL-Zakla, T., Seliman, A.F. and Abdel-Rassoul, A.A. (2008) Direct Gamma-Ray Measurement of Differentradionuclides in the Surface Water of Suez Canal. Journal of Radiological Protection, 43, 255-272. https://doi.org/10.1051/radiopro:2008002
[29]  United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR) (1988) Sources, Effects and Risks of Ionizing Radiation. UNSCEAR No. E88. IX.7, United Nations, New York.
[30]  NEA-OECD (1978) Nuclear Energy Agency. Exposure to Radiation from Natural Radioactivity in Building Materials. Report by NEA Group of Experts, OECD, Paris.
[31]  United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR) (1994) Exposure of the Population in the United State and Canada from Natural Background Radiation. NCRP Report No.94. National Council on Radiation Protection and Measurement, Bethesda, MD.
[32]  International Atomic Energy Agency (2003) Guidelines for Radioelement Mapping Using Gamma Ray Spectrometry Data. TECDOC No.1363, Vienna.
[33]  Lowson, R.T., Short, S.A., Davey, B.G. and Gray, D.J. (1998) 234U/238U and 230Th/234U Activity Ratios in Mineral Phases of a Lateritic Weathered Zone. Geochimica et Cosmochimica Acta, 50, 1697-1702. https://doi.org/10.1016/0016-7037(86)90131-6
[34]  Finch, R.J. and Ewing, R.C. (1992) The Corrosion of Uraninite under Oxidizing Conditions. Journal of Nuclear Materials, 190, 133-156. https://doi.org/10.1016/0022-3115(92)90083-W
[35]  El-Moselhy, K.M., Hamed, M.A. and Abd El-Azim, H. (1998) Distribution of Mercury and Tin along the Suez Canal. Journal of the Egyptian-German Society of Zoology, 27, 33-42.
[36]  Ibrahiem, N.M. and Pimpl, M. (1994) Uranium Concentrations in Sediments of the Suez Canal. Applied Radiation and Isotopes, 45, 919-921. https://doi.org/10.1016/0969-8043(94)90228-3
[37]  El Samra, M.I., El Deeb, K.Z., Askar, A.I., Wahby, S.D. and El Shazly, M.S.H. (1983) Preliminary Study of Petroleum Hydrocarbon Pollution along the Suez Canal. Bulletin of the Institute of Oceanography and Fisheries, 9, 97-101.
[38]  Din, K.S. and Vesterbacka, P. (2010) Spatial Distribution of U Isotopes in Sea-Water Sediments, Red Sea, Egypt. Journal of Environmental Radioactivity, 101, 165-169.
https://doi.org/10.1016/j.jenvrad.2009.10.001

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