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Determination of Radium-226 in Rock Samples by Liquid Scintillation Counter

DOI: 10.4236/ojapps.2019.94023, PP. 270-284

Keywords: Liquid Scintillation Counter, Spectrometry, Rock, Monazite, Radium-226

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Abstract:

The present work examines the validity of using barium as a carrier for radium-226 determination and optimizes the amount added during the radiochemical separation from rock samples. The activity concentration of Ra-226 is determined in rock samples by liquid scintillation spectrometer via its short-lived daughters after the radiochemical separation. The activity of Ra-226 was calculated based on the counts measured in a window set for Po-214 peak. The activity measured by Liquid Scintillation Counter, LSC using Pulse Shape Analysis, PSA. Ba-133 was used for chemical yield. The applied method was tested using a Certified Reference Material, CRM ore number-Dl-1a which shows a good agreement with the certified values. The applied method for measuring Ra-226 has been adapted to be used in rocks such as monazite. The average activity for Ra-226 in rock samples collected from the commercial grade Egyptian monazite was 13.85 ± 2.05 Bq/g with a detection limit 9.58 mBq/g. The optimum conditions have been established during the present work such as precision, cost and time preparation which makes the method useful for radio chemists and the decision makers.

References

[1]  International Atomic Energy Agency (2010) Analytical Methodology for the Determination of Radium Isotopes in Environmental Samples. Analytical Quality in Nuclear Applications, No. IAEA/AQ/19.
[2]  Martin, P. and Hancock, G.J. (2004) Routine Analysis of Naturally Occurring Radionuclides in Environmental Samples by Alpha-Particle Spectrometry. Supervising Scientist Report 180, Supervising Scientist Division, Darwin NT.
http://www.environment.gov.au/ssd/publications/ssr/180.html
[3]  Purkl, S. and Eisenhauer, A. (2003) A Rapid Method for α-Spectrometric Analysis of Radium Isotopes in Natural Waters Using Ion-Selective Membrane Technology. Applied Radiation and Isotopes, 59, 245-254.
https://doi.org/10.1016/S0969-8043(03)00172-6
[4]  Benedik, L., Spasova, Y., Vasile, M. and Atjen, U.W. (2008) Nuclear and Radiochemistry (NRC-7). Proceedings of the 7th International Conference on Nuclear and Radiochemistry, Budapest, Hungary, 24-29 August 2008, 320.
[5]  Jobbágy, V., Kávási, N., Somlai, J., Dombovári, P., Kardos, R. and Kovács, T. (2010) Radioanalytical Investigations of Uranium Concentrations in Natural Spring, Mineral, Spa and Drinking Waters in Hungary. Journal of Radioanalytical and Nuclear Chemistry, 286, 417-422.
https://doi.org/10.1007/s10967-010-0711-5
[6]  Tinker, R.A., Smith, J.D. and Cooper, M.B. (1995) An Assessment of the Selection criteria for an Analytical Method for Radium-226 in Environmental Samples. Journal of Radioanalytical and Nuclear Chemistry, 193, 329-336.
https://doi.org/10.1007/BF02039890
[7]  Lim, T.P. and Dave, N.K. (1981) A Rapid Method of Radium-226 Analysis in Water Samples Using Alpha Spectroscopic Technique. CIM Bulletin, 74, 97-105.
[8]  Gomez Escobar, V., Vera Tome, F. and Lozano, J.C. (1999) Extractive Procedure for 226Ra Determination in Aqueous Samples by Liquid Scintillation Counting. Radioactivity and Radiochemistry, 10, 17-21.
[9]  Manjon, G., Vioque, I., Moreno, H., Garcia-Tenorio, R. and Garc, M. (1997) Determination of Ra-226 and Ra-224 in Drinking Water by Liquid Scintillation Counting. Applied Radiation and Isotopes, 48, 535-540.
https://doi.org/10.1016/S0969-8043(96)00297-7
[10]  Saarinen, L. and Suksi, J. (1992) Determination of Uranium Series Radionuclides Pa-231 and Ra-226 by Liquid Scintillation Counting, Nuclear Waste Commission of Finnish Power Companies. Technical Report, Helsinki, Finland, October 1992 (YJT-95-01).
[11]  Juutunen, P., Ruutu, A. and Suksi, J. (2001) Determination of Ra-226 from Rock Samples Using LSC. Internal Report, University of Helsinki, Finland.
[12]  International Atomic Energy Agency (1990) The Environmental Behavior of Radium. Technical Report Series, Vienna, TECDOC No. 310.
[13]  Suksi, J. (2001) Natural Uranium as a Tracer in Radionuclide Geosphere Transport Studies. Report Series in Radiochemistry, University of Helsinki, 16/2001.
[14]  Jukka, L. and Hou, X. (2010) Chemistry and Analysis of Radionuclides, Laboratory Techniques and Methodology. Wiley, New York, 69-71.
[15]  International Atomic Energy Agency (2014) A Procedure for the Rapid Determination of Ra-226 and Ra-228 in Drinking Water by Liquid Scintillation Counting. Vienna, Series, AQ/39.
[16]  Lide, D.R. (2003) HandBook of Chemistry and Physics. 84th Edition, CRC Press, Boca Raton, FL.
[17]  Sill, C.W., Puphal, K.W. and Hindman, F.D. (1974) Simultaneous Determination of Alpha Emitting Nuclides of Radium through Californium in Soil. Analytical Chemistry, 46, 1725-1737.
https://doi.org/10.1021/ac60348a021
[18]  Bojanowski, R., Radecki, Z. and Burns, K. (2005) Determination of Radium and Uranium Isotopes in Natural Waters by Sorption on Hydrous Manganese Dioxide Followed by Alpha-Spectrometry. Journal of Radioanalytical and Nuclear Chemistry, 264, 437-443.
https://doi.org/10.1007/s10967-005-0734-5
[19]  Smith, C.W. and Steger, H.F. (1983) Radium-226 in Certified Uranium Reference Ores Dl-1a BL-4a, DH-1a and BL-5. Canada Central for Mineral Energy Technology, Ottawa, Canada.
[20]  Mien, N.Q. and Loat, B.V. (2008) Determination of the Annual Beta Dose by Measuring Beta Activity Using the Liquid Scintillation Technique. VNU Journal of Science, Mathematics-Physics, 24, 36-41.
[21]  Passo, C.J. and Cook, G.T. (1994) Handbook of Environmental of Liquid Scintillation Counter, LSC Spectrometry, Packard Instrument Company, Meriden, CT.
[22]  Yufu, Y., Salbu, B., Bjoernstad, H.E. and Lien, H. (1990) Improvement for α-Energy Resolution in Determination of Low-Level Plutonium by Liquid Scintillation Counting. Journal of Radioanalytical and Nuclear Chemistry, 45, 345-353.
https://doi.org/10.1007/BF02165075
[23]  Kleinschmidt, R.I. (2004) Gross Alpha and Beta Activity Analysis in Water—A Routine Laboratory Method Using Liquid Scintillation Analysis. Applied Radiation and Isotopes, 61, 333-338.
https://doi.org/10.1016/j.apradiso.2004.03.004
[24]  Canada Center for Minerals and Energy Technology (2017) Reference Uranium and Thorium Ore. Energy of Mines and Resources Canada, Number DL-1a.
http://www.nrcan.gc.ca/mining-materials/certified-reference-materials/certificate-price-list/8049
[25]  Goldin, A.S. (1961) Determination of Dissolved Radium. Analytical Chemistry, 33, 406-409.
https://doi.org/10.1021/ac60171a030
[26]  QuantulusWallac, L.K.B. (1991) Pulse Shape Analysis in Liquid Scintillation Counting. Wallac Application Product News, November 1991.
[27]  Volpe, A.M., Olivares, J.A. and Murrell, M.T. (1991) Determination of Radium Isotope Ratios and Abundances in Geologic Samples by Thermal Ionization Mass Spectrometry. Analytical Chemistry, 63, 913-916.
https://doi.org/10.1021/ac00009a015
[28]  Currie, L.A. (1968) Limits for Detection and Quantitative Determination. Analytical Chemistry, 40, 586-593.
https://doi.org/10.1021/ac60259a007
[29]  Cook, M.L. and Kleinschmidt, R. (2009) Simultaneous Measurement of Ra-226 and Ra-228 in Water by Liquid Scintillation Method. Queensland Health, Australia.
[30]  Chalupnik, S. and Lebecka, J.M. (1993) Determination of Ra-226, Ra-228 and Ra-224 in Water and Aqueous Solutions by Liquid Scintillation Counting. International Conference on Advances in LSC. Radiocarbon, 397-403.

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