全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

Characterization of Kaolin Deposits in Okpella and Environs, Southern Nigeria

DOI: 10.4236/ijg.2019.103018, PP. 317-327

Keywords: Kaolin, Mineral, Characterization, XRD, XRF, Okpella

Full-Text   Cite this paper   Add to My Lib

Abstract:

Kaolin is one of the most important industrial minerals whose application is dependent on its structure and chemical composition. This study makes an attempt to explore and determine the origin of kaolin deposits within and around Okpella, as well as to investigate the mineralogical and chemical compositions using the X-ray diffraction (XRD) and X-ray fluorescence (XRF) method. These were carried out with the intention of determining the most suitable applications for the clay mineral. It was observed that major phases in the clay samples from the three different deposits are kaolinite, microcline, illite/mica, plagioclase/albite and quartz. These phases were observed in varied percentages. Samples from Ajego 2 show a marked absence of kaolinite but contain high concentration of plagioclase feldspar and quartz which permit its usage in the production of glass and iron industries. Further, the samples from Ajego 1 contain by far the highest concentration of kaolinite, while the samples from Anegha consist of kaolinite, a mixed layer of illite/mica, plagioclase, alkali feldspars, and albite which is necessary for producing mullite fibers in ceramic matrix at a temperature of around 1400°C and it is suitable in pigment production. The XRF result for Ajego2 and Anegha samples has Silica composition of 51.847 wt%, 32.540 wt% and 37.295 wt% respectively and an alumina content of 14.962 wt%, 29.834 wt% and 20.227 wt% respectively. The trace amount of some of the oxides such as K2O, TiO2, Fe2O3 and SnO2 can help in the beneficiation process.

References

[1]  Idenyi, N.E. and Nwajagu, C.O. (2003) Non-Metallic Material Technology. Olison Publication, Enugu.
[2]  Murray, H.H. (1999) Applied Clay Mineralogy Today and Tomorrow. Clay Minerals, 34, 39-49.
https://doi.org/10.1180/000985599546055
[3]  Ekpunobi, U.E., Duru, C.B., Ogbuagu, A.S. and Obumselu, E.O. (2013) Analysis and Characterization of Clay Deposits in Idemili River, South Eastern Nigeria. Pelagia Research Library, Der Chemica Sinica, 4, 6-9.
[4]  Baker, C.J. and Uren, R.E. (1982) Kaolin in New South Wales. Geological Survey of New South Wales, 231.
[5]  Murray, H.H. (1988) Kaolin Minerals: Their Genesis and Occurrences. In: Bailey, S.W., Ed., Hydrous Phyllosilicates (Exclusive of Micas) Reviews in Mineralogy, Mineralogical Society of America, Washington DC, Vol. 19, 67-90.
[6]  Cravero, E. and Dominguez, F. (1999) Origin of Sedimentary Kaolin in the Neuquen Basin, Argentina as Determined by Oxygen Isotopes. Periodico di Mineralogia, 68, 213-222.
[7]  Hassan, M.D. (2014) Geochemistry and Origin of the Cretaceous Sedimentary Kaolin Deposits, Red Sea, Egypt. Geochemistry, 74, 195-203.
[8]  Lima, P.A., Angélica, R. and Neves, R. (2017) Dissolution Kinetics of Amazonian Meta-Kaolin in Hydrochloric Acid. Clay Minerals, 52, 75-82.
https://doi.org/10.1180/claymin.2017.052.1.05
[9]  Kotal, M. and Bhowmick, A.K. (2015) Polymer Nano-Composites from Modified Clays: Recent Advances and Challenges. Progress in Polymer Science, 51, 127-187.
https://doi.org/10.1016/j.progpolymsci.2015.10.001
[10]  Liu, P., Farzana, R., Rajarao, R. and Sahajwalla, V. (2017) Lightweight Expanded Aggregates from the Mixture of Waste Automotive Plastics and Clay. Construction and Building Materials, 145, 283-291.
https://doi.org/10.1016/j.conbuildmat.2017.04.009
[11]  Imerys, P. (2013) Calcined Clays in Light Weight Coatings Technical Guides.
http://www.imerys-paper.com/Technical/Guide/Calcined/Clayin_LWCpdf
[12]  Clark, M.D.T. (2013) Paints and Pigments Review.
http://www.nzic.org.nzChemProcess/polymer/10D.pdf
[13]  Rahaman, M.A. (1988) Recent Advances in the Study of the Basement Complex of Nigeria. Symposium on the Geology of Nigeria, Obafemi Awolowo University.
[14]  Parker, S.P. (1988) McGraw-Hill Encyclopedia of the Geological Sciences. 2nd Edition, McGraw-Hill, New York, 32-33, 69-72.
[15]  Kuzart, M. (1984) Betonite and Monmorrllonite Clayin: Industrial Minerals and Rocks. Elsevier, Amsterdam, 280-287.
[16]  Hosterman, J.W. and Patterson, S.H. (1992) Betonite and Fuller’s Earth Resources of the United States. US Geological Survey, Washington DC, 45.
[17]  Patterson, S.H. and Murray, H.H. (1975) Clays. In: Lefond, S.I., Ed., Industrial Minerals and Rocks, 4th Edition, American Institute of Mining, Metallurgical, and Petroleum Engineers, New York, 519-595.
[18]  Bates, T.F. (1964) Geology and Mineralogy of the Sedmentary Kaolins of the Southeastern United States: A Review. In: Clays and Clay Minerals, Pergamon Press, New York, 177-194.
[19]  Petit, S., Robert, J.L., Decarreau, A., Besson, G., Grauby, O. and Martin, F. (1995) Contribution of Spectroscopic Methods to 2/1 Clay Characterization. Bulletin des centres de Recherches Exploration-Production Elf Aquitaine, 19, 119-147.
[20]  Grauby, O., Petit, S., Decarreau, A. and Baronnnet, A. (1994) Nontrionite-Saponite Series: An Experimental Approach. European Journal of Mineralogy, 4, 99-112.
https://doi.org/10.1127/ejm/6/1/0099
[21]  Giresse, P. and Wiewiora, A. (2001) Stratigraphic Condensed Dposition and Diagenetic Evolution of Green Clay Minerals in Deep Water Sediments on the Ivory Coast-Ghana Ridge. Marine Geology, 179, 51-70.
https://doi.org/10.1016/S0025-3227(01)00193-1
[22]  Ergul, S., Akyildiz, M. and Karamanov, A. (2007) Ceramic Material from Basaltic Tuffs. Industrial Ceramics, 27, 89-94.
[23]  Aramide, F.O. (2012) Effect of Firing Temperature on Mechanical Properties of Fired Masonry Bricks Produced from Ipetumodu Clay. Leonardo Journal of sciences, 70-82.
[24]  Aramide, F.O. (2012) Production and Characterization of Porous Insulating Fired Bricks from Ifon Clay with Varied Sawdust Admixture. Journal of Minerals and Materials Characterization and Engineering, 11, 970-975.
https://doi.org/10.4236/jmmce.2012.1110097
[25]  Bayraktar, I. and Çakır, U. (2002) Quality Feldspar Production at Çine Akınaden. Industrial Minerals, 56-59.
[26]  Sedmale, G., Sperberga, I., Sedmalis, U. and Valancius, Z. (2006) Formation of High-Temperature Crystalline Phases in Ceramics from Illite Clay and Dolomite. Journal of the European Ceramic Society, 26, 3351-3355.
https://doi.org/10.1016/j.jeurceramsoc.2005.10.012
[27]  Virta, R.L. (2002) US Geological Survey Mineral Industry Surveys. Clay and Shale.
http://minerals.usgs.gov/minerals/pubs/commodity/clays/claysmyb02.pdf
[28]  Fan, C.M. and Aw, P.C. (1988) Processing of Illite Powder in Bidor, Perak: A Study of the Process and Potential Use of Illite Clay. Buletin Persatuan Geologi Malaysia, 15, 37.
[29]  Mesbah, H., Wilson, M.A. and Carter, M.A. (2011) The Role of the Kaolinite-Mullite Reaction Sequence in Moisture Mass Gain on Fired Kaolinite.
http://www.scientific.net/ATS.68.38.pdf

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133