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-  2017 

Sm原子精细结构能级的理论分析
Theoretical analysis of energy levels for the fine structure of Sm I

DOI: 10.7523/j.issn.2095-6134.2017.01.003

Keywords: Sm原子,精细结构能级,拟合计算方法
Sm I
,fine structure energy levels,fitting method

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Abstract:

摘要 根据非相对论加相对论修正的原子能量表达式,结合实验能级拟合方法计算Sm原子的精细结构能级。对于基组态[Xe]4f66s2的能级,通过对比不同拟合计算结果与实验值,得到各参量对能级的影响规律。对于奇宇称组态4f66s6p+4f55d6s2的能级,利用22条实验能级,得到134条已知能级较精确的拟合计算值。对于偶宇称组态4f66s2+4f65d6s+4f66s7s的能级,利用17条实验能级,得到65条已知能级较精确的计算值。最后,标识了5条高激发态偶宇称4f6(7F)6s7s5FJ(J=1~5)谱项能级。

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