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-  2017 

差分脉冲阳极溶出伏安法检测重金属离子
Detection of Heavy Metal Ions by Differential Pulse Stripping Voltammetry

DOI: 10.3969/j.issn.1001-0548.2017.05.022

Keywords: 差分脉冲阳极溶出伏安法,玻碳电极,重金属离子,同位镀汞法

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Abstract:

采用新型的差分脉冲阳极溶出伏安法检测液相环境下的铅、镉重金属离子。通过改变不同的实验条件,优化实验参数,最终选用以玻碳电极同位镀汞的方法测定液相环境下的铅、镉离子。该方法对铅、镉两种离子的检出限分别达到0.54、0.79 g/L,其中镉离子线性相关系数达到了0.999 7。该差分脉冲阳极溶出伏安法具有灵敏度高、仪器设备简单、操作简便,污染小,能重复测量等优点,是一种高效,廉价的检测重金属浓度的方法,为重金属离子的实时监测打下一定基础。

References

[1]  FARGHALY O A. Direct and simultaneous voltammetric analysis of heavy metals in tap water samples at Assiut city:an approach to improve the analysis time for nickel and cobalt determination at mercury film electrode[J]. Microchemical Journal, 2003, 75(2):119-131.
[2]  李建平, 彭图治, 张雪君. 铋膜电极电位溶出法测定痕量铅、镉、锌[J]. 分析化学, 2002, 30(9):1092-1095. LI Jian-pin, PENG Tu-zhi, ZHANG Xue-jun. Determination of lead, cadmium, zinc using bismuth-film electrodes by potentiometric stripping analysis[J]. Chinese Journal of Analytical Chemistry, 2002, 30(9):1092-1095.
[3]  吕志进, 李建虎, 黄欣, 等. 阳极溶出伏安法测定食品中铅镉的含量[J]. 天津医科大学学报, 2002, 8(2):187-190. Lü Zhi-jin, LI Jian-hu, HUANG Xin, et al. Determination of Pb, Cd in food by anodic stripping voltammetry[J]. Journal of Tianjin Medical University, 2002, 8(2):187-190.
[4]  方宾, 金家英, 张玉忠, 等. 微分电位溶出法测定人发中铜铅镉锌的研究[J]. 分析试验室, 1995, 11(4):37-39. FANG Bin, JIN Jia-ying, ZHANG Yu-zhong, et al. Study on continuous determination of trace copper, lead, cadmium and zinc in human hair[J]. Chinese Journal of Analysis of Laboratory, 1995, 11(4):37-39.
[5]  邓天龙, 廖梦霞. 微量铅, 镉极谱法连续测定[J]. 分析化学, 1998(11):1403-1403. DENG Tian-long, LIAO Meng-xia. Continuous determination of Ca Pb polarography[J]. Chinese Journal of Analytical Chemistry, 1998(11):1403-1403.
[6]  宋桂金, 魏小平. 电位溶出法测定污泥中的痕量铅和镉[J]. 广西科学, 2003, 10(2):107-109. SONG Gui-jin, WEI Xiao-ping. Determination of Pb<sup>2+</sup> and Cd<sup>2+</sup> in sludge samples by potential stripping analysis[J]. Guangxi Sciences, 2003, 10(2):107-109, 112.
[7]  于庆凯, 李丹. 阳极溶出伏安法同时测定海水中铜、铅、镉、锌[J]. 化学工程师, 2009(10):25-27. YU Qing-kai, LI Dan. Determination of Cu, Pb, Cd, Zn in sea water by anodic stripping voltammetry[J]. Chemical Engineer, 2009(10):25-27.
[8]  SAHLIN E, JAGNER D, RATANA-OHPAS R. Mercury nucleation on glassy carbon electrodes[J]. Analytica Chimica Acta, 1997, 346(2):157-164.
[9]  陶海升, 阚显文, 方宾. 同位镀汞差示脉冲溶出伏安法对铅镉的同时测定[J]. 安徽师范大学学报:自然科学版, 2005, 28(2):197-199. TAO Hai-sheng, KAN Xian-wen, FANG Bin. Simultaneity plating Hg derivative pulse stripping voltammetric successive determinationg of Pb and Cd[J]. Journal of Anhui Normal University (Natural Science), 2005, 28(2):197-199.
[10]  朱浩嘉, 潘道东, 顾愿愿, 等. 同位镀汞阳极溶出伏安法测定牛奶中镉、铅、铜[J]. 食品科学, 2014, 35(8):121-124. ZHU Hao-jia, PAN Dao-dong, GU Yuan-yuan, et al. Determination of cadmium, lead and copper in milk by Hg-plated anodic stripping voltammetry[J]. Food Science, 2014, 35(8):121-124.
[11]  LEGEAI S, SOROPOGUI K, CRETINON M, et al. Economic bismuth-film microsensor for anodic stripping analysis of trace heavy metals using differential pulse voltammetry[J]. Analytical & Bioanalytical Chemistry, 2005, 383(5):839-847.
[12]  KOROLCZUK M, MOROZIEWICZ A, GRABARCZYK M. Determination of subnanomolar concentrations of cobalt by adsorptive stripping voltammetry at a bismuth film electrode[J]. Analytical & Bioanalytical Chemistry, 2005, 382(7):1678-1682.
[13]  赖瑢, 丘福保, 徐镇耿, 等. 微波消解-溶出伏安法对食品中铜、铅、镉的同时测定[J]. 分析测试学报, 2010, 29(2):203-206. LAI Rong, QIU Fu-bao, XU Zhen-geng, et al, Determination of copper, lead and cadmium in food by microwave digestion-anodic stripping voltammetry[J]. Journal of Instrumental Analysis, 2010, 29(2):203-206.
[14]  BROWN R J C, MILTON M J T. Analytical techniques for trace element analysis:an overview[J]. Trac Trends in Analytical Chemistry, 2005, 24(3):266-274.
[15]  KEFALA G, ECONOMOU A, VOULGAROPOULOS A, et al. A study of bismuth-film electrodes for the detection of trace metals by anodic stripping voltammetry and their application to the determination of Pb and Zn in tapwater and human hair[J]. Talanta, 2003, 61(61):603-610.
[16]  高红艳, 孙佳林, 李宁. 阳极溶出方波伏安法测自来水中的镉[J]. 伊犁师范学院学报:自然科学版, 2008(2):31-33. GAO Hong-yan, SUN Jia-lin, LI Ning. Determination of cadmium in a water sample with anodic stripping square wave voltammetry[J]. Journal of Ili Normal University (Natural Scienc Edition), 2008(2):31-33.
[17]  ENSAFI A A, NAZARI Z, FRITSCH I. Highly sensitive differential pulse voltammetric determination of Cd, Zn and Pb ions in water samples using stable carbon-based mercury thin-film electrode[J]. Electroanalysis, 2010, 22(21):2551-2557.
[18]  王静, 贺鹏, 孙海林, 等. 同位镀汞膜电极同时测定水中的铅和镉[J]. 中国环保产业, 2015(6):39-42. WANG Jing, HE Peng, SUN Hai-lin, et al. On plating mercury film electrode while eetermining lead and cadmium in water[J]. China Environmental Protection Industry, 2015(6):39-42.

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