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- 2016
碳/碳复合材料SiC/MoSi2/ZrO2涂层体系氧化烧蚀性能
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Abstract:
抗氧化涂层技术是解决碳/碳复合材料高温抗氧化性的最有效技术途径之一。为了提高材料在1 800℃以上的高温抗氧化性能，首次采用包埋法、涂刷法和等离子喷涂法在碳/碳复合材料表面制备出SiC/MoSi2/ZrO2梯度抗氧化涂层体系。采用SEM/EDS、结合力和粗糙度测试对涂层表面及断面形貌进行微观分析，利用等离子风洞对整个涂层体系进行氧化试验。结果表明：基体、过渡层和高温抗氧化层之间结合力良好，高温抗氧化层厚度均匀、结构致密。经等离子风洞氧化600 s后，涂层表面温度达到1 850℃，氧化质量失重速率仅为3.15×10-6 g/（cm2·s）。表明SiC/MOSi2/ZrO2梯度抗氧化涂层体系在1 800℃以上的高温环境下具有很好的抗氧化性能。 Anti oxidation coating technology is one of the most effective ways to solve the high temperature oxidation resistance of carbon/carbon composites. In order to improve the high temperature oxidation resistance of materials above 1 800℃, a SiC/MoSi2/ZrO2 gradient oxidation resistant coating system was fabricated on surface of the carbon/carbon composites by the pack cementation method, slurry method and plasma spraying process. The surface and section morphologies of coating were observed by XRD/EDS, intensity and roughness testing. The total coating system is tested by plasma wind tunnel. Results show that the coating has a compact interfacial bonding strength among matrix, transition layer and high temperature oxidation resistance layer. High temperature oxidation resistance layer has uniform thickness and dense structure. After 600 s plasma wind tunnel oxidation, surface temperature of coating reaches up to 1 850℃. The oxidation mass loss rate is 3.15×10-6 g/(cm2·s). The SiC/MoSi2/ZrO2 gradient oxidation resistant coating system has good antioxidant capacity over 1 800℃.
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