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- 2016
阻抗渐变高介电钛酸钡/聚酰亚胺复合薄膜的设计与制备
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Abstract:
人体皮肤与空气间在介电常数上有着失配性，可穿戴设备所用的材料需要与人体皮肤有良好的匹配性能，而单一的材料与结构已不能满足这种需求。利用原位聚合法合成了一系列钛酸钡（BaTiO3）/聚酰亚胺（PI）混合溶液，通过逐层流延涂覆的方法设计制备了一种具有阻抗渐变性质的多层BaTiO3/PI复合薄膜。结果表明：BaTiO3纳米粒子可在复合薄膜中均匀分散，调节无机粒子的含量，能够有效地控制复合薄膜的介电常数在2.5~34.0之间变化；同时，BaTiO3/PI复合薄膜对外加电场的频率具有不敏感性，也具有良好的力学性能，能够满足可穿戴设备对材料的要求。 The dielectric constant of human skin and air have a large mismatch. The materials used for wearable devices need to have a great matching performance with human shin, which can not be achieved by solo material and structure. By using the in-situ polymerization method, a series of barium titanate (BaTiO3)/polyimide(PI) mixed solutions were synthesized. Then, by means of casting method step by step, a multilayer BaTiO3/PI composite film with impedance gradient was designed and fabricated. The results show that BaTiO3 nano-particles can distribute in the composite film uniformly. By adjusting the content of inorganic particles, the dielectric constant of prepared BaTiO3/PI composite film can be controlled in the range of 2.5-34.0. Besides, BaTiO3/PI composite film is insensible to the frequency of electric field and also has a good mechanical property, which can meet the requirements of wearable device materials. 国家国际科技合作专项（2013DFA31770）；国家自然科学基金（51373007，51003004）；国家“973”计划（2010CB934700）；北京市自然科学基金（2142019）
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