微米六方BN-KH550/聚丁二酸丁二醇酯耐热性复合膜的制备及性能
Preparation and properties of micron hexagonal BN-KH550/poly (butylene succinate) thermal endurance composite films

为进一步改善聚丁二酸丁二醇酯(PBS)的力学性能和耐热性能, 采用硅烷偶联剂KH550改性微米六方氮化硼(h-BN), 对PBS进行共混改性, 通过熔融共混与开炼压延工艺制备了具有较高耐热性的h-BN-KH550/PBS复合膜。对h-BN-KH550粒子结构和复合膜的力学性能、聚集态结构、断面形貌、结晶性能及热稳定性进行了测试和表征。结果表明:与PBS相比, h-BN-KH550/PBS复合膜的力学性能得到改善, 当KH550与h-BN质量比为2:50、 h-BN-KH550与PBS质量比为3:50时, 综合力学性能最优;h-BN-KH550粒子可在PBS中均匀分散;在PBS结晶过程中, h-BN-KH550作为成核剂, 使PBS的结晶速率加快, 结晶度增大;h-BN-KH550/PBS复合膜的热稳定性显著提高, 当h-BN-KH550与PBS质量比为3:50时, 复合膜热分解过程中质量损失为5%、10%、50%时的温度(T5d、T10d、T50d)和热分解峰值温度(Tp)分别提高了30.0、22.6、9.5和10.0 ℃。 In order to significantly improve the mechanical properties and thermal endurance of poly(butylene succinate), the micron hexagonal boron nitride (h-BN) was treated with silane coupling agent KH550, and blended with PBS to modify PBS. The high thermal endurance h-BN-KH550/PBS composite films were prepared through melt blending and rolling mill process. The particle structure of h-BN-KH550 and the mechanical properties, aggregation state structure, fracture morphologies, crystallization property and thermal stability of composite films were investigated. The results reveal that the mechanical properties of h-BN-KH550/PBS composite films are greatly improved compared with PBS. When the mass ratio of KH550 to h-BN is 2:50 and h-BN-KH550 to PBS is 3:50, the comprehensive mechanical properties are optimal. The h-BN-KH550 particles are well dispersed in PBS. During the crystallization process of PBS, h-BN-KH550 can act as nucleating agent and increase the crystallization rate and crystallinity of PBS. The thermal stability of h-BN-KH550/PBS composite films is significantly increased. When the mass ratio of h-BN-KH550 to PBS is 3:50, the temperatures at 5%, 10%, 50% mass loss (T5d, T10d,T50d) and the peak of pyrolysis temperature (Tp) are increased by 30.0, 22.6, 9.5 and 10.0 ℃ during the pyrolysis process of composite films, respectively. 高等学校博士学科点专项科研基金(20126125110001); 高分子材料工程国家重点实验室(四川大学)开放课题基金(KF201101)