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- 2017
化石燃料环境友好工业路线开发
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Abstract:
摘要： 提出了化石燃料环境友好的工业开发路线。将化石燃料碳氢化合物在一定工艺过程条件转化为H2和CO2,将CO2转化为CO2含量最高的稳定固体产品三嗪醇C3H3N3O3,部分H2再进行发电,这是一条化石燃料环境友好的能源工业路线;将二氧化碳封存产品三嗪醇继续合成低碳排放的三嗪类高分子材料是一条化石燃料环境友好的材料工业路线。阐述了化石燃料环境友好工业路线的关键工艺过程,并从能耗及产品应用等方面分析了该路线的优点,该路线从源头上控制了二氧化碳排放,是一条化石燃料环境友好的工业路线。
Abstract: This paper proposes an environment-friendly industrial route of fossil fuel. Fossil fuels are converted into CO2 and H2 in certain technological conditions, and CO2 is converted into triazinetriol, the rest of H2 is used to generate power, which is an environment-friendly energy industrial route of fossil fuel. Triazinetriol continues to be synthetized polymer materials which are an environment-friendly material industrial route of fossil fuel. We expound the key technology and analyze the advantages of this industrial line from the energy consumption and the product application. It is concluded that this industrial line regulates carbon dioxide emission from the source, and at the same time realizes the fossil fuel environment-friendly industrial route
| [1] | 王付燕,孙洪志,宋名秀,等.二氧化碳的氨化反应研究进展[J].化工进展,2014,33(1):209-218. WANG Fuyan, SUN Hongzhi, SONG Mingxiu, et al. Research progress of ammonization reaction of carbon dioxide[J]. Journal of Chemical industry and Engineering Progress, 2014, 33(1):209-218. |
| [2] | 王勤辉,沈洵.骆仲泱,等.新型近零排放煤气化燃烧利用系统[J].动力工程, 2003, 23(5):2711-2715. WANG Qinhui, SHEN Xun, LUO Zhongyang, et al. New near zero emissions coal utilization technology with combined gasification and combustion[J]. Power Engineering, 2003, 23(5):2711-2715. |
| [3] | 王智化,王勤辉,骆仲泱,等.新型煤气化燃烧集成制氢系统的热力学研究[J].中国电机工程学报, 2005, 25(12):91-97. WANG Zhihua, WANG Qinhui, LUO Zhongyang, et al. The ermodynamic analysis of hydrogen production by new coal utilization technology with combined gasification and combustion[J]. Proceedings of the CSEE, 2005, 25(12):91-97. |
| [4] | ZHOU Xinhui, SU Tongming, JIANG Yuexiu, et al. CuO-Fe<sub>2</sub>O<sub>3</sub>-CeO<sub>2</sub>/HZSM-5 functional catalyst hydrogenated CO<sub>2</sub> for enhanced dimethyl ether synthesis[J]. Chemical Engineering Science, 2016, 153:10-20. |
| [5] | 宋名秀,孙洪志,阿布都拉江·那斯尔,等.二氧化碳减排技术路线探讨[J].现代化工,2013,33(8):5-8. SONG Mingxiu, SUN Hongzhi, Abudoulajiang·Nasier, et al. Discussion on carbon dioxide emission reduction technologies[J]. Journal of Modern Chemical Industry, 2013, 33(8):5-8. |
| [6] | 靳治良,钱玲,吕功煊.二氧化碳化学——现状及展望[J].化学进展,2010,22(6):1102-1115. JIN Zhiliang, QIAN Ling, Lü Gongxuan. CO<sub>2</sub> Chemistry——Actuality and Expectation[J]. Progress in Chemistry, 2010, 22(6):1102-1115. |
| [7] | 朱维群,王倩,宋名秀,等.一种利用高反应氨基还原剂进行烟气脱硝的方法:CN 102553412 A[P].2012. ZHU Weiqun, WANG Qian, SONG Mingxiu, et al. A kind of amino reducer with high response method for flue gas denitration: China, CN 102553412 A[P]. 2012. |
| [8] | ROMANO M C, LOZZA G G. Long-term coal gasification-based power plants with near-zero emissions. Part A: zecomix cycle[J]. Greenh Gas Control, 2010, 4(3):459-468. |
| [9] | LIN Shiying, SUZUKI Yoshizo, HATANO Hiroyuki, et al. Hydrogen production from hydrocarbon by integration of water-carbon reaction and carbon dioxide removal(HyPr-ring method)[J]. Energy Fuels, 2001, 15(2):339-343. |
| [10] | Hasliza Bahruji, Michael Bowker, Graham Hutchings. Pd/ZnO catalysts for direct CO<sub>2</sub> hydrogenation to methanol[J]. Journal of Catalysis, 2016, 343:133-146. |
| [11] | 孙洪志,王倩,朱维群,等.CO<sub>2</sub>化学利用的研究进展[J].化工进展,2013,32(7):1666-1672. SUN Hongzhi, WANG Qian, ZHU Weiqun, et al. Progress in the chemical utilization of carbon dioxide[J]. Chemical Industry and Engineering Progress, 2013, 32(7):1666-1672. |
| [12] | 张娟利,杨天华. 二氧化碳的资源化化工利用[J]. 煤化工, 2016, 44(3):1-5. ZHANG Juanli, YANG Tianhua. Chemical utilization of carbon dioxide as a resource[J]. Coal Chemical Industry, 2016, 44(3):1-5. |
| [13] | AMIN Roohul, LIU Bingsi, HUANG Zhaobiao, et al. Hydrogen and syn gas production via CO<sub>2</sub> dry reforming of methane over Mg/La promoted CoeNi/MSU-S catalyst[J]. International Journal of Hydrogen Energy, 2016, 41:807-819. |
| [14] | 沈华民.工业尿素合成理论(四)[J].化肥工业,2010,37(2):11-17. SHEN Minghua. Industrial urea synthesis theory(4)[J]. Journal of Chemical Fertilizer Industry, 2010, 37(2):11-17. |
| [15] | 金涌,王垚.低碳经济:理念·实践·创新[J].中国工程科学,2008,10(9):4-13. JIN Yong, WANG Gui. Low carbon economy: concept, practice, innovation[J]. Journal of China Engineering Science, 2008, 10(9):4-13. |
| [16] | 梁英. 三嗪胺废渣氮素释放特征及对黑麦草生长影响的研究[D].泰安:山东农业大学,2009. LIANG Yin. Nutrients release characters of melamine waste and its effects on ryegrass growth[D]. Taian: Shandong Agricultural University, 2009. |
| [17] | 王峰,田文栋,肖云汉.煤直接制氢实验研究[J].中国电机工程学报, 2007, 27(32):40-45. WANG Feng, TIAN Wendong, XIAO Yunhan. Experimental study on direct hydrogen production from coal[J]. Proceedings of the CSEE, 2007, 27(32):40-45. |
| [18] | 关键,王勤辉,骆仲泱,等.新型近零排放煤气化燃烧利用系统的优化及性能预测[J].中国电机工程学报, 2006, 26(9):7-13. GUAN Jian, WANG Qinhui, LUO Zhongyang, et al. Optimization and performance prediction of a new near zero emissions coal utilization[J]. Proceedings of the CSEE, 2006, 26(9):7-13. |
| [19] | Konstantinos Atsonios, Kyriakos D Panopoulos, Emmanuel Kakaras, et al. Thermocatalytic CO<sub>2</sub> hydrogenation for methanol and ethanol production: Process improvements[J]. International Journal of Hydrogen Energy, 2016, 41:792-806. |
| [20] | 朱维群,孙洪志,王倩,等.一种合成三聚氰酸树脂的方法:CN 103865020 B[P].2015. ZHU Weiqun, SUN Hongzhi, WANG Qian, et al. A method of synthesis of cyanuric acid-formaldehyde resin: China, CN 103865020 B[P]. 2015. |
| [21] | 陈苏锋,史铁钧,杨兆攀,等.三炔丙基异氰尿酸酯的合成、表征及其非等温固化动力学[J].化工学报,2012,63(7):2085-2091. CHEN Sufeng, SHI Tiejun, YANG Zhaopan, et al. Synthesis, characterization and non-isothermal curing kinetics of tri-propargyl isocyanurate[J]. Journal of CIESC, 2012,63(7):2085-2091. |
| [22] | PAIVA N T, PEREIRA J, FERRA J M. Study of influence of synthesis conditions on properties of melamine-urea formaldehyde resins[J]. International Wood Products Journal, 2012, 3(1):51-57. |
| [23] | 朱维群,宋名秀,王倩,等.一种低温合成三嗪胺的方法:中国,CN 102295615 B[P]. 2013. ZHU Weiqun, SONG Mingxiu, WANG Qian, et al. A method of low temperature synthesis of melamine: China, CN 102295615 B[P]. 2013. |
| [24] | 王付燕.二氧化碳化学封存产物三嗪醇的合成及应用研究[D].济南:山东大学,2015. WANG Fuyan. Study on the synthesis of carbon dioxide chemical sequestration product triazinetriol and its application[D]. Jinan: Shandong University, 2015. |
| [25] | 中国科学院能源战略研究组.中国能源可持续发展战略专题研究[M].北京:科学出版社,2006. Energy strategy of the Chinese academy of sciences research group. Chinas energy town sustainable development strategy research[M]. Beijing: Science Press, 2006. |
| [26] | BARRETO L, MAKIHIRA A, RIAHI K.The hydrogen economy in the 21 century: a sustainable development scenario[J]. International Journal of Hydrogen Energy, 2003, 28(3):267-284. |
| [27] | 李超华.浅谈天然气和煤制氢气的技术[J].中国化工贸易,2015,7(16):176. LI Chaohua. Introduction to hydrogen gas and coal technology[J]. Journal of China national chemical trade, 2015, 7(16):176. |
| [28] | GAO L, PATERSON N, DUGWELL D, et al. Zero-Emission Carbon concept(ZECA): equipment commissioning and extents of the reaction with hydrogen and steam[J]. Energy Fuels, 2008, 22(1):463-470. |
| [29] | LIN Shiying, HARADA Michiaki, SUZUKI Yoshizo, et al. Hydrogen production from coal by separating carbon dioxide during gasification[J]. Fuel, 2002, 81(16):2079-2085. |
| [30] | 肖云汉.煤制氢零排放系统[J].工程热物理学报, 2001, 22(1):13-15. XIAO Yunhan. Hydrogen from coal zero emission[J]. Engineering thermorphysics, 2001, 22(1):13-15. |
| [31] | Renata J da Silva, Allan F Pimentel, Robson S Monteiro, et al. Synthesis of methanol and dimethyl ether from the CO<sub>2</sub> hydrogenation over CuZnO supported on Al<sub>2</sub>O<sub>3</sub> and Nb<sub>2</sub>O<sub>5</sub>[J]. International Journal of CO<sub>2</sub> Utilization, 2016, 15:83-88. |
| [32] | 孙洪志.二氧化碳氨化衍生物三嗪醇的应用性能研究[D].济南:山东大学,2014. SUN Hongzhi. Study on carbon dioxide ammoniated derivatives triazinetriol and its application properties[D]. Jinan: Shandong University, 2014. |
| [33] | 彭敏,单文伟,曾光明,等.三(环氧丙基)异氰尿酸酯的合成[J].热固性树脂,2004,19(6):12-14. PENG Ming, SHAN Weiwen, ZENG Guangming, et al. Synthesis of tris-glycidyl isocyanuratel[J]. Journal of Thermosetting Resin, 2004, 19(6):12-14. |
| [34] | 王莎.煤基化学链反应器制氢研究[D].南京:东南大学,2009. WANG Sha. Coal-based chemical chain reactor hydrogen production research[D]. Nanjing: Southeast University, 2009. |
| [35] | FRANCO A, DIAZ A R. The future challenges for “clean coal technologies”: joining efficiency increase and pollutant emission control[J]. Energy, 2009, 34(3):348-354. |
| [36] | LIN Shiying, SUZUKI Yoshizo, HATANO Hiroyuki, et al. developing an innovative method HyPr-RING to produce hydrogen from hydrocarbons[J]. Energy Conversion and Management, 2002, 43(9):1283-1290. |
| [37] | SATO Shinya, LIN Shiying, SUZUKI Yoshizo, et al. Hydrogen production from heavy oil in the presence of calcium hydroxide[J]. Fuel, 2003, 82(5):561-567. |
