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- 2018
非贵金属电催化析氧催化剂的最新进展
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Abstract:
摘要 氢气具有环境友好、含量丰富、高能量密度等特点，是一种可以替代化石能源的绿色环保可再生能源. 电解水是制备氢气最有效途径之一. 但在电解水过程中，动力学过程非常缓慢，过电位较大的阳极析氧半反应严重限制了阴极析氢反应效率. 因此，研究高效、稳定和低成本的催化剂来降低析氧反应的过电位，从而提高析氢反应效率受到了广泛关注. 基于非贵金属催化剂本身特性及其在高浓度OH-条件下具有较高OER催化活性等原因，本文首先简要介绍碱性条件下析氧反应机理及其性能的评价方法，然后重点讨论非贵金属电催化析氧催化剂的最新研究进展. 最后对如何深入研究催化机理、设计高效、双功能及新型非贵金属电催化析氧催化剂进行了展望
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