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-  2018 

镀锡层上钛-磷复合体系钝化膜的制备与表征
Preparation and Characterization of Titanate-Phosphate Passivation Film on Tinplate

DOI: 10.13208/j.electrochem.170442

Keywords: 电镀锡,钛盐,磷酸盐,无铬钝化,耐蚀性,
tin plating
,titanium salt,phosphate,Cr free passivation,corrosion resistance

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Abstract:

摘要 通过钛盐与磷酸盐体系复配的方法,在镀锡层表面得到了一种钛-磷复合体系钝化膜. 利用扫描电子显微镜(SEM)、X射线光电子能谱 (XPS)、盐雾试验、Tafel极化曲线和EIS交流阻抗谱测试等方法,研究了所得钝化膜的表面形貌、组成与耐蚀性能. 结果表明,得到的钝化膜层的主要组成成分为Ti3(PO4)4nH2O和TiO2,在镀锡层表面结晶细致并有封孔的作用,因此有很好的耐蚀性能

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