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- 2018
高性能析氧电催化剂的设计策略
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Abstract:
摘要 电催化水分解反应是可以实现规模化制取氢气的一种重要绿色无污染的手段，但是其效率极大地受制于阳极析氧反应. 因此，发展廉价、高效的析氧反应催化剂是当下的研究热点. 通过分析决定析氧反应催化活性的因素，本综述总结了低成本、高效、稳定的析氧电催化剂的一些通用设计与制备策略，包括：1）通过电子结构调控、结晶度调控、相调控、缺陷位调控以及自旋态调控提升单个催化活性位点的本征催化活性；2）设计与构筑先进电极结构，以实现活性位点数量最大化，获得大电流下稳定的电极材料. 进而，选取了一些具有代表性的高效析氧催化剂作为例子来阐述这些策略的实用性. 最后，对高效、可在大电流密度下稳定工作的析氧催化剂的理性设计、可控制备和发展方向提出了展望，以期为新型高性能析氧催化剂的设计提供指导
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