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- 2018
有机氧化还原液流电池的研究进展
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Abstract:
摘要 氧化还原液流电池（简称液流电池）是一种正在积极研制开发的新型大容量电化学储能装置，其活性物质是流动的电解质溶液，最显著的特点是规模化蓄电. 在广泛利用可再生能源的呼声高涨形势下，可以预见液流电池将迎来一个快速发展的时期. 氧化还原活性物质是液流电池能源转化的载体，也是液流电池中最核心的部分.传统液流电池利用无机材料作为活性物质，然而，无机材料成本高、毒性、资源有限、形成枝晶和电化学活性低等缺点限制了液流电池的大规模应用. 有机活性物质由于具有成本低、“绿色”、资源丰富、分子能级易于调节和电化学反应快等优点，引起了国内外的广泛关注. 近年来，有机液流电池的性能得到快速提升，一系列有机活性物质相继被开发出来. 本文梳理了近年来有机液流电池的研究进展. 首先简要介绍了液流电池的应用领域和技术特点；然后根据电解液种类的不同，详细讨论了有机活性物质在水系和非水系液流电池的应用情况；最后展望了有机液流电池走向实际应用所面临的挑战和潜在研究方向
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