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Analysis of Spectral Signatures of Silicone-Based Sealant Materials Used in Residential and Commercial Buildings

DOI: 10.4236/jbcpr.2018.63008, PP. 112-121

Keywords: Silicone Sealant, Characterization of Construction Materials, Raman Spectra of Building Sealants, Reflectance Spectra of Silicone Sealants

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Abstract:

In the construction industry, silicone is primarily used as sealant material to fill gaps and cracks providing water and air-tightness to vertical construction projects reducing energy usage bills and enhancing the integrity of construction materials. This paper reports the results of spectral analysis of commonly used building sealant materials used in residential and commercial buildings. A dozen commercially available silicone-based sealant materials composed of different ingredients representing three manufacturer brands are characterized using Raman and UV-VIS-NIR spectroscopic techniques. The characteristic vibrational fingerprints of the selected sealant materials are summarized, and the Raman and reflectance spectra of the samples are also presented. It is observed that most of the samples appear to have similar vibrational band assignments and reflectance spectra. However, analysis of the Raman spectral positions and the reflectance spectra reveals that there are distinct differences among the sealant materials.

References

[1]  Silicone, American Chemistry Council, Inc. (2014).
https://www.chemicalsafetyfacts.org/silicones-post/
[2]  Wen, X., Yuan, X., Lan, L., Hao, L., Wang, Y., Li, S., Lu, H. and Bao, Z. (2017) RTV Silicone Rubber Degradation Induced by Temperature Cycling. Energies, 10, 1-12.
https://doi.org/10.3390/en10071054
[3]  Jia, Z., Fang, S., Gao, H., Guan, Z., Wang, L. and Xu, Z. (2008) Development of RTV Silicone Coatings in China: Overview and Bibliography. IEEE Electrical Insulation Magazine, 24, 28-41. https://doi.org/10.1109/MEI.2008.4473052
[4]  Kim, S.H., Cherney, E.A. and Hackam, R. (1992) Hydrophobic Behavior of Insulators Coated with RTV Silicone Rubber. IEEE Electrical Insulation Magazine, 27, 610-622.
https://doi.org/10.1109/14.142726
[5]  Chang, H., Wan, Z., Chen, X., Wan, J., Luo, L., Zhang, H., Shu, S. and Tu, Z. (2016) Temperature and Humidity Effect on Aging of Silicone Rubbers as Sealing Materials for Proton Exchange Membrane Fuel Cell Applications. Applied Thermal Engineering, 104, 472-478.
https://doi.org/10.1016/j.applthermaleng.2016.05.095
[6]  Polysiloxanes (Silicones), Polymer Properties Database (2015)
http://polymerdatabase.com/polymer%20classes/Silicone%20type.html
[7]  Wu, J., Dong, J., Wang, Y. and Gond, B.K. (2017) Thermal Oxidation Aging Effects on Silicone Rubber Sealing Performance. Polymer Degradation and Stability, 135, 43-53.
https://doi.org/10.1016/j.polymdegradstab.2016.11.017
[8]  Feng, J., Zhang, Q., Tu, Z., Tu, W., Wan, Z., Pan, M. and Zhang, H. (2014) Degradation of Silicone Rubbers with Different Hardness in Various Aqueous Solutions. Polymer Degradation and Stability, 109, 122-128.
https://doi.org/10.1016/j.polymdegradstab.2014.07.011
[9]  Beigbeder, A., Linares, M., Devalckenaere, M., Degée, P., Claes, M., Beljonne, D., Lazzaroni, R. and Dubois, P. (2008) CH-π Interactions as the Driving Force for Silicone-Based Nanocomposites with Exceptional Properties. Advanced Materials, 20, 1003-1007.
https://doi.org/10.1002/adma.200701497
[10]  Boström, L. (2002) Ageing Effects on the Fire Resistance of Building Structures. Brandforsk Project 322-011. SP Report 2002:29, SP Swedish National Testing and Research Institute, Borås.
[11]  Kassu, A., Walker, L., Sanders, R., Farley, C., Mills, J. and Sharma, A. (2017) Nondestructive Spectroscopic Characterization of Building Materials. SPIE Smart Structures and Materials and Nondestructive Evaluation and Health Monitoring, Portland, Vol. 10169, 101692V-1.
[12]  Fernández-Carrasco, L., Torrens-Martín, D., Morales, L.M. and Martínez-Ramírez, S. (2012) Infrared Spectroscopy in the Analysis of Building and Construction Materials, Infrared Spectroscopy. InTech, London. http://www.intechopen.com/
[13]  Anderson, E., Almond, M.J. and Matthews, W. (2014) Analysis of Wall Plasters and Natural Sediments from the Neolithic Town of öatalhüyük (Turkey) by a Range of Analytical Techniques. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 133, 326-334.
https://doi.org/10.1016/j.saa.2014.04.072
[14]  Lampakis, D., Karapanagiotis, I. and Katsibiri, O. (2017) Spectroscopic Investigation Leading to the Documentation of Three Post-Byzantine Wall Paintings. Applied Spectroscopy, 71, 129-140.
https://doi.org/10.1177/0003702816654151
[15]  Brough, A.R. and Atkinson, A. (2001) Micro-Raman Spectroscopy of Thaumasite. Cement and Concrete Research, 31, 421-424.
https://doi.org/10.1016/S0008-8846(00)00459-2
[16]  ASTM C 834-00 (2000) Standard Specification for Latex Sealants.
[17]  ASTM C 920-98 (1998) Standard Specification for Elastomeric Joint Sealants.
[18]  DAP (2015) Safety Data Sheet. SDS No. 00010013001.
[19]  DAP (2016) Safety Data Sheet. SDS No. 00010002001.
[20]  Cai, D., Neyer, A., Kuckuk, R. and Heise, H.M. (2010) Raman, Mid-Infrared, Near-Infrared and Ultraviolet-Visible Spectroscopy of PDMS Silicone Rubber for Characterization of Polymer Optical Waveguide Materials. Journal of Molecular Structure, 976, 274-281.
https://doi.org/10.1016/j.molstruc.2010.03.054
[21]  Jayes, L., Hard, A.P., Séné, C., Parker, S.F. and Jayasooriya, U.A. (2003) Vibrational Spectroscopic Analysis of Silicones: A Fourier Transform-Raman and Inelastic Neutron Scattering Investigation. Analytical Chemistry, 75, 742-746.
https://doi.org/10.1021/ac026012f

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