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Peculiar Set-Retarding Effect of Miserly Amounts of Pyrocatechol on Calcium Aluminate Cement Hydration

DOI: 10.4236/msa.2018.95031, PP. 455-463

Keywords: Pyrocatechol, Calcium Aluminate Cements, Hydration, NMR Spectroscopy

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Abstract:

Pyrocatechol (benzene-1,2-diol) acts upon a calcium aluminate cement (CAC) as a very strong set and hardening retardant and a potent plasticizing agent at the same time. By studying CAC-pyrocatechol compositions using different analytical methods it was shown that pyrocatechol indeed slows CAC hydration and decreases strength of hardening stone. What makes this behavior a peculiar one is that pyrocatechol is known to accelerate Portland cement (PC) setting drastically.

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