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More Insight on Structure of New Binary Cerium Borate Glasses

DOI: 10.4236/njgc.2018.81002, PP. 12-21

Keywords: Borate, Cerium, Former Units, NMR Analysis

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Abstract:

The structure of glasses in the system of xCeO2(100？-？x)B2O3, x = 30, 40, 50 mol% CeO2 has been explored for the first time by correlation between data obtained from XRD, FTIR and 11B NMR analyses. NMR spectroscopy andFTIR spectroscopy have confirmed that transformation rate of BO3 to BO4 groups is reduced by CeO2 addition.The concentration of Ce4-O-Ce4 is increased at the expense of

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