Polyurethane-imide elastomers (PUIEs) are formed from isocyanate, polyol,
acid anhydride, and diamine by liquid polymerization. Unfortunately, many of
the diamines have rarely been applied to the formation of PUIEs. Hence, investigating the effect of diamines on PUIEs
remains a challenge in polymer chemistry. Herein, PUIEs prepared from
4,4'-diphenylmethane diisocyanate (MDI), polytetramethylene glycol (Mw:
1000), pyromelliticdianhydride, and aromatic diamines (such as p-phenylene diamine, 4,4'-oxydianiline, and 1,3-bis(4-aminophenoxy)benzene),and aliphatic diamines (such as 1,2-ethylene diamine,
1,6-hexamethylene diamine, and 1,12-dodecamethylene diamine) were
synthesized by liquid polymerization. The morphologies and the chemical,
thermal, and mechanical properties of the various PUIEs were investigated. The
obtained elastomeric sheets were characterized in terms of the following tests
and methods: solubility and swelling tests, X-ray diffraction and differential scanning calorimetry, dynamic
mechanical analysis and thermogravimetric
analysis, tensile tests, nuclear magnetic resonance spectroscopy, infrared spectroscopy, atomic force microscopy, contact angle microscopy, and
scanning electron microscopy
References
[1]
Lin, M.-F., Shu, Y.-C., Tsen, W.-C. and Chuang, F.-S. (1999) Synthesis of Polyurethane-Imide (PU-Imide) Copolymers with Different Dianhydrides and Their Properties. Polymer International, 48, 433-435. https://doi.org/10.1002/(SICI)1097-0126(199906)48:6<433::AID-PI161>3.0.CO;2-1
[2]
Asai, K., Inoue, S. and Okamoto H. (2000) Preparation and Properties of Imide-Containing Elastic Polymers from Elastic Polyureas and Pyromellitic Dianhydride. Journal of Polymer Science Part A: Polymer Chemistry, 38, 715-723. https://doi.org/10.1002/(SICI)1099-0518(20000215)38:4<715::AID-POLA6>3.0.CO;2-8
[3]
Takeichi, C., Yamazaki, Y., Fukui, T., Matsumoto, A. and Inagaki, M. (2000) Preparation and Characterization of Porous Carbonized Films by the Pyrolysis of Poly (Urethane-Imide) Films. Tanso, 2000, 388-394. https://doi.org/10.7209/tanso.2000.388
[4]
Liu, J. and Ma, D. (2002) Study on Synthesis and Thermal Properties of Polyurethane-Imide Copolymers with Multiple Hard Segments. Journal of Applied Polymer Science, 84, 2206-2215. https://doi.org/10.1002/app.10421
[5]
Qiu, F., Yang, D. and Li, P. (2009) Synthesis, Characterization, and Thermos-Optical-Properties of Poly (Urethane-Imide) Based on Azo-Disperse Dye in Its Side Chains. Iranian Polymer Journal, 18, 651-661.
[6]
Kogiso, T. and Inoue, S. (2010) Synthesis and Properties of Elastic Polyurethane-Imide. Journal of Applied Polymer Science, 115, 242-248. https://doi.org/10.1002/app.31126
[7]
Zang, L., Han, X., Xiao, W. and Li, J. (2011) Synthesis and Property Study of a New Polyurethane-Imide. Hua Gong Jin Zhan, 30, 2491-2494.
[8]
Sang, X., Wang, R., Chen, X., Zang, L., An, M. and Shen, Y. (2011) A Review on Synthesis and Property of Polyurethane-Imide. Advanced Materials Research, 284, 1746. https://doi.org/10.4028/www.scientific.net/AMR.284-286.1746
[9]
Sang, X., Chen, X., Hou, G. and Yu, S. (2011) Preparation and Properties of RigidPolyurethane-Imide Foams. Advanced Materials Research, 150, 1119.
[10]
Wang, Y., Tian, H., Bian, Q., Xiang, A., Ge, X. and Liu, G. (2015) Effect of Trolamine and Dibutyltin Dilaurate on the Structure and Properties of Polyurethane-Imide Foams. Cellular Polymers, 34, 119-135.
[11]
Jiang, B., Hao, J., Wang, W., Jiang, L. and Cai, X. (2001) Synthesis and Thermal Properties of Poly (Urethane-Imide). Journal of Applied Polymer Science, 81, 773-781. https://doi.org/10.1002/app.1494
[12]
Yeganeh, H. and Shamekli, M.A. (2004) Poly (Urethane-Imide), a New Generation of Thermoplastic Elastomers with Enhanced Thermal Stability. Polymer, 45, 359-365.
[13]
Gnanasekaran, D. and Reddy, B.S.R. (2011) Synthesis and Characterization of Poly (Urethane-Imide) POSS Nanocomposites. NanoTech Conference & Expo 2011, 1, 445-448.
[14]
Tai, M.-H., Huang, S.-H., Liu, S.-J., Chen, C.-J., Chen, P.-J. and Chen, S.-H. (2008) Synthesis and Properties of Poly(Urethane-Imide) Interpenetrating Network Membranes. Desalination, 233, 191-200.
[15]
Zuo, M. and Takeichi, T. (1999) Preparation and Characterization of Poly (Urethane-Imide) Films Prepared from Reactive Polyimide and Polyurethane Prepolymer. Polymer, 40, 5153-5160.
[16]
Patel, B.P., Patel, H.S. and Patel, D.B. (2011) Glass Reinforcement of Epoxy Resin Based Poly(Urethane-Imide)S. International Journal of Plastics Technology, 15, 163-173. https://doi.org/10.1007/s12588-012-9021-9
[17]
Gui, D., Gao, X., Hao, J. and Liu, J. (2014) Preparation and Characterization of Liquid Crystalline Polyurethane-Imide Modified Epoxy Resin Composites. Polymer Engineering & Science, 54, 1704-1711. https://doi.org/10.1002/pen.23712
